Electrocatalytic Reduction of CO2 to Ethylene by Molecular Cu‐Complex Immobilized on Graphitized Mesoporous Carbon

The electrochemical reduction of carbon dioxide (CO₂) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO₂ to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO₂ to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO₂ in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions.     

Yield optimization for complex reactor systems

For complex reactions, the choice of reactor type is important for attaining optimum product yields. Strategies for specifying reactor types have beenIn this paper, product yield in a Van de Vusse reaction scheme has been studied for a wide range of the rate constants, in a reactor system consisting     

Fast Li+ Transport via Silica Network-Driven Nanochannels in Ionomer-in-Framework for Lithium Metal Batteries

For the development of all-solid-state lithium metal batteries (LMBs), a high-porous silica aerogel (SA)-reinforced single-Li⁺ conducting nanocomposite polymer electrolyte (NPE) is prepared via two-step selective functionalization. The mesoporous SA is introduced as a mechanical framework for NPE as well as a channel for fast lithium cation migration. Two types of monomers containing weak-binding imide anions and Li⁺ cations are synthesized and used to prepare NPEs, where these monomers are grafted in SA to produce SA-based NPEs (SANPEs) as ionomer-in-framework. This hybrid SANPE exhibits high ionic conductivities (≈10⁻³ S cm⁻¹), high modulus (≈10⁵ Pa), high lithium transference number (0.84), and wide electrochemical window (>4.8 V). The resultant SANPE in the lithium symmetric cell possesses long-term cyclic stability without short-circuiting over 800 h under 0.2 mA cm⁻². Furthermore, the LiFePO₄|SANPE|Li solid-state batteries present a high discharge capacity of 167 mAh g⁻¹ at 0.1 C, good rate capability up to 1 C, wide operating temperatures (from −10 to 40 °C), and a stable cycling performance with 97% capacity retention and 100% coulombic efficiency after 75 cycles at 1 C and 25 °C. The SANPE demonstrates a new design principle for solid-state electrolytes, allowing for a perfect complex between inorganic silica and organic polymer, for high-energy-density LMBs.     

Design and analysis of miniaturized all-optical binary to gray code converter using Y-shaped plasmonic waveguide for optical processors

In this paper, an all-optical miniaturized binary to gray code converter is designed and analyzed. The all-optical domain is now an alternative for electronic devices, where performance and speed are the key issues. Code converters are significantly used in digital data transmission in the areas of error detection and correction. Gray code is one of the cyclic codes, where the cyclic shift of each codeword is also a code word. An all-optical XOR gate, realized using a Y-shaped power combiner is used in this design to generate the desired gray code from the given binary code. The insertion loss and extinction ratio parameters are found to be 0.347 dB and 22.26 dB, respectively. The entire simulation is carried out using finite-difference time-domain method. The obtained practical results are verified mathematically using MATLAB.

     

Design,simulation and analysis of RF MEMS capacitive shunt switches with high isolation and low pull-in-voltage

Microsystem Technologies - This paper presents the design a capacitive shunt type RF-MEMS switch with high isolation, high switching speed and low actuation voltage for Ka-band applications. The...     

A comparative dielectric relaxation study of PMN–PT and PMN–PZ ceramics using impedance spectroscopy

AC-impedance spectroscopic studies in the temperature range of 30–400 °C are carried out on solid solutions of lead magnesium niobate (PMN) with lead titanate (PT) and lead zirconate (PZ), both of them in the 65/35 atomic ratio. For PMN–PT this corresponds to the morphotropic phase boundary composition (with normal ferroelectric behaviour), and for PMN–PZ it is near the phase boundary between normal ferroelectric and relaxor ferroelectric compositions. The variation of dielectric permittivity with temperature at different frequencies shows normal ferroelectric and relaxor-like dependence for PMN–PT and PMN–PZ, respectively. Temperature-dependent spectroscopic modulus plots reveal a much broader peak for PMN–PZ compared to that for PMN–PT, which is consistent with the dielectric behaviour. PMN–PT shows nearly ideal Debye behaviour below T_m (the temperature of the permittivity maximum) and the behaviour departs from ideality above T_m, whereas non-ideal Debye behaviour is seen both below and above T_m for PMN–PZ. Complex modulus plots fit well with two depressed semicircles and three depressed semicircles, respectively, for PMN–PT and PMN–PZ. The relaxation observed in the spectroscopic plots around 1 MHz for PMN–PT has been assigned to polarisation relaxation expected for normal-sized domains. No such relaxation could be observed for PMN–PZ around 1 MHz because of the mesoscopic domain sizes.     

A methodology to model the information structure of an organization

The Integrated Computer Aided Manufacturing (ICAM) program of the U.S. Air Force identified a need to better communicate and analyze manufacturing for the people involved in improving productivity. To satisfy that need, the ICAM program developed the IDEF (ICAM Definition) method to address particular characteristics of manufacturing. This IDEF method is equally applicable in analyzing other types of organizations. IDEF comprises three modeling methodologies: function model methodology (IDEF₀), information model methodology (IDEF₁) and dynamics model methodology (IDEF₂). This paper reports on the Information model methodology only. This methodology is used to construct an information model that helps in understanding the structure of information needed to support the functions of an organization.     

Studying grain boundary regions in polycrystalline materials using spherical nano-indentation and orientation imaging microscopy

In this article, we report on the application of our spherical nanoindentation data analysis protocols to study the mechanical response of grain boundary regions in as-cast and 30% deformed polycrystalline Fe–3%Si steel. In particular, we demonstrate that it is possible to investigate the role of grain boundaries in the mechanical deformation of polycrystalline samples by systematically studying the changes in the indentation stress–strain curves as a function of the distance from the grain boundary. Such datasets, when combined with the local crystal lattice orientation information obtained using orientation imaging microscopy, open new avenues for characterizing the mechanical behavior of grain boundaries based on their misorientation angle, dislocation density content near the boundary, and their propensity for dislocation source/sink behavior.     

Large Eddy Simulations of Double-Ruler Electromagnetic Field Effect on Transient Flow During Continuous Casting

Transient flow during nominally steady conditions is responsible for many intermittent defects during the continuous casting of steel. The double-ruler electromagnetic field configuration, or “FC-Mold EMBr,” is popular in commercial slab casting as it provides independent control of the applied static field near the jet and free surface regions of the mold. In the current study, transient flow in a typical commercial caster is simulated in the absence and in the presence of a double-ruler magnetic field, with rulers of equal strengths. Large eddy simulations with the in-house code CU-FLOW resolve the important transient behavior, using grids of over five million cells with a fast parallel solver. In the absence of a magnetic field, a double-roll pattern is observed, with transient unbalanced behavior, high surface velocities (~0.5 m/s), surface vortex formation, and very large surface-level fluctuations (~±12 mm). Applying the magnetic field suppresses the unbalanced behavior, producing a more complex mold flow pattern, but with much lower surface velocities (~0.1 m/s), and a flat surface level with small level fluctuations (<±1 mm). Nail board measurements taken at this commercial caster, in the absence of the field, matched reasonably well with the calculated results, both quantitatively and qualitatively.     

Hydrogen storage in TiO2 functionalized (10, 10) single walled carbon nanotube (SWCNT) – First principles study

Hydrogen storage in titanium dioxide (TiO₂) functionalized (10, 10) armchair single walled carbon nanotube (SWCNT) is investigated through first principle calculations using density functional theory (DFT). This first principles study uses Vienna Ab-initio Simulation Package (VASP) with ultrasoft pseudopotentials and local density approximation (LDA). The necessary benchmark and other systematic calculations were carried out to project the hydrogen storage capability of the designed system. Interestingly, the TiO₂ molecules functionalized on the outer surface of SWCNT do not undergo any dimerization/clustering thus giving excellent stability and usable gravimetric hydrogen storage capacity of 5.7 wt.% and the value nearly fulfills the US DOE target (i.e. 6 wt.%). The band structure and density of states (DOS) plots suggest that the functionalization can lead a way to transform the nature (metallic → semiconducting) of the pristine SWCNT. The nominal values of H₂ storage capacity and binding energies give much hope for using CNT functionalized with TiO₂ as a practical and reversible hydrogen storage medium (HSM).