Premixed metal fibre burners based on a Pd catalyst

As an alternative to previously developed catalytic FeCrAlloy fibre mat burners based on perovskite catalysts, new catalytic burners have been developed based on Pd catalyst on lantana-stabilised Al₂O₃ and different fibre structures (NIT100A, NIT100S and NIT200S by ACOTECH NV). All development steps are considered, shifting from catalyst preparation (based on combustion synthesis of γ-Al₂O₃) to the optimisation of lantana and Pd loadings, from the definitions of the best catalyst-deposition conditions (washcoating) to the catalytic burners performances, determined in an ad hoc developed combustion chamber. The results show almost half pollutants emissions and better performance compared to various non-catalytic counterparts, especially as far as CO and NO_x emissions are concerned. Some flame instability problems were though registered, especially for one of the catalytic burner mattresses employed, at low specific power inputs and excesses of air (<375 kW/m² and <12%, respectively). Further, PdO/Pd transition is shown to influence the dynamic behaviour of the catalytic burners.     

Dental caries in nineteenth century upper Canada

This study examines the presence of dental caries in a large sample of adult skeletons from the 19th century cemetery of St. Thomas' Anglican Church in Belleville, Ontario. The cemetery was used from 1821 to 1874. Caries prevalence and frequencies of diseased and missing teeth were calculated both by observing summary statistics of individual rates and by the total sample of teeth. Postmortem tooth loss is low in this sample and antemortem tooth loss is highest in first mandibular molars, all other molars and then premolars. Age at death, but not sex, was found to be significantly related to the overall Caries Rate while both age and sex were significantly associated with the Diseased-Missing Index. The increase in diseased and missing teeth in older individuals is expected while the sex difference is not explained by simple dietary factors. When compared to reports on British and American samples, caries and antemortem tooth loss in the St. Thomas' sample is most similar to a pre-1850 British group and higher than American samples. Although there is undoubtedly a complex of factors contributing to caries prevalence in this sample, more data are required from large historic samples, particularly from the American northeast and late 19th century Britain, to have a clearer understanding of the influence of diet, cultural, and environmental factors affecting caries rates in historic populations.     

On the evolution of homogeneous two-robot teams: clonal versus aclonal approaches

This study compares two different evolutionary approaches (clonal and aclonal) to the design of homogeneous two-robot teams (i.e. teams of morphologically identical agents with identical controllers) in a task that requires the agents to specialise to different roles. The two approaches differ mainly in the way teams are formed during evolution. In the clonal approach, a team is formed from a single genotype within one population of genotypes. In the aclonal approach, a team is formed from multiple genotypes within one population of genotypes. In both cases, the goal is the synthesis of individual generalist controllers capable of integrating role execution and role allocation mechanisms for a team of homogeneous robots. Our results diverge from those illustrated in a similar comparative study, which supports the superiority of the aclonal versus the clonal approach. We question this result and its theoretical underpinning, and we bring new empirical evidence showing that the clonal outperforms the aclonal approach in generating homogeneous teams required to dynamically specialise for the benefit of the team. The results of our study suggest that task-specific elements influence the evolutionary dynamics more than the genetic relatedness of the team members. We conclude that the appropriateness of the clonal approach for role allocation scenarios is mainly determined by the specificity of the collective task, including the evaluation function, rather than by the way in which the solutions are evaluated during evolution.     

Computational study on the interaction of a ring-hydroxylating dioxygenase from Sphingomonas CHY-1 with PAHs

The massive computational resources available in the framework of a grid paradigm approach represent an emerging tool in the bioinformatics field. In this paper, we used the above approach in the rapid determination of the interactions between the ring-hydroxylating dioxygenase, comprised six enzymatic subunits, and polycyclic aromatic hydrocarbons (PAHs) in their optimal positions. The results were obtained by simulating enzyme dynamics at 300 K through molecular dynamics calculations. For the first time, the equilibrated structure of the dioxygenase revealed a network of channels throughout the enzyme that were sufficiently large to allow a flow of small ions or molecules from the inner core of the complex to its exterior surface. The ring-hydroxylating dioxygenase was able to interact with some of the studied PAHs. Additionally, not only the number of aromatic rings but also the PAH shape were critical in predicting the ability of the dioxygenase to interact with these types of molecules. Docking calculations shed light on a new possible binding site that is far from the enzymatic one, which is potentially interesting in considering the stability of the enzyme itself.     

ROMANSEVAL: Results for Italian by SENSE

The paper describes SENSE, a word sense disambiguation system thatmakes use of different types of cues to infer the most likelysense of a word given its context. Architecture and functioning ofthe system are briefly illustrated. Results are given for theROMANSEVAL Italian test corpus of verbs.     

High-automation proofs for properties of requirements models

We describe an approach and experimental results in the application of mechanized theorem proving to software requirements analysis. Serving as the test article was the embedded controller for SAFER, a backpack propulsion system used as a rescue device by NASA astronauts. SAFER requirements were previously formalized using the prototype verification system (PVS) during a NASA pilot project in formal methods, details of which appear in a NASA guidebook. This paper focuses on the formulation and proof of properties for the SAFER requirements model. To test the prospects for deductive requirements analysis, we used the PVS theorem prover to explore the upper limits of proof automation. A set of property classes was identified, with matching proof schemes later devised. After developing several PVS proof strategies (essentially prover macros), we obtained fully automatic proofs of 42 model properties. These results demonstrate how customized prover strategies can be used to automate moderate-complexity theorem proving for state machine models.     

Investigation of the Equivalence of National Dew-Point Temperature Realizations in the ?50?°C to +?20?°C Range

In the field of humidity quantities, the first CIPM key comparison, CCT-K6 is at its end. The corresponding European regional key comparison, EUROMET.T-K6, was completed in early 2008, about 4?years after the starting initial measurements in the project. In total, 24 NMIs from different countries took part in the comparison. This number includes 22 EURAMET countries, and Russia and South Africa. The comparison covered the dew-point temperature range from ?50?°C to +20?°C. It was carried out in three parallel loops, each with two chilled mirror hygrometers as transfer standards in each loop. The comparison scheme was designed to ensure high quality results with evenly spread workload for the participants. It is shown that the standard uncertainty due to the long-term instability was smaller than 0.008?°C in all loops. The standard uncertainties due to links between the loops were found to be smaller than 0.025?°C at ?50?°C and 0.010?°C elsewhere. Conclusions on the equivalence of the dew-point temperature standards are drawn on the basis of calculated bilateral degrees of equivalence and deviations from the EURAMET comparison reference values (ERV). Taking into account 16 different primary dew-point realizations and 8 secondary realizations, the results demonstrate the equivalence of a large number of laboratories at an uncertainty level that is better than achieved in other multilateral comparisons so far in the humidity field.     

Postharvest performance of fresh‐cut ‘Big Top’ nectarine as affected by dipping in chemical preservatives and packaging in modified atmosphere

Fresh‐cut ‘Big Top’ nectarines were dipped in 2% (w/v) ascorbic acid–1% (w/v) calcium lactate and stored at 4 °C for up to 12 days in 10 kPa O₂‐ and 10 kPa CO₂‐modified atmosphere packaging (MAP). The used microperforated plastic film allowed O₂ and CO₂ concentrations to reach steady values from the fifth day in storage onwards. Samples stored in MAP after chemical dipping showed the highest visual quality score, slight browning symptoms, increment in firmness and very low ethanol and acetaldehyde content. The chemical dipping also increased antioxidant capacity, probably due to the effect of ascorbic acid. The results suggested that the control of yeasts was mainly exerted by MAP, whereas only a slight effect was achieved by the chemical dipping. Therefore, MAP plus ascorbic acid/calcium lactate dipping was the best combination to preserve phytochemical content, antioxidant capacity and microbiological safety of fresh‐cut nectarines during storage.     

Single-ion-conducting nanocomposite polymer electrolytes based on PEG400 and anionic nanoparticles: Part 2. Electrical characterization

Molecular relaxation and polarization phenomena of twelve single-ion-conducting nanocomposite polymer electrolytes (nCPEs) are studied using Broadband Electrical Spectroscopy (BES). The electrolytes are obtained by combining PEG400 oligomers with increasing amounts of anionic nanofiller comprised of fluorinated-TiO₂ associated with Li⁺ cations (LiFT^®), resulting in [PEG400/(LiFT)_y] systems with 0 ≤ y ≤ 26.4. This new class of [PEG400/(LiFT)_y] electrolytes allows us to achieve a significant single-ion conductivity (1.1·10⁻⁵ S cm⁻¹ at 30 °C for n_Li/n_O = 0.113) without the addition of lithium salts. To the best of our knowledge, this is the highest conductivity value reported for this class of electrolytes. This study, in conjunction with the results reported in Part 1, leads us to hypothesize a conduction mechanism in terms of two types of long-range charge-transfer processes. The first charge-transfer occurs at the interface between the filler nanoparticles and filler-PEG domains, while the second occurs through the PEG400 matrix with the assistance of polymer segmental motion. The measured Li⁺ transference numbers confirm that the studied materials are single-ion conductors.