Structure and properties of polyimide‐bonded magnets processed from prepolymers based on diacetyl derivatives of aromatic diamines and dianhydrides

We report a novel method of polyimide (PI) synthesis from prepolymers based on dianhydrides and diacetyl derivatives of aromatic diamines that facilitate the preparation of a melt processable mixture at 300 ± 10°C of the prepolymer and magnetic Nd‐Fe‐B alloy to provide PI‐bonded magnets with enhanced properties. It is shown that chemical structure of the prepolymers strongly influences viscosity behavior via crystallization of the oligoimide in the melt, leading to formation of PI with rigid‐rod like structure. This structural ordering of the prepolymers based on diacetyl derivative of diamine used in this study, if not controlled, leads to exponential increase of melt viscosity with time, making it practically impossible to prepare melt processable mixture of the magnetic particles and the PI prepolymers at elevated temperatures. The results obtained demonstrate that appropriate dianhydrides and diacetyl derivatives of diamines that do not lead to crystallization of oligoimides in prepolymer mixture can be used under controlled processing conditions to prepare melt‐processable PI‐bonded magnets containing rigid‐rod like PI structure that significantly increases thermal stability of the magnets. The temperature dependencies of the magnetic properties of the PI‐bonded magnets under conditions that they are likely to encounter during their service life were found to be remarkably similar to that of commercial thermoplastic magnets such as injection‐molded nylon magnets. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 478–485, 2006     

Viscosity reduction of isotonic solutions of the photosensitizer TPCS2a by cyclodextrin complexation

Meso-tetraphenyl chlorin disulphonate (TPCS_2a) is a photosensitizer (PS) particularly developed and patented for use in the technology of photochemical internalization (PCI) against cancer. TPCS_2a is known to aggregate in aqueous media even at low concentrations (≥0.1?µM) and to form a high-viscosity network at clinically relevant concentrations (mM). The aim of this work was to evaluate the effect of two hydroxypropylated cyclodextrin derivatives of beta and gamma type, respectively i.e. HPβCD and HPγCD, on the aggregation and solubilization of TPCS_2a in isotonic solutions. Samples containing micromolar concentrations of TPCS_2a were studied spectrophotometrically, while samples containing a clinical relevant concentration (10?mM?=?9?mg/ml) of TPCS_2a were evaluated by dynamic viscosity measurements. HPβCD was determined to be a more suitable solubilizer of TPCS_2a than HPγCD in aqueous media both in the absence and presence of salt. The complexation stoichiometry between TPCS_2a/HPβCD at micromolar to millimolar concentrations of TPCS_2a was determined to be 1:3 and 1:2 in the absence and presence of isotonic NaCl, respectively. The network of TPCS_2a (10?mM) was broken down in the presence of 3% w/v (=?20?mM) HPβCD, i.e. a 1:2 molar ratio between TPCS_2a and the cyclodextrin. Formation of the inclusion complex resulted in low viscosity samples both in water and in the presence of isotonic NaCl or phosphate buffered saline (PBS) at 25?°C and 37?°C.     

Phenols as defensive secretion in a Malayan cockroach,Archiblatta hoeveni vollenhoven

A sternal abdominal defensive gland in adults of the Malayan cockroachArchiblatta hoeveni is described. It producesp-cresol and as a minor compound, phenol. When the animals are attacked, they eject the secretion as a spray that can be aimed in the direction of, the stimulus. The position, morphology, and chemistry of the gland support the taxonomic position ofArchiblatta within the Blattoidea.     

End-to-end delay margin balancing approach for routing in multi-class networks

This paper presents Quality of Service (QoS) based routing and priority class assignment algorithms. It introduces an end-to-end delay margin balancing approach to routing, and uses it to formulate a nonlinear optimization problem. In a single-class network, the formulation is shown to be convex; however in a multi-class priority network, it is only convex within specific regions, and is infeasible otherwise. A centralized off-line computation technique is proposed to calculate both the route configuration and end-to-end priority assignment. A gradient-based solution in the convex region and a heuristic to overcome the multi-class discontinuity are derived. An approximation of the optimization problem is developed for on-line distributed processing is then presented. Using the approximation, arriving traffic flows can use vector routing tables to search for routes. Compared with minimum-hop, minimum-delay, and min-interference routing algorithms, the proposed approach enables the single-class network to accommodate more users of different end-to-end delay requirements. In a multi-class priority network, results show that using the objective function to combine route and priority class assignment further increases the supportable network traffic volume. Mohamed Ashour received his B.Sc. (1991) and M.Sc. (1997) in Electrical Engineering from Ain Shams University, Cairo, Egypt. He worked for Hughes and General Dynamics as a Telecommunications Engineer. Currently, he is a Ph.D. Candidate in the Department of Electrical and Computer Engineering of McGill University, Montreal, Quebec, Canada. His current area of research is focused on traffic engineering, routing, and QoS provisioning in DiffServ and MPLS Networks. He is also interested in multi-class queuing analysis of long-range traffic, and QoS provisioning in ad hoc networks and satellite communications. Tho Le-Ngoc obtained his B. Eng. (with Distinction) in Electrical Engineering in 1976, his M.Eng. in Microprocessor Applications in 1978 from McGill University, Montreal, and his Ph.D. in Digital Communications 1983 from the University of Ottawa, Canada. During 1977–1982, he was with Spar Aerospace Limited as a Design Engineer and then a Senior Design Engineer, involved in the development and design of the microprocessor-based controller of Canadarm (of the Space Shuttle), and SCPC/FM, SCPC/PSK, TDMA satellite communications systems. During 1982–1985, he was an Engineering Manager of the Radio Group in the Department of Development Engineering of SRTelecom Inc., developed the new point-to-multipoint DA-TDMA/TDM Subscriber Radio System SR500. He was the System Architect of this first digital point-to-multipoint wireless TDMA system. During 1985–2000, he was a Professor the Department of Electrical and Computer Engineering of Concordia University. Since 2000, he has been with the Department of Electrical and Computer Engineering of McGill University. His research interest is in the area of broadband digital communications with a special emphasis on Modulation, Coding, and Multiple-Access Techniques. He is a Senior Member of the Ordre des Ingénieur du Quebec, a Fellow of the Institute of Electrical and Electronics Engineers (IEEE), a Fellow of the Engineering Institute of Canada (EIC), and a Fellow of the Canadian Academy of Engineering (CAE). He is the recipient of the 2004 Canadian Award in Telecommunications Research, and recipient of the IEEE Canada Fessenden Award 2005.     

MMPP models for multimedia traffic

The paper presents a study on the use of Markov‐Modulated Poisson Processes (MMPP's) for characterizing multimedia traffic with short‐term and long‐term correlation. The applicability of the 2‐state MMPP and a refined moment‐based parameter‐matching technique to model an arbitrary ATM traffic stream in evaluating its queueing performance are examined by simulation. Following a discussion on the limitation of the 2‐state MMPP model, a model using a superposition of N homogeneous 2‐state MMPP to characterize bursty multimedia traffic is presented. The proposed model requires only five parameters which can be estimated from the samples of the traffic counting process by using a pdf‐based matching technique. The introduced pdf‐based parameter‐matching procedure uses the probability density function of the arrival rate and the IDC curve of the traffic samples. An approximation for the probability of loss in MMPP/D/1 queues is also obtained. The versatility and accuracy of the proposed model to characterize bursty multimedia traffic are shown by several case studies and test results. This revised version was published online in June 2006 with corrections to the Cover Date.     

Diversity Analysis of Relay Selection Schemes for Two-Way Wireless Relay Networks

One-way wireless relay networks have recently received a lot of attention due to their ability to provide spatial diversity in fading wireless environment. Moreover, performing single-relay selection is a very attractive method due to its cost effective implementation and superior performance. However, one-way relay networks with the half-duplex signalling suffer from a spectral efficiency loss. To overcome such a drawback, two-way wireless relay networks have been proposed and these are also the networks considered in this paper. The paper analyzes the diversity orders of various relay selection schemes, including the best-relay selection, best-worse-channel selection, and maximum-harmonic-mean selection. The analysis is done for the amplify-and-forward protocol and under the two-step and three-step transmission procedures. In particular, it is shown that full diversity orders of R and R + 1 can be achieved in a R-relay wireless network with the two-step and three-step procedures, respectively. Numerical and simulation results are provided to verify our analysis.     

Performance analysis of M-PAM signaling with Tomlinson-Harashima precoding over ISI channels

An analytical method is developed to evaluate the symbol error probability of multilevel pulse amplitude modulation system using Tomlinson-Harashima precoding over inter-symbol interference channels. Analytical and simulation results are in an excellent agreement for different values of M.     

Outage Probability with Correlated Lognormal Interferers using Log Shifted Gamma Approximation

The computation of outage probability in cellular radio system has been extensively studied. The Signal-to-Interference-plus-Noise Ratio (SINR) distribution involves the sum of lognormal distributions due to dominant effect of shadowing in both the signal and interference components. Since no closed-form expression can be found for the sum of lognormal distributions, many approximation methods and bounds were proposed in the past. In this paper, Log Shifted Gamma (LSG) approximation is proposed to calculate the sum of correlated lognormal random variables (RVs), hence the outage probability, accurately with a wide range of dB spreads, number of interferers M, correlation coefficients r among interference components, and noise power N. Overall, LSG approximation shows consistent accuracy due to its flexibility over the classical lognormal approximation, especially with small correlation coefficients r and/or large dB spreads.     

Performance evaluation of a switch using priority-based dynamic capacity allocation scheme

Performance-analysis of a switching system using priority-based dynamic capacity allocation is presented. The system provides connectivity between a number of point-to-multipoint communication access clusters. The scheduling of traffic transmission at each access cluster is based on a priority scheme with priority given to real-time (rt) traffic over nonreal-time (nrt) traffic. An analytical model is developed to evaluate the covariance functions of both rt and nrt traffic arriving at the output ports. Aggregate traffic arrival streams are approximated to 2-state Markov-modulated Poisson processes (MMPPs) by matching their statistical characteristics. Analytical and simulation results on performance of an example 4 /spl times/ 4 switch for different traffic loads are discussed.     

A novel tunable gain equalizer based on a long-period fiber grating written by high-frequency CO/sub 2/ laser pulses

A novel tunable gain equalizer based on the long-period fiber grating (LPFG) induced by high-frequency CO/sub 2/ laser pulses is demonstrated, for the first time, to our knowledge. Both the resonant wavelength and the resonant peak amplitude of the novel LPFG have a good linearity with temperature and transverse load, respectively. The wavelength and the peak amplitude of the gain equalizer can be tuned by the means of adjusting temperature and transverse load independently, showing that this tunable equalizer is a practical approach to realizing dynamic gain equalization in erbium-doped fiber amplifier systems.