Selective Coating of SnS on the Bio‐Inspired Moth‐Eye Patterned PEDOT:PSS Polymer Films

A new strategy for the selective coating of tin sulfide (SnS) on the surface of moth‐eye patterned (MEP) conducting polymer film is studied by considering the optical properties of the antireflective moth‐eye pattern and flexibility of polymer films. The semiconductor SnS is selectively coated on the surface of MEP microdomes of poly(3,4‐ethylenedioxythiophene) poly(styrene‐sulfonate) (PEDOT:PSS) film. The SnS coated MEP film is obtained by using pore selectively SnS thin layer functionalized polystyrene honeycomb‐patterned porous (HCP) film as a template. Aqueous PEDOT:PSS solution is poured on the SnS functionalized HCP films and detached for the fabrication of SnS coated MEP films. The films show a satisfactory photo‐responsive property under solar stimulated light illumination due to the antireflective MEP structure of PEDOT film and homogenous SnS coating on the surface of the conducting polymer.     

Evaluating the mixing performance of a ribbon blender

This paper investigates the effects of processing and equipment parameters of a ribbon blender (i.e. loading method of lubricant, fill level, blade speed and blade design) on magnesium stearate homogeneity. A core sampling technique is used to obtain at least one hundred samples per sampling event, which are extracted throughout the blender and yield a thorough characterization of the entire bed. The results presented here can be used as a guideline to develop appropriate blending processes and characterization protocols for ribbon blenders.     

Coexisting static and flowing regions in a centrifuging granular heap

We report an unexpectedly rich variety of new flow patterns on a granular heap that is centrifuged so as to simulate a reduction in gravity. These surface patterns exhibit coexisting static and flowing regions that depend strongly on centrifugal stress, but surprisingly not on mass flow rate. A discrete cellular automata model reproduces some of the patterning features and indicates that subsurface jamming may precipitate the formation of localized frozen patterns on the surface. This model provides insights into the mechanics of granular flows under controlled stress environment and jammed-to-flowing transitions in granular media.     

High voltage electrophoresis of amino acids in urine containing ampicillin

Analysis of amino acids is complicated by treatment with ampicillin. High voltage electrophoresis, which is convenient for the qualitative assessment of metabolic diseases, yields smears of ampicillin that mask the bands of citrulline, homocitrulline, phenylalanine, cystine, and homocystine. The addition of penicillinase prior to high voltage electrophoresis eliminates ampicillin and other penicillins and reveals these key amino acids.     

Extending the Kernighan/Lin Heuristic for Hardware and Software Functional Partitioning

The Kernighan/Lin graph partitioning heuristic, also known as min-cut or group migration, has been extended over several decades very successfully for circuit partitioning. Those extensions customized the heuristic and its associated data structure to rapidly compute the minimum-cut metric central to circuit partitioning; as such, those extensions are not directly applicable to other problems. In this paper, we extend the heuristic for functional partitioning, which in turn can solve the much investigated codesign problem of partitioning a system's coarse-grained functions among hardware and software components. The key extension customizes the heuristic and data structure to rapidly compute execution-time and communication metrics, crucial to hardware and software partitioning, and leads to near-linear time-complexity and excellent resulting quality. Another extension uses a new criteria for terminating the heuristic, eliminating time-consuming and unnecessary fine-tuning of a partition. Our experiments demonstrate extremely fast execution times (just a few seconds) with results matched only by the slower simulated annealing heuristic, meaning that the extended Kernighan/Lin heuristic will likely prove hard to beat for hardware and software functional partitioning.     

On the evaluation of the J-integral by a plastic crack tip element

Two crack tip elements are formulated for a stationary, mode I plastic crack in planar structures using hybrid assumed stress approach, based on the secant modulus and the Newton-Raphson schemes, respectively. The stress distribution in the crack tip element is assumed to be the HRR field superimposed by the regular polynomial terms. The formulated (hybrid) crack tip elements are compatible with the isoparametric element so that they can be used conveniently along with the conventional displacement-based finite elements. The intensity of the HRR stress field, the J-integral, is determined directly from the finite element equations together with the nodal displacements. The dominance of the HRR stress field at the crack tip is pertinent to the present approach, which depends on geometry and loading conditions. Since the J-integral is globally path-independent for nonlinear elastic materials (deformation plasticity model), in order to assess the accuracy and efficiency of the methodology as compared to the contour integration approach, numerical studies of common plane-stress cracked configurations are performed for these materials. The results indicate that for a sufficiently small crack tip element size, J from the present approach correlates well, within 6 percent difference, with that from the contour integration for a wide range of material hardening coefficients if the HRR zone exists at the crack tip. These highly accurate results for J from the crack tip stresses could not be achieved without using (newly) modified variational principles and a refined numerical technique. It should be emphasized that the present methodology also can be applied to cracks in J ₂ flow materials under HRR dominance. In such case, the J integral may not be globally path independent, and hence it now must be determined from the stress and strain fields near the crack tip.     

APPLICATION OF THE CONSTANT MOLAR FLOW METHOD IN THE STUDY OF MASS TRANSFER OF GASES AND VAPORS IN BIDISPERSE STRUCTURED SOLIDS

In this paper, we provide exact analytical solutions for a new method of constant molar flow of pure gas into a reservoir containing solid adsorbents having a bidispersed structure, such as zeolite, activated carbon and alumina. Depending on the diffusion mechanism, two models are proposed under the isothermal conditions and linear isotherm. One is applicable to zeolite, and the other for alumina and activated carbon. The solutions of these two models are in the form of an infinite series, and its eigenvalues are determined from a transcendental equation. This transcendental equation is such that the eigenvalues are lumped into infinite but countable groups, and in each group there are infinite but countable eigenvalues. The dominant eigenvalues are generally the first ten to thirty eigenvalues (depending on the value of time at which the series is evaluated) in each group. The pressure response of the reservoir is a function of time as the result of the introduction of adsorbate into the reservoir, and as time is sufficiently large it asymptotes to a straight line, of which the slope is a function of the equilibrium parameters only and the intercept is found to be an explicit function of the equilibrium parameters as well as the diffusivities in the macropore and micropore.     

Enhanced Dynamic Authentication Scheme (EDAS)

With non-stop growth in network environments, communication security is necessary. A strong protocol guarantees that users and service providers are secure against many kinds of attacks, such as impersonation and replay attack. Sood et al. proposed an authentication scheme based on dynamic identity to prevent transactions from being intercepted by malicious users. Although they claimed that their scheme has advantages over previous schemes with the same approach, we prove that their scheme is vulnerable to impersonation attack and stolen verification attack, and can be affected by clock synchronization. Therefore we propose a novel authentication scheme to enhance security and overcome limitations existing in Sood’s scheme. Our security analysis shows that our proposed method can efficiently resist known types of attacks. Experimental results also show that the method can be implemented and processed in real-time thus applicable for not only regular computers but also mobile devices.     

Segregation in granular materials and the direct measurement of surface forces using atomic force microscopy

It is known that one of the dominant forces controlling the macroscopic motion of particles is the cohesive force due to the presence of liquid bridges between particles. In a mixing process, this force directly impacts the degree of homogeneity achievable by the system. The work presented here provides a quantitative analysis of this relationship through concurrent direct measurements of surface forces due to moisture and blending/segregation experiments. Atomic force microscopy (AFM) was employed to measure the force required to remove the AFM's cantilever from the surface of a glass bead with varying degrees of surface moisture. Corresponding blending/segregation experiments were performed using the same materials and conditions to develop a correlation between the interparticle forces due to the liquid layer and the final state of a mixing process. The extent to which greater moisture content increased the interparticle surface forces was quantified, and it was observed that segregation decreases proportionately to increases in surface forces.