Solution-Synthesized Multifunctional Janus Nanotree Microswimmer

Synthetic active matters are perfect model systems for non-equilibrium thermodynamics and of great potential for novel biomedical and environmental applications. However, most applications are limited by the complicated and low-yield preparation, while a scalable synthesis for highly functional microswimmers is highly desired. In this paper, an all-solution synthesis method is developed where the gold-loaded titania-silica nanotree can be produced as a multi-functional self-propulsion microswimmer. By applying light, heat, and electric field, the Janus nanotree demonstrated multi-mode self-propulsion, including photochemical self-electrophoresis by UV and visible light radiation, thermophoresis by near-infrared light radiation, and induced-charge electrophoresis under AC electric field. Due to the scalable synthesis, the Janus nanotree is further demonstrated as a high-efficiency, low-cost, active adsorbent for water decontamination, where the toxic mercury ions can be reclaimed with enhanced efficiency.     

Centimeter-scale low-damage micromachining on single-crystal 4H–SiC substrates using a femtosecond laser with square-shaped Flat-Top focus spots

Femtosecond (fs) lasers have been proved to be reliable tools for high-precision and high-quality micromachining of ceramic materials. Nevertheless, fs laser processing using a single-mode beam with a Gaussian intensity distribution is difficult to obtain large-area flat and uniform processed surfaces. In this study, we utilize a customized diffractive optical element (DOE) to redistribute the laser pulse energy from Gaussian to square-shaped Flat-Top profile to realize centimeter-scale low-damage micromachining on single-crystal 4H–SiC substrates. We systematically investigated the effects of processing parameters on the changes in surface morphology and composition, and an optimal processing strategy was provided. Mechanisms of the formation of surface nanoparticles and the removal of surface micro-burrs were discussed. We also examined the distribution of subsurface defects caused by fs laser processing by removing a thin surface layer with a certain depth through chemical mechanical polishing (CMP). Our results show that laser-induced periodic surface structures (LIPSSs) covered by fine SiO₂ nanoparticles form on the fs laser-processed areas. Under optimal parameters, the redeposition of SiO₂ nanoparticles can be minimized, and the surface roughness Sa of processed areas reaches 120 ± 8 nm after the removal of a 10 μm thick surface layer. After the laser processing, micro-burrs on original surfaces are effectively removed, and thus the average profile roughness Rz of 2 mm long surface profiles decreases from 920 ± 120 nm to 286 ± 90 nm. No visible micro-pits can be found after removing ~1 μm thick surface layer from the laser-processed substrates.     

反坦克导弹用热电池研究进展

反坦克导弹作为击毁坦克和其他装甲目标的武器装备,在国家安全领域具有重要地位.热电池作为反坦克导弹的能源系统,对导弹功能实现具有重要意义.围绕反坦克导弹用热电池快激活和瞬时高比功率技术,结合热电池电化学材料体系发展历史、现状,探讨了提升快激活能力,提高瞬时比功率输出能力的技术,并对技术发展趋势进行了展望.     

Fabrication strategies and application fields of novel 2D Ti3C2Tx (MXene) composite hydrogels: A mini-review

Ti₃C₂T_x (MXene), a new kind of 2D ceramic nanosheets, is receiving more and more attention in the fields of medicine, biology, energy, electronics, etc. However, the preparation and application of MXene in hydrogel is still in its infancy period. Here, we review the latest progress (after 2018) related to MXene hydrogels in time. Aiming at the key issue of the dispersion stability of MXene in hydrogel systems, the preparation strategy, mechanism, advantages and disadvantages of MXene hydrogels are sorted out in detail, and the potential application prospects of MXene composite hydrogel are introduced. Finally, future viewpoints are put forward for the dispersion stability challenges that need solving in the design of MXene hydrogel.     

Elucidation of colour development and microstructural characteristics of Allium sativum fumigated with acetic acid

It has been well known that the greening of Allium sativum cloves could be formed after immersed in acetic acid solution. Nonetheless, no investigation was reported on colour development of A. sativum in response to acetic acid vapour until now. In this study, the brief exposure of A. sativum to acetic acid vapour (200–400 ppm) was combined with controlled atmosphere (5%, 20% and 80% CO₂) packaging storage to break cell membrane and green garlic. The garlic bulbs were fumigated with acetic acid before controlled CO₂ atmosphere packaging for 25 days at 4 °C. Fumigation with 200 ppm acetic acid followed by high CO₂ atmosphere packaging (80% CO₂) facilitated the garlic greening. It was also verified that γ‐glutamyl transpeptidase was involved in garlic greening in present study, and the compromise of glacial acetic acid vapour fumigation and CO₂ gas atmosphere in package stored at low temperature could result in garlic greening as well.     

0Cr20Mn21Ni2N奥氏体不锈钢锻件组织性能研究

研究了无磁钻铤用0Cr20Mn21Ni2N奥氏体不锈钢圆棒锻件横截面的室温强度、硬度和韧性等力学性能,并从微观角度进行了分析。在圆棒表层区域观察到了锻造变形态晶粒组织,而直径四分之一区域为再结晶组织,平均晶粒尺寸为80μm,芯部再结晶晶粒尺寸粗化为150μm,这些差异是由不同的变形温度和降温速度造成的。这种组织差异导致的室温拉伸性能和冲击韧性也有相应的变化趋势。研究结果表明,在900、1000℃以0.5 s-1的应变速率压缩的0Cr20Mn21Ni2N试验钢样品,其应力应变曲线具有一定的加工硬化特征,其芯部硬度比应变速率为0.1 s-1的样品分别提升了28、15 HB。在700、800℃以20%以上的变形量进行压缩时,峰值抗力显著提高,而在900、1000℃以10%~50%的变形量进行压缩时,峰值抗力均无明显提高,可保证顺利的变形过程。     

中原油田集中供热锅炉房改扩建工程设计

阐述了中原油田基地北区锅炉房改扩建工程的工艺流程、DCS控制系统等设计特点,依据中原油田燃料种类、特性及环保要求,确定了设备的合理选型,针对节能和环境保护,提出了设计中应采取的技术措施.工程投产后,系统运行平稳,各项指标均达到设计要求,保证了锅炉安全、经济地运行.     

镁掺杂磷铝分子筛可见光光催化性能的初步研究

采用水热反应的方法合成了金属镁掺杂的磷铝分子筛MgAPO-5,通过XRD、DR UV-Vis、FT-IR等手段对其结构性能进行表征,并以亚甲基蓝溶液为目标降解物,在可见光下考察了MgAPO-5的光催化性能.结果表明,MgAPO-5具有与AlPO4-5相同的分子筛结构,掺杂的镁可能存在于磷铝分子筛的骨架中,在可见光下对亚甲基蓝溶液具有优良的光催化性能,反应5 h,脱色率可达92.5%.     

重复压裂裂缝转向时油藏数值模拟研究

裂缝转向的实现及选井、选层、优化设计等的数值模拟和机理是转向重复压裂需进一步研究解决的问题,为此,采用黑油模型,研究了在反九点注采井网中,不同储集层渗透率下,转向重复压裂的裂缝穿透率和导流能力等对采油动态的影响。研究表明,不论是渗透率高的地层还是渗透率低的地层,不利裂缝方位的边井最适合实施转向重复压裂且需要比常规重复压裂更大的缝长,而有利裂缝方位的边井和角井只需要与常规重复压裂相当的缝长;同时,转向重复压裂需要比常规重复压裂更高的裂缝导流能力。