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Text document clustering is used to separate a collection of documents into several clusters by allowing the documents in a cluster to be substantially similar. The documents in one cluster are distinct from documents in other clusters. The high-dimensional sparse document term matrix reduces the clustering process efficiency. This study proposes a new way of clustering documents using domain ontology and WordNet ontology. The main objective of this work is to increase cluster output quality. This work aims to investigate and examine the method of selecting feature dimensions to minimize the features of the document name matrix. The sports documents are clustered using conventional K-Means with the dimension reduction features selection process and density-based clustering. A novel approach named ontology-based document clustering is proposed for grouping the text documents. Three critical steps were used in order to develop this technique. The initial step for an ontology-based clustering approach starts with data pre-processing, and the characteristics of the DR method are reduced with the Info-Gain collection. The documents are clustered using two clustering methods: K-Means and Density-Based clustering with DR Feature Selection Process. These methods validate the findings of ontology-based clustering, and this study compared them using the measurement metrics. The second step of this study examines the sports field ontology development and describes the principles and relationship of the terms using sports-related documents. The semantic web rational process is used to test the ontology for validation purposes. An algorithm for the synonym retrieval of the sports domain ontology terms has been proposed and implemented. The retrieved terms from the documents and sport ontology concepts are mapped to the retrieved synonym set words from the WorldNet ontology. The suggested technique is based on synonyms of mapped concepts. The proposed ontology approach employs the reduced feature set in order to clustering the text documents. The results are compared with two traditional approaches on two datasets. The proposed ontology-based clustering approach is found to be effective in clustering the documents with high precision, recall, and accuracy. In addition, this study also compared the different RDF serialization formats for sports ontology.

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The growing interest in low-temperature direct ammonia fuel cells (DAFCs) arises from the utilization of a carbon-neutral ammonia source; however, DAFCs encounter significant electrode overpotentials due to the substantial energy barrier of the *NH2 to *NH dehydrogenation, compounded by the facile deactivation by *N on the Pt surface. In this work, a unique catalyst, Pt4Ir@AlOOH/NGr i.e., Pt4Ir/ANGr, is introduced composed of PtIr alloy nanoparticles controllably decorated on the pseudo-boehmite phase of AlOOH-supported nitrogen-doped reduced graphene (AlOOH/NGr) composite, synthesized via the polyol reduction method. The detailed studies on the structural and electronic properties of the catalyst by XAS and VB-XPS reveal the possible electronic modulations. The optimized Pt4Ir/ANGr composition exhibits a significantly improved onset potential and mass activity for AOR. The DFT study confirms the OHad species spillover by AlOOH and Pt4Ir (100) facilitates the conversion of the *NH2 to *NH with minimal energy barriers. Finally, testing of DAFC at the system level using a membrane electrode assembly (MEA) with Pt4Ir/ANGr as the anode catalyst, demonstrating the suitability of the catalyst for its practical applications. This study thus uncovers the potential of the Pt4Ir catalyst in synergy with ANGr, largely addressing the challenges in hydrogen transportation, storage, and safety within DAFCs.  相似文献   
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Fine control over the graphitization level of carbonized nanostructures can play a strategic role in tuning the crystallization of supported nanocatalysts, thereby modulating the kinetics of catalysis. However, realizing the synergistic interplay of graphitization-tunable support and supported catalysts poses a significant challenge. This study proposes a current pulse-induced ultrafast strategy for developing MOF-derived graphitic nano-leaves (GNL) and supported ultrafine ruthenium nanoclusters exhibiting selective crystallization states depending on the tunable graphitization level of GNL. The resulting ultrafine (≈0.7 nm) amorphous-ruthenium nanoclusters linked with GNL (a-Ru@GNL500) exhibit state-of-the-art performance in the hydrogen evolution reaction (HER), requiring very low overpotentials of only 23.0 and 285.0 mV to achieve current densities of 10  and 500 mA cm−2, respectively. Furthermore, a-Ru@GNL500 demonstrates exceptional operational stability for 100 h under high HER currents of 200 and 400 mA cm−2. Density functional theory reveals that the unique electronic structure of a-Ru and the cooperative effect of cobalt embedded in the graphitic layer lower the occupancy of the antibonding orbital, resulting in an accelerated HER process. Additionally, the unique electronic structure, highly conducting GNL, and efficient bubble release dynamics of super-aerophobic a-Ru@GNL500 contribute to reduced overpotentials, particularly at high HER current densities.  相似文献   
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