Fine Purification of Monoisotopic Silanes 28SiH4 , 29SiH4 , and 30SiH4 via Distillation

High-purity isotopically enriched (99.98% ²⁸Si, 99.57% ²⁹Si, and 99.83% ³⁰Si) silane samples are prepared for the first time. The total hydrocarbon content of the samples is no higher than 0.1–0.3 ppm. The concentration of electroactive impurities in the silicon prepared from the purified monoisotopic silane is below 10¹⁵ cm^–3.     

New Refractories Developed by the Ukrainian Research Institute of Refractories Named after A.S. Berezhnoy

The article gives an introduction to the Ukrainian Research Institute of Refractories and especially its R D and refractory products for the industries of iron and steel,nonferrous,glass and chemistry etc.     

Transformation of Simulink models to IEC 61499 Function Blocks for verification of distributed control systems

In this paper, a new model-based engineering approach is introduced by bridging MATLAB Simulink with IEC61499 Function Block models. This is achieved by a transformation between the two block-diagram languages. The transformation supported by the developed tools sets the cornerstone of the verification and validation framework for IEC 61499 Function Blocks in closed-loop with the models of the plant. The framework also paves the way to running distributed simulations of complex hybrid (i.e., continuous-discrete) closed-loop plant-controller systems and building complex models using the efficient object instantiation techniques of IEC 61499.     

The Influence of the Size of the Unit Cell on the Physical and Mechanical Properties of Samples with the Schwartz Primitive Topology

Glass Physics and Chemistry - The aim of this study is to establish the dependence of the mechanical strength of products with the geometry of the Schwarz P-surface on the number and size of unit...     

Structurally Determined Inequality Constraints on Correlations in the Cycle of Linear Dependencies

Several simple inequality constraints on correlations in a rhombus-like causal model (structured as a cycle with one collider) are formulated and proved. These constraints follow from the linearity and Markov properties of the model. The presented inequalities are specific to the basic model and are incorrect for alternative models that differ in Markov properties due to the presence of an additional edge (connection). The plausibility of the violation of these inequalities in alternative models is evaluated by stochastic simulation. It is shown that the presented inequalities are useful for model verification under partial observability.     

Preparation of weakly agglomerated yttrium aluminum garnet powders by burning a mixture of yttrium aluminum hydroxynitrates, urea, and acetic acid

We have optimized the composition of a mixture of aluminum yttrium hydroxynitrates, urea, and acetic acid for the self-propagating high-temperature synthesis of yttrium aluminum garnet (YAG) powder. The powder prepared in this way offers a low degree of agglomeration, and the ceramic produced from it has a low carbon content. A technique has been proposed for carbon determination in YAG ceramics through gas chromatographic analysis of the gaseous products of carbide hydrolysis after the dissolution of the ceramic in pyrophosphoric acid.     

Nano-Blast Synthesis of Nano-size CeO2–Gd2O3 Powders

CeCl₃·7H₂O and GdCl₃·6H₂O that were dissolved in water were precipitated with urea (NH₂CONH₂) to produce matrix agglomerates for three-component nano-reactors. Mixing hexamethylenetetramine with dilute nitric acid resulted in the formation of well-dispersed nano-particles of cyclotrimetilene trinitramine (C₃H₆N₆O₆) (RDX) in the solvent. Nano-reactors were produced by impregnating the nano-C₃H₆N₆O₆ into the matrix agglomerates of an intermediate complex of cerium and gadolinium compounds. Blast initiation of the C₃H₆N₆O₆ resulted in extremely rapid detonation and gaseous products formation at temperatures of 2000°–5000°C, which were compressed into a volume nearly equal to the initial volume of each RDX nano-particle. Multiple "nano-blasts" occurred in the volume of each nano-reactor. The impact of the blast waves led to fragmentation of the surrounding matter. The evolution of a large volume of gaseous products dissipated the heat of the process and limited temperature increase, thus reducing the possibility of local sintering among the primary particles. The short-term high temperature generated during the blasts enhanced the solid solubility of the metal oxides. Uniform aggregates of 22∼74 nm consisting of 6∼14 nm crystallites of gadolinia in ceria solid solution were synthesized.     

Low-Temperature Processing and Mechanical Properties of Zirconia and Zirconia–Alumina Nanoceramics

The 1.5- to 3-mol%-Y₂O₃-stabilized tetragonal ZrO₂ (Y-TZP) and Al₂O₃/Y-TZP nanocomposite ceramics with 1 to 5 wt% of alumina were produced by a colloidal technique and low-temperature sintering. The influence of the ceramic processing conditions, resulting density, microstructure, and the alumina content on the hardness and toughness were determined. The densification of the zirconia (Y-TZP) ceramic at low temperatures was possible only when a highly uniform packing of the nanoaggregates was achieved in the green compacts. The bulk nanostructured 3-mol%-yttria-stabilized zirconia ceramic with an average grain size of 112 nm was shown to reach a hardness of 12.2 GPa and a fracture toughness of 9.3 MPa·m^1/2. The addition of alumina allowed the sintering process to be intensified. A nanograined bulk alumina/zirconia composite ceramic with an average grain size of 94 nm was obtained, and the hardness increased to 16.2 GPa. Nanograined tetragonal zirconia ceramics with a reduced yttria-stabilizer content were shown to reach fracture toughnesses between 12.6–14.8 MPa·m^1/2 (2Y-TZP) and 11.9–13.9 MPa·m^1/2 (1.5Y-TZP).