We study the mechanical and conformational properties of networks of helical polymers with a combination of Monte Carlo simulations based on the Wang-Landau algorithm and the three-chain model. We find that the stress-strain behavior of these networks has novel features not observed in typical networks made of synthetic polymers. In particular, we find that as these networks are stretched they first strengthen, then soften and finally strengthen again. This non-monotonic behavior of the stress correlates with the one of the helical content and is rationalized by the elongation-induced formation and melting of the helical structure of the polymer. We complement these results with a study of other conformational properties of the polymer strands that clarify the molecular mechanisms behind the mechanical behavior of these networks. Finally, we present a qualitative comparison of some of our results with the theoretical ones recently reported by Kutter and Terentjev. 相似文献
Fractions of Elbistan and Seyitomer (Turkish) lignites, extracted with supercritical toluene at 340 °C and 8 MPa, have been separated by solvent extraction and silica-gel chromatography. Analyses by n.m.r. and i.r. spectroscopies and other methods have been combined in structural-analysis schemes to yield information about the average molecule in aromatic extracts. Carbon aromaticities, fa, derived from 22.63 MHz 1H-decoupled pulse Fourier-transform (PFT) 13C-n.m.r. are more widely spread for Elbistan (0.34–0.56) than for Seyitomer (0.40–0.43), and are lower than for supercritical-gas (SCG) products from bituminous coals. 13C-n.m.r. also reveals the presence of aromatic ether-O in polar fractions. Narrow aromatic signals in 100 MHz 1H-n.m.r. spectra suggest the presence of single-aromatic-ring average structures. In the hexane-soluble aromatics, 27% (Elbistan) and 29% (Seyitomer) of the available sites are substituted by alkyI groups, some of which are at least eight carbon atoms long; the hexane-soluble polar and asphaltene/asphaltol fractions contain fewer such groups. 相似文献
The aim of this study was to compare the performance of coagulation, Fenton's oxidation (Fe2+/H2O2) and ozonation for the removal of chemical oxygen demand (COD) and colour from biologically pretreated textile wastewater. FeSO4 and FeCl3 were used as coagulants at varying doses and varying colour removal efficiency was measured. For the Fenton process, COD and colour removal efficiencies were found to be 78% and 95% for the Fenton process, and to be 64% and 71% for the Fenton-like process (Fe3+/H2O2), respectively. Ozonation experiments were conducted at different initial pH values and fixed ozone doses. Ozonation resulted in 43% COD and 97% colour removal whereas these rates increased to 54% and 99% when 5 mg/l hydrogen peroxide was added to the wastewater before ozonation at the same dose. The operating costs of all proposed treatment systems were also evaluated in this study. 相似文献
We present a comprehensive review of the evolutionary design of neural network architectures. This work is motivated by the fact that the success of an Artificial Neural Network (ANN) highly depends on its architecture and among many approaches Evolutionary Computation, which is a set of global-search methods inspired by biological evolution has been proved to be an efficient approach for optimizing neural network structures. Initial attempts for automating architecture design by applying evolutionary approaches start in the late 1980s and have attracted significant interest until today. In this context, we examined the historical progress and analyzed all relevant scientific papers with a special emphasis on how evolutionary computation techniques were adopted and various encoding strategies proposed. We summarized key aspects of methodology, discussed common challenges, and investigated the works in chronological order by dividing the entire timeframe into three periods. The first period covers early works focusing on the optimization of simple ANN architectures with a variety of solutions proposed on chromosome representation. In the second period, the rise of more powerful methods and hybrid approaches were surveyed. In parallel with the recent advances, the last period covers the Deep Learning Era, in which research direction is shifted towards configuring advanced models of deep neural networks. Finally, we propose open problems for future research in the field of neural architecture search and provide insights for fully automated machine learning. Our aim is to provide a complete reference of works in this subject and guide researchers towards promising directions.
In practice, classifiers in an ensemble are not independent. This paper is the continuation of our previous work on ensemble subset selection [A. Ula?, M. Semerci, O.T. Y?ld?z, E. Alpayd?n, Incremental construction of classifier and discriminant ensembles, Information Sciences, 179 (9) (2009) 1298–1318] and has two parts: first, we investigate the effect of four factors on correlation: (i) algorithms used for training, (ii) hyperparameters of the algorithms, (iii) resampled training sets, (iv) input feature subsets. Simulations using 14 classifiers on 38 data sets indicate that hyperparameters and overlapping training sets have higher effect on positive correlation than features and algorithms. Second, we propose postprocessing before fusing using principal component analysis (PCA) to form uncorrelated eigenclassifiers from a set of correlated experts. Combining the information from all classifiers may be better than subset selection where some base classifiers are pruned before combination, because using all allows redundancy. 相似文献
In the literature, there exist statistical tests to compare supervised learning algorithms on multiple data sets in terms of accuracy but they do not always generate an ordering. We propose Multi2Test, a generalization of our previous work, for ordering multiple learning algorithms on multiple data sets from “best” to “worst” where our goodness measure is composed of a prior cost term additional to generalization error. Our simulations show that Multi2Test generates orderings using pairwise tests on error and different types of cost using time and space complexity of the learning algorithms. 相似文献
Bubble formation and stability in the film blowing processing of in situ polymerized and melt-compounded polyamide 6-based layered silicate nanocomposites (LSNs) are correlated to their underlying rheology, structure, and crystallization behavior. The layered silicates enhance melt elasticity, induce γ -form crystallinity, and increase crystallization rates without having any significant effect on the extent of crystallinity. A bubble stability quantification method employed to assess the level of instability during the film blowing process finds the in situ polymerized LSNs to be more stable than PA6, while melt-compounded LSNs do not display such an improved processability. All of the LSN films produced by film blowing possess superior mechanical properties compared to neat nylon 6, despite their relatively rougher film surfaces. 相似文献
Fused deposition modeling (FDM) is one of the most popular additive manufacturing technologies for fabricating prototypes with complex geometry and different materials. However, current commercial FDM machines have the limitations in process reliability and product quality. In order to overcome these limitations and increase the levels of machine intelligence and automation, machine conditions need to be monitored more closely as in closed-loop control systems. In this study, a new method for in situ monitoring of FDM machine conditions is proposed, where acoustic emission (AE) technique is applied. The proposed method allows for the identification of both normal and abnormal states of the machine conditions. The time-domain features of AE hits are used as the indicators. Support vector machines with the radial basis function kernel are applied for state identification. Experimental results show that this new method can potentially serve as a non-intrusive diagnostic and prognostic tool for FDM machine maintenance and process control. 相似文献