连续重整装置仿真系统的设计开发

为提高操作人员对连续重整装置开停工及事故处理的熟练程度，并对生产进行指导，采用半机理模型结合设计和现场数据介发的连续重整装置仿真系统已在现场成功投用。介绍了该仿真系统的软硬件结构、动态模型及仿真功能。     

罗坡坝水电站泄水建筑物设计及试验研究

罗坡坝水电站拱坝设置有三个溢流表孔,中间孔高程低于两侧的孔,三个泄水孔设有差动式挑坎。通过模型试验表明,不发生危及岸坡稳定的泄流雾化问题,此外,适当控制泄流水舌射程可以减少坝下冲坑深度,消能效果良好。     

Structural optimization of the cross-beam of a gantry machine tool based on grey relational analysis

Crossbeam structural design of gantry machine tool is a multi-level, multi-index and multi-scheme decision-making problem. In order to solve the above problem, the optimum seeking model of crossbeam structure was built through using the grey relational analysis and Analytic Hierarchy Process. The finite element analysis of the static and dynamic performance parameters for four kinds of crossbeam structural schemes designed had been done, and the optimal design scheme was selected by using the optimum seeking model. After conducting sensitivity analysis for the optimal crossbeam selected, the reasonable design variables were obtained, and the dynamic optimization design model of crossbeam was established. Six groups of non-inferior solutions were obtained after solving the optimization design model. The optimal solution was selected from the non-inferior solution set through using the crossbeam structural optimization method based on grey relational analysis again, which makes the crossbeam’s dynamic performance improving greatly. The dynamic experiments on the crossbeams before and after optimization design were conducted, then the experimental results show that the first four order natural frequencies of the crossbeam increase 17.56 %, 19.36 %, 17.04 % and 19.58 % respectively, which proves that the structural optimization design method based on grey relational analysis proposed in this paper is reasonable and practicable.     

环氧氯丙烷的生产技术与市场分析

综述了环氧氯丙烷国内外生产现状 ,消费概况及生产技术 ,并对其发展前景作了初步预测     

相转移催化剂与反应机理的结构适应性研究

有机化学反应中,催化剂的选择关系到有机物合成的效率及产物的纯度,为了提高催化剂的研制效率,缩小催化剂的选择范围,对某些季铵盐类相转移催化剂与反应速率、产物组成之间的关系进行了研究。结果表明:适宜的催化剂,其结构往往与反应机理相适应。     

Local Electronic Structure Modulation Enables Fast-Charging Capability for Li-Rich Mn-Based Oxides Cathodes With Reversible Anionic Redox Activity

Anionic and cationic redox chemistries boost ultrahigh specific capacities of Li-rich Mn-based oxides cathodes (LRMO). However, irreversible oxygen evolution and sluggish kinetics result in continuous capacity decay and poor rate performance, restricting the commercial fast-charging cathodes application for lithium ion batteries. Herein, the local electronic structure of LRMO is appropriately modulated to alleviate oxygen release, enhance anionic redox reversibility, and facilitate Li⁺ diffusion via facile surface defect engineering. Concretely, oxygen vacancies integrated on the surface of LRMO reduce the density of states of O 2p band and trigger much delocalized electrons to distribute around the transition metal, resulting in less oxygen release, enhancing reversible anionic redox and the MnO₆ octahedral distortion. Besides, partially reduced Mn and lattice vacancies synchronously stimulate the electrochemical activity and boost the electronic conductivity, Li⁺ diffusion rate, and fast charge transfer. Therefore, the modified LRMO exhibits enhanced cyclic stability and fast-charging capability: a high discharging capacity of 212.6 mAh·g⁻¹ with 86.98% capacity retention after 100 cycles at 1 C is obtained and to charge to its 80%, SOC is shortened to 9.4 min at 5 C charging rate. This work will draw attention to boosting the fast-charging capability of LRMO via the local electronic structure modulation.     

A calibration method of external parameters of 2D laser in rotary 3D scanning

Aiming at the problem of external parameter calibration in the combined rotating three-dimensional (3D) scanning process of laser radar and turntable, a fast 3D data scanning and accurate equipment calibration method suitable for industrial application scenarios is proposed. The coordinates of the center of the circle in the laser radar coordinate system are obtained by fitting the coordinates of the center of the circle with the scanning arc. Through the standard size and rotation angle of the target ball, the coordinates of the ball center in the turntable coordinate system are obtained. The rotation parameter R and the translation parameter T of the minimum value of the data set conversion error function in the two coordinate systems are calculated. The experimental results show that the error between the converted data and the actual data is within 0.1 mm, which meets the actual work requirements. This calibration method has the advantages of high accuracy and strong robustness.     

基于DaVinci平台的桶标在线双目识别系统设计

为解决工业生产线灌装桶标在线识别,避免人工检测的疏失、降低工作量,提出并实现基于DaVinci平台和嵌入式图像检测技术的桶标在线识别系统,该系统采用双核处理器OMAP3530对运动桶标图像进行处理,并采用双摄像头、双处理器的双目并行处理架构解决灌装桶在生产线上不规则旋转识别,提出的嵌入式图像识别及融合决策算法克服了工业现场光线变化大、不规则背景扰动等干扰影响,经过现场2 000次随机试验,无漏识和错识虚警,仅存在部分因桶标遮挡、污损导致未识别,总识别率达到99.81%,满足实际使用要求。