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排序方式: 共有82条查询结果,搜索用时 31 毫秒
1.
Carla G. Luciano Larissa Tessaro Rodrigo V. Lourenço Ana Mônica Q. B. Bittante Andrezza M. Fernandes Paulo J. A. Sobral 《应用聚合物科学杂志》2021,138(42):51246
Research on biopolymers-based active films produced with natural antioxidants and/or antimicrobials has gained attention over the last few years; however, anti-mold activity has been less studied than those of anti-bacteria. The aim of this work was the development and characterization of bi-layer films based on gelatin with natamycin and/or “Pitanga” leaf hydroethanolic extract in the second thin layer in order to determine the effects of these bioactive compounds on bi-layered film properties. The films were characterized regarding their moisture content and solubility in water, optical properties, microstructure, mechanical and thermal properties, water contact angle, water vapor permeability, UV/visible light transmission, X-ray diffraction, Fourier transform infrared (FTIR) spectroscopy, and antioxidant and anti-mold activities. Active films presented activity against Penicillium spp and Aspergillus niger and demonstrated antioxidant activity, as measured by ABTS •+ and DPPH • methods. Neither additive used in the films' second layer significantly affected the films' moisture content, thermal properties or the molecular interactions of the polymer matrix, assessed by FTIR, although some mechanical properties were affected, and the water contact angle. In conclusion, bi-layer films have reduced the quantity of additives required to maintain the antioxidant and anti-mold activities, as compared to similar monolayer films of the same thickness. 相似文献
2.
Rui C. Gonçalves Don Batory João L. Sobral Taylor L. Riché 《Software and Systems Modeling》2017,16(4):929-947
Dataflow programs are widely used. Each program is a directed graph where nodes are computations and edges indicate the flow of data. In prior work, we reverse-engineered legacy dataflow programs by deriving their optimized implementations from a simple specification graph using graph transformations called refinements and optimizations. In MDE speak, our derivations were PIM-to-PSM mappings. In this paper, we show how extensions complement refinements, optimizations, and PIM-to-PSM derivations to make the process of reverse engineering complex legacy dataflow programs tractable. We explain how optional functionality in transformations can be encoded, thereby enabling us to encode product lines of transformations as well as product lines of dataflow programs. We describe the implementation of extensions in the \(\mathtt{ReFlO}\) tool and present two non-trivial case studies as evidence of our work’s generality. 相似文献
3.
Carla Giovana Luciano Larissa Tessaro Rodrigo Vinicius Lourenço Ana Mônica Quinta Barbosa Bittante Andrezza Maria Fernandes Isabel Cristina Freitas Moraes Paulo José do Amaral Sobral 《International Journal of Food Science & Technology》2021,56(2):587-599
The addition of nisin into a gelatin matrix can change properties of the film. The aim of this work was to develop gelatin-based films containing different nisin concentrations in order to study their influence on the film's antimicrobial and physical properties and their rheological properties as a film-forming solution (FFS). The FFS was characterised by rheological assays, and the gelatin-based active films were characterised and assessed by the effects of nisin concentrations on their various properties, including antimicrobial activity. Nisin's concentration affected not only its viscoelastic properties of FFS but also its film solubility in water, film surface roughness and light barrier. The addition of nisin also slightly modified the water contact angle and the mechanical properties of the gelatin films. Finally, the films demonstrated activity against Staphylococcus aureus and Listeria monocytogenes at concentrations above 56 mg of nisin g−1 of gelatin. 相似文献
4.
5.
ABSTRACT Biofilms are edible films formed from biopolymers. In the casting process technique, the biofilm is obtained by the drying of a colloidal solution in the final process stage The aim of this work was to analyse the drying process of gelatin based biofilms, in room frontier conditions. The biofilms were prepared initially by dissolving gelatin in water and adding sorbitol as plasticizer. The filmogenic solution was dried in an automatic drier under various drying conditions, for 1mm film: air temperature (T= 35, 40 and 45 °C), relative humidity (?= 60 and 75 %) and air velocity (v= 3m/s). The drying kinetics was measured for 15, 30 and 45 % sorbitol concentrations. Sorption isotherms at 25, 35 and 45 °C were determined for the 15% sorbitol concentration films by the static gravimetric method. The glass transition and the melting temperature for various moisture contents were determined with a Differential Scanning Calorimeter TA 2010. The results showed an unusual behaviour for temperature dependence: decreasing drying kinetics with increasing air temperature. Also separation of gelatin and sorbitol were seen when the temperature increased. This phenomenon occurs when the film temperature during the drying process gets close to the melting temperature of the film. 相似文献
6.
E. Sabadini B. C. Carvalho Jr. P.J do A. Sobral M.D. Hubinger 《Drying Technology》1998,16(9):2095-2115
Dehydrated salted meat is widely used in Brazil as a very important source of animal protein. The main objective of this kind of processing is water removal. initially by osmotic pressure changes and then by drying, resulting in a product with intermediate moisture levels.
In this work, mass transfer and salt diffusion in pieces of meat submitted to wet and dry salting were studied. Slabs of beef m. trapezius with an infinite plate geometry were salted in a NaCl saturated solution or in a dry salt bed, at two temperatures (10 and 20°C) and different time exposures (120 min and 96 hours). Equilibration studies were extended up to six days.
It was observed that water loss increased with salt uptake, for increasing periods of times. At 20°C the moisture loss was higher than it was at 10°C in both salting processes. On the other hand, the kinetics of salt uptake and moisture loss were of greater importance in the process of dry salting than in that of wet salting.
The salt diffusion coefficient for wet salting was 0.26 × 10-10m2/s at20°C and 0.25 × 10-10 m2/s at 10°C and for the dry salting the values were 19.37 × 10-10 m2/s at 20°C and 17.21 × 10-10 m2/s at 10°C. 相似文献
In this work, mass transfer and salt diffusion in pieces of meat submitted to wet and dry salting were studied. Slabs of beef m. trapezius with an infinite plate geometry were salted in a NaCl saturated solution or in a dry salt bed, at two temperatures (10 and 20°C) and different time exposures (120 min and 96 hours). Equilibration studies were extended up to six days.
It was observed that water loss increased with salt uptake, for increasing periods of times. At 20°C the moisture loss was higher than it was at 10°C in both salting processes. On the other hand, the kinetics of salt uptake and moisture loss were of greater importance in the process of dry salting than in that of wet salting.
The salt diffusion coefficient for wet salting was 0.26 × 10-10m2/s at20°C and 0.25 × 10-10 m2/s at 10°C and for the dry salting the values were 19.37 × 10-10 m2/s at 20°C and 17.21 × 10-10 m2/s at 10°C. 相似文献
7.
Gabriel de Souza Ferreira Louise Sobral Daniel Weingart Barreto Verônica Calado 《European Journal of Lipid Science and Technology》2023,125(6):2200141
The processing of the orange leads to a large generation of waste, which is underutilized or discarded. Thus, this study proposes a route to treat oily waste from the orange juice industry, transforming it into a by-product of higher added value to the chemical industry. The orange wax is obtained by hydrodistillation and solvent extraction, and the clarification of the wax is carried out with the oxidative treatment using H2O2. A 32 Experimental Design confirmed that the factors, temperature, and concentration of the reactant, influence both response variables, the colorimetric changes and yield. The obtained waxes are characterized by chromatographic (CG-MS), thermal, and rheological analysis. The results of the CG-MS indicate that the clarification method is effective as the components responsible for the pigmentation and odor of the wax cannot be identified after the clarification process. Thermogravimetry analysis and differential exploratory calorimetryindicate a slight increase in thermal stability and a decrease in crystallinity after the clarification process. Rheological analyses show that the obtained waxes present similar flow behavior as commercial beeswax. Therefore, it can be affirmed that this work obtains a green wax from a residue for potential replacement of commercial waxes according to its properties analyzed. Practical applications: This work shows the extraction of orange wax from oily industrial wastes for possible applications in the food and cosmetics industries. The orange wax can be a sustainable substitute for nonrenewable products and supply the wax market due to the high demand. In addition, methods for processing and characterization of the waxes are presented in this work. 相似文献
8.
E. Sabadini B. C. Carvalho Jr. P.J do A. Sobral M.D. Hubinger 《Drying Technology》2013,31(9-10):2095-2115
ABSTRACT Dehydrated salted meat is widely used in Brazil as a very important source of animal protein. The main objective of this kind of processing is water removal. initially by osmotic pressure changes and then by drying, resulting in a product with intermediate moisture levels. In this work, mass transfer and salt diffusion in pieces of meat submitted to wet and dry salting were studied. Slabs of beef m. trapezius with an infinite plate geometry were salted in a NaCl saturated solution or in a dry salt bed, at two temperatures (10 and 20°C) and different time exposures (120 min and 96 hours). Equilibration studies were extended up to six days. It was observed that water loss increased with salt uptake, for increasing periods of times. At 20°C the moisture loss was higher than it was at 10°C in both salting processes. On the other hand, the kinetics of salt uptake and moisture loss were of greater importance in the process of dry salting than in that of wet salting. The salt diffusion coefficient for wet salting was 0.26 × 10?10m2/s at20°C and 0.25 × 10?10 m2/s at 10°C and for the dry salting the values were 19.37 × 10?10 m2/s at 20°C and 17.21 × 10?10 m2/s at 10°C. 相似文献
9.
Priscila M.A. Alves Rosemary A. CarvalhoIzabel C.F. Moraes Carla G. LucianoAna Mônica Q.B. Bittante Paulo J.A. Sobral 《Food Hydrocolloids》2011
Both gelatin and poly(vinyl alcohol) (PVA) can be cross linked with glutaraldehyde (GLU). In the case of gelatin, the GLU reacts with each ε-NH2 functional group of adjacent lysine residues, while for PVA, the GLU reacts with two adjacent hydroxyl groups, forming acetal bridges. Thus it can be considered possible to cross link adjacent macromolecules of gelatin and PVA using GLU. In this context, the aims of this work were the development of biodegradable films based on blends of gelatin and poly(vinyl alcohol) cross linked with GLU, and the characterization of some of their main physical and functional properties. All the films were produced from film-forming solutions (FFS) containing 2 g macromolecules (PVA + gelatin)/100 g FFS, 25 g glycerol/100 g macromolecules, and 4 g GLU (25% solution)/100 g FFS. The FFS were prepared with two concentrations of PVA (20 or 50 g PVA/100 g macromolecules) and two reaction temperatures: 90 or 55 °C, applied for 30 min. The films were obtained after drying (30 °C/24 h) and conditioning at 25 °C and 58% of relative humidity for 7 days, and were then characterized. The results for the color parameters, mechanical properties, phase transitions and infrared spectra showed that some chemical modifications occurred, principally for the gelatin. However, in general, all the characteristics of the films were either typical of films based on blends of these macromolecules without cross linking, or slightly higher. A greater improvement in the properties of this material was probably not observed due to the crystallinity of the PVA, which has a melting point above 90 °C. The presence of microcrystals in the polymer chain probably reduced macromolecular mobility, hindering the reaction. Thus more research is necessary to produce biodegradable films with improved properties. 相似文献
10.
A series of three meso-tetra-alkyl porphyrins (H2TAPs) were synthesised and their electrochemical properties were studied in dichloromethane containing either tetra-butyl ammonium perclorate (TBAP) or tetra-butyl ammonium hexafluorophosphate TBA(PF6) as supporting electrolyte (SE) by cyclic voltammetry and in situ UV/vis spectroelectrochemistry. Values of E1/2 for the recorded four redox processes of these porphyrins and of the meso-tetra-phenyl porphyrin (H2TPP) on glassy carbon and platinum were measured and compared. The redox data collected on the first oxidation and the first reduction processes predict that the value of Δ(LUMO − HOMO) for the H2TAPs is lower than for meso-tetra-phenyl porphyrin and, therefore, that the first Q band of the electronic spectra of the H2TAPs is red shifted relatively to the same band in the spectrum of H2TPP; this shift was indeed found. The second oxidation process of the H2TAPs is influenced by the supporting electrolyte used and the dication then formed is consumed by an irreversible chemical reaction. The species produced in this reaction is irreversibly reduced at a considerably lower potential. The electrochemical and spectroelectrochemical data collected are consistent with the occurrence of structural distortion in the macrocycle rings of the H2TAPs. 相似文献