Metal Organic Framework-MXene Nanoarchitecture for Fast Responsive and Ultra-Stable Electro-Ionic Artificial Muscles

Electro-ionic soft actuators, capable of continuous deformations replacing non-compliant rigid mechanical components, attract increasing interest in the field of next-generation metaverse interfaces and soft robotics. Here, a novel MXene (Ti₃C₂T_x) electrode anchoring manganese-based 1,3,5-benzenetricarboxylate metal-organic framework (MnBTC) for ultrastable electro-ionic artificial muscles is reported. By a facile supramolecular self-assembly, the Ti₃C₂T_x-MnBTC hybrid nanoarchitecture forms coordinate bond, hydrogen bond, and hydrophilic interaction with the conducting polymer of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), resulting in a mechanically flexible and electro-ionically active electrode. The superior electrical and electrochemical performances of the electrode stem from the synergistic effects between intrinsically hierarchical nanoarchitecture of MnBTC and rapid electron transport behavior of Mxene, leading to fast diffusion and accommodation of ions in the ion-exchangeable membrane. The developed artificial muscle based on Ti₃C₂T_x-MnBTC is found to exhibit high bending displacement (12.5 mm) and ultrafast response time (0.77 s) under a low driving voltage (0.5 V), along with wide frequency response (0.1–10 Hz) and exceptional stability (98% retention at 43,200 s) without any distortion of actuation performance. Furthermore, the designed electro-active artificial muscle is successfully used to demonstrate mimicry of eye motions including eyelid blinking and eyeball movement in a doll.     

An optimal solution for magnetohydrodynamic nanofluid flow over a stretching surface with constant heat flux and zero nanoparticles flux

This article examines the hydromagnetic three-dimensional flow of viscous nanoliquid. A bidirectional linear stretching surface has been used to create the flow. Novel features regarding Brownian motion and thermophoresis have been studied by employing Buongiorno model to examine the slip velocity of nanoparticle. Viscous liquid is electrically conducting subject to uniform applied magnetic field. Problem formulation in boundary-layer region is performed for low magnetic Reynolds number. Simultaneous effects of constant heat flux and zero nanoparticles flux conditions are utilized at boundary. Appropriate transformations correspond to the strongly nonlinear ordinary differential expressions. The resulting nonlinear systems have been solved through the optimal homotopy analysis method. Graphs have been sketched in order to analyze that how the temperature and concentration profiles are affected by various physical parameters. Further the coefficients of skin-friction and heat transfer rate have been numerically computed and discussed. Our findings show that the temperature distribution has a direct relationship with the magnetic parameter. Moreover, the temperature distribution and thermal boundary-layer thickness are higher for hydromagnetic flow in comparison with the hydrodynamic flow.

     

Magnetically and Electrically Responsive Soft Actuator Derived from Ferromagnetic Bimetallic Organic Framework

The advancement in smart devices and soft robotics necessitates the use of multiresponsive soft actuators with high actuation stroke and stable reversibility for their use in real-world applications. Here, this work reports a magnetically and electrically dual responsive soft actuator based on neodymium and iron bimetallic organic frameworks (NdFeMOFs@700). The ferromagnetic NdFeMOFs@700 exhibits a porous carbon structure with excellent magnetization saturation (166.96 emu g⁻¹) which allows its application to a dual functional material in both magnetoactive and electro-ionic actuations. The electro-ionic soft actuator, which is fabricated using NdFeMOFs@700 and PEDOT-PSS, demonstrates 4.5 times higher ionic charge storage capacity (68.21 mF cm⁻²) and has excellent cycle stability compared with the PEDOT-PSS based actuator. Under a low sinusoidal input voltage of 1 V, the dual-responsive actuator displays bending displacement of 15.46 mm and also generates deflection of 10 mm at 50 mT. Present results show that the ferromagnetic bimetallic organic frameworks can open a new way to make dual responsive soft actuators due to the hierarchically porous structures with its high redox activity, superior magnetic properties, and larger electrochemical capacitance. With the NdFeMOFs@700 based soft actuators, walking movement of a starfish robot is demonstrated by applying both the magnetic and electric fields.