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1.
Gladson S. Chrisben Prasad P. Siva Manickam Bhaskar 《Analog Integrated Circuits and Signal Processing》2021,109(3):571-583
Analog Integrated Circuits and Signal Processing - As the 5G era beckons in the world of communication and information technology, there is a surge in demand for battery-operated, mobile wireless... 相似文献
2.
Kalli Sai Bhavani Tummala Anusha Pradeep Kumar Brahman 《International Journal of Hydrogen Energy》2021,46(13):9199-9214
In the present study, we report an eco-friendly and simple route to design and synthesize novel nanocomposite catalyst based on platinum nanoparticles anchored on binary support of graphitic carbon nitride (g-C3N4) and cobalt-metal-organic framework (ZIF-67). For this purpose, ZIF-67 was prepared by precipitation method and g-C3N4 was prepared through thermal polymerization method. Later, ZIF-67 and g-C3N4 were hybridized through sonication to get homogeneous g–C3N4–ZIF-67 nanocomposite support material. Platinum nanoparticles (PtNPs) were uniformly deposited on g–C3N4–ZIF-67 by an electrochemical method. The as-developed nanocatalyst was characterized by morphological, structural and electrochemical techniques. The electrocatalytic activity of PtNPs@g–C3N4–ZIF-67 nanocatalyst towards butanol oxidation was evaluated via CV, CA, LSV and EIS in an alkaline medium. Results revealed that the proposed catalyst showed greatly enhanced electrooxidation of butanol in terms of high magnificent current density, lower oxidation potential, excellent long-term stability, large surface area, low charge transfer resistance and less toxic ability. Enhanced catalytic performance of the proposed catalyst could be ascribed to the synergistic effect of g–C3N4–ZIF-67 nanocomposite and PtNPs. The PtNPs@g–C3N4–ZIF-67 catalyst holds promising potential applications to be used as an anodic electrocatalyst for the development of high-performance alkaline fuel cells. 相似文献
3.
P. Sampath Brijesh Kakarla Raghava Reddy C. Venkata Reddy Nagaraj P. Shetti Raghavendra V. Kulkarni Anjanapura V. Raghu 《化学工程与技术》2020,43(7):1240-1248
Hydrogen fuel is a promising alternative to fossil fuels because of its energy content, clean nature, and fuel efficiency. However, it is not readily available. Most current producion processes are very energy intensive and emit carbon dioxide. Therefore, this article reviews technological options for hydrogen production that are eco-friendly and generate clean hydrogen fuel. Biological methods, such different fermentation processes and photolysis are discussed together with the required substrates and the process efficiency. 相似文献
4.
Mani Balamurugan Hui‐Yun Jeong Venkata Surya Kumar Choutipalli Jung Sug Hong Hongmin Seo Natarajan Saravanan Jun Ho Jang Kang‐Gyu Lee Yoon Ho Lee Sang Won Im Venkatesan Subramanian Sun Hee Kim Ki Tae Nam 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(25)
The electrochemical reduction of carbon dioxide (CO2) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO2 to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO2 to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO2 in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions. 相似文献
5.
6.
M.G. Pujar N. Parvathavarthini Sidhartha S. Jena B.V.R. Tata R.K. Dayal H.S. Khatak 《Journal of Materials Engineering and Performance》2008,17(6):793-801
In the present work 316LN as well as 316 stainless steel (SS) coupons each of dimensions (0.025 × 0.018 × 0.006 m3) in well-polished condition were used as two nominal electrodes which were immersed in the aerated solution of 0.5 M NaCl.
Correlated current and potential electrochemical noise (EN) signals were collected at 1 Hz sampling frequency for 1 h daily
over a period of 30 days. The detrended EN data were used to calculate the noise resistance (R
N) as well as the spectral noise resistance at zero frequency (R
SNo) values and other statistical parameters. To study the nature of pits and distribution of their diameters as well as depths,
extensive observations of the pitted and the blank specimens were carried out using Confocal Laser Scanning Microscopy (CLSM).
The current and the potential records of the two alloys showed distinct differences in their corrosion behavior. It was observed
that within less than 4 h of immersion, 316SS showed signals indicative of unstable pitting and onset of stable pitting was
noticed after 48 h of exposure. However, until about 24 h, 316LN showed just the random signals and unstable pitting was observed
after 28 h. The signals clearly indicated continuous growth of the stable pits in 316SS as against the repassivation of the
unstable pits in 316LN after 7 days exposure. It was observed that R
N values showed a continuous decrease in the case of 316SS, but were quite stable in the case of 316LN over the exposure period.
Concurrent to these observations it was observed that 316SS specimen was extensively pitted. The frequency distributions of
pit diameters as well pit depths were observed to be highest at 10-20 μm and 5-10 μm, respectively. However, pits with as
large as 70-80 μm diameter and as deep as 20-25 μm too were observed. No pits were observed in case of 316LN even after 30 days
of exposure, an observation that corroborates well with the stable R
N values. Thus, in the present investigation, the long-term tests using EN technique coupled with CLSM studies conclusively
prove that many unstable pits initiated in 316SS turn into stable ones resulting in insidious localized corrosion attack whereas
the unstable pits initiated in 316LN get passivated in the simulated coastal environment. 相似文献
7.
I Tamai T Nakanishi K Hayashi T Terao Y Sai T Shiraga K Miyamoto E Takeda H Higashida A Tsuji 《Canadian Metallurgical Quarterly》1997,49(8):796-801
Although recent evidence suggests that certain beta-lactam antibiotics are absorbed via a specific transport mechanism, its nature is unclear. To confirm whether peptide transport in the rat can be largely ascribed to the intestinal oligopeptide transporter PepT1, the transporter has been functionally characterized and its significance in the intestinal absorption of beta-lactam antibiotics was evaluated. For evaluation of transport activity complementary RNA (cRNA) of rat PepT1 was synthesized in-vitro and expressed in Xenopus laevis oocytes. cRNA induced uptake of several beta-lactam antibiotics and the dipeptide [14C]glycylsarcosine; this was specifically inhibited by various dipeptides and tripeptides but not by their constituent amino acids or by tetra- or pentapeptides. The transport activity of PepT1 for beta-lactam antibiotics correlated well with their in-vivo intestinal transport and absorption. Furthermore, mutual inhibitory effects on uptake were observed between glyclsarcosine and beta-lactam antibiotics. Hybrid depletion of the functional expression of rat PepT1 in oocytes injected with rat intestinal epithelial total mRNA was studied using an antisense oligonucleotide corresponding to the 5'-coding region of PepT1. In oocytes injected with rat mRNA pre-hybridized with the antisense oligonucleotide against rat PepT1, the uptake of [14C]glycylsarcosine was almost completely abolished, whereas its uptake was not influenced by a sense oligonucleotide for the same region of PepT1. Similarly, the uptake of beta-lactam antibiotics was also reduced by the antisense oligonucleotide against rat PepT1. These results demonstrate that the intestinal proton-coupled oligopeptide transporter PepT1 plays a predominant role in the carrier-mediated intestinal absorption of beta-lactam antibiotics and native oligopeptides in the rat. 相似文献
8.
V Douzdjian SS Bhaskar PK Baliga KK Gugliuzza PR Rajagopalan 《Canadian Metallurgical Quarterly》1997,20(8):1310-1314
OBJECTIVE: The racial impact on graft outcome is not well defined in diabetic recipients. The purpose of this study is to analyze our experience with kidney-alone (A) and kidney-pancreas (KP) transplantation in type 1 diabetic recipients and evaluate the impact of racial disparity on outcome. RESEARCH DESIGN AND METHODS: The records of 217 kidney transplants (118 KA, 99 KP) performed on type 1 diabetic patients between 1985 and 1995 at the Medical University of South Carolina and the University of Texas Medical Branch were reviewed. RESULTS: A total of 53 (31%) white patients and 15 (33%) black patients experienced at least one episode of biopsy-proven acute rejection of the renal graft (NS). Patient survival at 1, 2, and 5 years was similar in white (92, 87, 69%) and black (91, 91, 69%) patients (NS). Kidney graft survival at 1, 2, and 5 years in the KA group was 72, 62, and 42% in blacks, compared with 79, 76, and 53% in whites (NS). Kidney graft survival at 1, 2, and 5 years in the KP group was 92, 92, and 74% in blacks, compared with 83, 77, and 58% in whites (NS). Pancreas graft survival at 1, 2, and 5 years was 81, 81, and 81% in blacks, compared with 81, 75, and 62% in whites (NS). Cox regression analysis revealed that donor age > or = 40 years increased the risk of renal graft failure 6.2-fold (P = 0.0001), whereas the addition of a pancreas transplant to a kidney and a living-related transplant decreased the risk of failure of the kidney graft 0.2 (P = 0.005) and 0.1 times (P = 0.005). CONCLUSIONS: Our results suggest that when compared with whites, there may be a trend toward an improved kidney and pancreas graft outcome in blacks undergoing KP transplants. These findings suggest that diabetes may override the risk factors that account for the pronounced disparity in outcome observed between nondiabetic white and black recipients. 相似文献
9.
The nature of localized deformation that occurs both in metal and polymer samples was examined under uniaxial tension by measuring the complete strain distribution of a deforming specimen at a constant crosshead speed. The development of localized deformation in 6111-T6 aluminium alloy and polycarbonate was recorded along both the longitudinal and lateral directions as the specimen was stretched until it fractured. Determination of the true strain at various points on the tensile specimens was made by using an automated, vision-based image processing method using a CCD camera to measure the deformation of a silk-screened grid on the specimen. This vision-based system produced accurate results, allowing for careful analysis of the entire necking process from initiation to propagation. It has been observed that localized deformation develops principally in the longitudinal direction. The major and minor true strain are uniform for the uniform section specimens, however, these strains peak in the centre of the hourglass specimens in the longitudinal direction for both materials. For both specimen geometries, the major strain is uniform while the minor strain is non-uniform in the lateral direction. The longitudinal true strain to lateral true strain ratio remains at about two for the uniform section specimens, but this ratio increases to between 3 and 5 for the hourglass specimens, due to the constraining effect of the sample geometry. 相似文献
10.
Solutions, within the framework of linear uncoupled thermoelasticity, are presented for certain problems of flexure of composite laminates. Benchmark numerical results, useful for the validation or otherwise of approximate laminate models, are tabulated. Finally, these results are used to examine the accuracy of the classical lamination theory based on Kirchhoff's hypothesis. 相似文献