Optimization of the dye-sensitized solar cell performance by mechanical compression

In this study, the P25 titanium dioxide (TiO₂) nanoparticle (NP) thin film was coated on the fluorine-doped tin oxide (FTO) glass substrate by a doctor blade method. The film then compressed mechanically to be the photoanode of dye-sensitized solar cells (DSSCs). Various compression pressures on TiO₂ NP film were tested to optimize the performance of DSSCs. The mechanical compression reduces TiO₂ inter-particle distance improving the electron transport efficiency. The UV–vis spectrophotometer and electrochemical impedance spectroscopy (EIS) were employed to quantify the light-harvesting efficiency and the charge transport impedance at various interfaces in DSSC, respectively. The incident photon-to-current conversion efficiency was also monitored. The results show that when the DSSC fabricated by the TiO₂ NP thin film compressed at pressure of 279 kg/cm², the minimum resistance of 9.38 Ω at dye/TiO₂ NP/electrolyte interfaces, the maximum short-circuit photocurrent density of 15.11 mA/cm², and the photoelectric conversion efficiency of 5.94% were observed. Compared to the DSSC fabricated by the non-compression of TiO₂ NP thin film, the overall conversion efficiency is improved over 19.5%. The study proves that under suitable compression pressure the performance of DSSC can be optimized.     

The economic consequences of mortgage debt

Unsurprisingly, a great deal of attention has been paid to the economic consequences of the credit crunch. However, this paper shows that the credit crunch was preceded by a strong build-up of mortgage debt internationally, which, in the long run, could turn out to be more significant than the credit crunch itself. Indeed, the debt build-up suggests that the credit crunch is more likely to reoccur, because highly-indebted households have weaker buffers to withstand unexpected shocks to their incomes or to interest rates. The paper presents a model that can explain the debt build-up and changes to the distribution of debt between existing owners and first-time buyers, which hinders access to home-ownership for the latter, even amongst those households who would be considered as credit-worthy.     

Clutter filters adapted to tissue motion in ultrasound color flow imaging

The quality of ultrasound color flow images is highly dependent on sufficient attenuation of the clutter signals originating from stationary and slowly moving tissue. Without sufficient clutter rejection, the detection of low velocity blood flow will be poor, and the velocity estimates will have a large bias. In some situations, e.g., when imaging the coronary arteries or when the operator moves the probe in search for small vessels, there is considerable movement of tissue. It has been suggested that clutter rejection can be improved by mixing down the signal with an estimate of the mean frequency prior to high pass filtering. In this paper, we compare this algorithm with several other adaptive clutter filtering algorithms using both experimental data and simulations. We found that realistic accelerations of the tissue have a large effect on the clutter rejection. The best results were obtained by mixing down the signal with non-constant phase increments estimated from the signal. This adapted the filter to a possibly accelerated tissue motion and produced a significant improvement in clutter rejection     

CFL-Violating Numerical Schemes for a Two-Fluid Model

In this paper we propose a class of linearly implicit numerical schemes for a two-phase flow model, allowing for violation of the CFL-criterion for all waves. Based on the Weakly Implixit Mixture Flux (WIMF) approach [SIAM J. Sci. Comput., 26 (2005), pp. 1449–1484], we here develop an extension denoted as Strongly Implicit Mixture Flux (SIMF). Whereas the WIMF schemes are restricted by a weak CFL condition which relates time steps to the fluid velocity, the SIMF schemes are able to break the CFL conditions corresponding to both the sonic and advective velocities. The schemes possess some desirable features compared to current industrial pressure-based codes. They allow for sequential updating of the momentum and mass variables on a nonstaggered grid by solving two sparse linear systems. The schemes are conservative in all convective fluxes and consistency between the mass variables and pressure is formally maintained. Numerical experiments are presented to shed light on the inherent differences between the WIMF and SIMF families of schemes. In particular, we demonstrate that the WIMF scheme is able to give an exact resolution of a moving contact discontinuity. The SIMF schemes do not possess the “exact resolution” property of WIMF, however, the ability to take larger time steps can be exploited so that more efficient calculations can be made when accurate resolution of sharp fronts is not essential, e.g. to calculate steady state solutions.     

Sources accounting for alliance and cohesion at three stages in group psychotherapy: Variance component analyses.

This study examined patient, therapist, and group variability accounting for alliance and cohesion over three stages in a sample of 145 patients attending short- and long-term psychodynamic group therapy. G-study variance components were estimated for the 14 sources of variation identifiable by the research design. Results indicated that patient variability represented the strongest clinically relevant contribution to both alliance and cohesion. Therapists were important for alliance at all stages, but for cohesion only in the middle stage. The therapist × group interaction was important to the alliance in early therapy and for cohesion within the two first stages, but this contribution then decreased. Group length did not account for any variability in the process measures. Theoretical implications were discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Design ideas for IT in public spaces

This paper examines the usability issues involved in ticketless travelling with an airport train. The main contribution of this paper is that it describes actual use situations in detail. We show how users’ intentions are difficult to anticipate, unless in explicit communication, e.g., with people whose job it is to help out with using the system. Being conspicuously assisted, however, only aggravates a situation where users usually prefer anonymity. Given a “private in public” type of design, users had little chance of learning from watching others. Moreover, users were quickly annoyed when they struggled with the machine. They seemed to treat it as an agent for the provider rather than an assistant or tool for themselves. At the end of this paper, we outline and illustrate some new design ideas, which we think ought to be considered for future designs of IT in public spaces.     

Digital dysfunctions in primary school: A pilot study

Learning often involves complex cognitive and motorical processes, and while most learners cope adequately with these challenges there are always some that struggle. When new kinds of knowledge are introduced there is a possibility that some learners will find this new knowledge hard to acquire, and thus manifest a dysfunction. Today the new knowledge can be found within the digital domain. Some learners need more time and more efforts to master the different aspects of digital literacy, some of these even need special attention from friends, teachers or others. Is it possible that this group of learners is experiencing some kind of dysfunctions? It is likely to think so, there are a variety of different learning dysfunctions related to many learning domains, and when a new domain is established it would not come as a surprise that a new form of dysfunction is discovered. This article seeks to answer the question: “Do digital dysfunctions exist?” The answer is given as indicators more than as solid proof. In this study a group of 144 pupils is reduced through a triangulation of qualitative and quantitative methods, and ends up with three cases where there are obvious lacks of digital literacy without any obvious reason. The study also deals with definitions on “digital literacy”, and tries to point out what construct the term “digital literacy” in the study material. This construct is then used for measuring digital literacy.