官能团化MCM-41在分离低碳醇-水混合物中的应用

采用一步法水热合成了介孔材料氯丙基官能团化的MCM-41(Cl(CH2)3-MCM-41)、氨丙基官能团化MCM-41(NH2(CH2)3-MCM-41)、甲基官能团化MCM-41(CH3-MCM-41)和氯丙基官能团化硅胶,并考察了它们作为气相色谱固定相分离低碳醇-水混合物的情况。实验结果表明,Cl(CH2)3-MCM-41能够分离低碳醇-水混合物中的各组分,随水、甲醇、乙醇、异丙醇、正丁醇极性的减小,各分子与Cl(CH2)3-MCM-41的作用力增强,保留时间延长。氯丙基官能团化硅胶、NH2(CH2)3-MCM-41)和CH3-MCM-41均不能分离低碳醇-水混合物,表明介孔材料规则的孔道结构、表面嫁接基团等对低碳醇-水混合物的分离有重要影响。同时考察了Cl(CH2)3-MCM-41的氯丙基负载量对低碳醇-水混合物分离效果的影响,结果表明,当氯丙基的摩尔分数为15%时,分离效果最佳。     

Feasibility of the indirect determination of blast-induced rock movement based on three new hybrid intelligent models

Engineering with Computers - The indirect and accurate determination of blast-induced rock movement has important significance in the reduction of ore loss and dilution and in the protection of...     

Ru/CN催化对苯二甲酸二甲酯加氢制备1,4-环己烷二甲酸二甲酯

通过超声辅助NaBH4还原法制备了3%Ru/CN催化剂（Ru的质量分数）,该催化剂用于对苯二甲酸二甲酯（DMT）加氢制备1,4-环己烷二甲酸二甲酯（DMCD）。采用Raman、SEM、TEM、N2吸脱附、XRD、XPS等对载体和催化剂的组成、表面性质进行表征,结果表明,氮元素成功掺入碳骨架中且氮掺杂碳材料为介孔结构。研究了催化剂的用量、反应温度、H2 压力、反应时间等对催化剂加氢性能的影响。结果表明,当反应物用量为1.00 g,催化剂（含载体）用量为0.05 g,反应温度140 ℃,反应压力5.0 MPa,反应时间1 h时,DMT转化率为100%,DMCD选择性为99.3%。3%Ru/CN-1000催化剂循环使用5次后,催化剂催化性能未见明显下降,DMT转化率为98.8%,DMCD选择性为99.7%。     

取向硅钢氧化膜结构对渗氮层深度的影响

摘要：低温板坯加热技术生产取向硅钢,其关键点之一在于脱碳退火后要进行渗氮处理。通过控制脱碳气氛,获得不同的氧化膜结构;并进一步分析在近似渗氮量条件下,氧化膜结构对渗氮层深度的影响。结果表明：氧化膜分为外层颗粒状氧化膜和内层层片状氧化膜两部分。随着脱碳气氛露点增加,脱碳板O含量增加,氧化膜厚度增厚、层片状氧化膜占氧化膜总厚度的比例下降,渗氮层深度增加。当层片状氧化膜厚度占比较高时,［N］原子积聚在试样的极表层,形成氮沿厚度方向的单峰分布,渗层较浅。当层片状氧化膜厚度占比较低时,［N］原子会越过该层,而在次表层再次发生积聚;从而除了极表层的氮峰外,在次表层形成一个或多个氮峰,渗层较深。     

Human tracking system based on adaptive multi-feature mean-shift for robot under the double-layer locating mechanism

Human tracking has been a challenging task for robot in the past decades. In this paper, to realize the human following in a cluttered environment, a human tracking system based on adaptive multi-feature mean-shift (AMF-MS) under the double-layer locating mechanism (DLLM) is proposed to solve the problem of distinguishing target, occlusion, and quick turning. The DLLM, considering the course location processing and fine location processing, is designed to estimate the person’s position using the fusion of heterogeneous data. As an ID tag attached on target can be detected by RF antennas, the course locating method can track the target easily and quickly. The Bayes rule is introduced to calculate the probability where the tag exists due to the instability of RF signals. In the fine locating step, the AMF-MS is proposed because it can reduce computational load and represent target by multi-feature histogram function. Meanwhile, we combine extended Kalman filter and AMF-MS to overcome MS’s inability of occlusion. To control the robot following the target person precisely, an intelligent gear shift strategy based on fuzzy control is implemented by analyzing the robot structure. Experiments demonstrate that the proposed approach is robust to handle complex tracking conditions, and show the system has an optimum performance.     

热处理对照相明胶溶液粘度和分子量分布的影响

本文以四种照相明胶为研究对象，探讨热处理对照相胶胶溶液粘度和分子量分布的影响，实验结果表明，随着加热温度上升，照相明胶溶液粘度下降，数均分子量下降，照相明胶溶液粘度和数均分子量密切相关，照相明胶溶液粘度下降发生的内在原因是数均分子量下降，在本实验条件下，惰胶、活性胶的加热温度不超过７５℃，ＰＡ胶的加热温度不超过６０℃。     

Mechanical properties of poly(lactic acid) and wheat starch blends with methylenediphenyl diisocyanate

Poly(lactic acid) (PLA) and wheat starch are biodegradable polymers derived from renewable sources. A previous study showed that thermally blending starch and PLA in the presence of methylenediphenyl diisocyanate (MDI) enhanced the mechanical properties of the blends. In this work, blends of PLA with various levels of wheat starch and MDI were hot mixed at 180°C then hot‐pressure molded at 175°C to form test specimens. The blends were characterized for mechanical properties, fracture microstructure, and water absorption. Pure PLA had a tensile strength of 62.7 MPa and elongation of 6.5%. The blend with 45% wheat starch and 0.5 wt % MDI gave the highest tensile strength of about 68 MPa with about 5.1% elongation. The blend with 20% starch and 0.5 wt % MDI had the lowest tensile strength of about 58 MPa with about 5.6% elongation. Dynamic mechanical analysis showed that storage modulus increased and tan δ decreased as starch level increased, but almost leveled off when starch level reached 45% or higher. Water absorption of the blends increased significantly with starch content. Yet the blend, if water proofed on its surface, has potential for short‐term disposable applications. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1257–1262, 2002; DOI 10.1002/app.10457     

基于神经网络的曲轴滚压校直专家系统研究

介绍了曲轴滚压强化及校直工艺,分析了滚压校直方式具有的优缺点,研究了利用BP神经网络建立关于校直输入输出数学模型的方法,建立了曲轴滚压校直专家推理系统,并将其应用到曲轴圆角滚压强化校直机床中,取得了较好的效果。     

边坡稳定性预测的Bayes判别分析方法及应用

边坡稳定性的分析是一个复杂的系统工程问题.基于Bayes判别分析(BDA)理论并结合工程实际,选用边坡岩体的重度黏聚力、摩擦角、边坡角、边坡高度及孔隙压力比等6个指标作为边坡稳定性预测的判别因子,建立边坡稳定性预测的Bayes判别分析模型;以32组边坡实测数据作为学习样本进行训练,建立Bayes线性判别函数;以交差确认估计法对判别准则进行评价以检验模型的优良性,以Bayes线性判别函数计算7个待判样品的Bayes判别函数值.研究表明:Bayes判别分类性能良好,与支持向量机方法有较好的一致性,且预测精度高,交差确认估计的误判率较低,为边坡稳定性预测提供了一种新思路.     

矫直辊曲线及调整角度计算程序

简述了矫直辊辊形曲线计算原理，并作了定性分析；根据解析法与椭圆法归纳出辊形曲线程序设计的数学模型联；计算出了各种钢管对应的矫直辊调整角度。