Reaction behaviors and specific exposed crystal planes manipulation mechanism of TiC nanoparticles

Titanium carbide (TiC) nanoparticles with well-designed exposed crystal planes perform intriguing prospects for functional and engineering applications. In this study, a simple and controllable in situ synthesis strategy was proposed for the synthesis of TiC nanoparticles with specific morphology. Reaction behaviors suggested that most of TiC nanoparticles were formed by an instantaneous reaction between Al₃Ti and Al₄C₃ in the Al-rich melt and the resultant morphology was controlled by the discrepant growing rates of (100) and (111) crystal planes. In addition, a growth morphology control model was presented for the prediction and manipulation of the morphology of TiC nanoparticles by the doping of different alloying elements Me (Me = Cu, Mg, Mn, Zn, and Si). According to the morphological observations and density functional theory analyses including the interface energy, charge density differences, and orbital hybridization: Cu, Mg, and Zn atoms could stabilize the Al/TiC(111) interface, whereas Mn and Si atoms promoted the rapid growing and disappearance of the TiC(111) planes in the Al melt. This work provides a feasible way to intelligently design and manipulate TiC nanoparticles with desirable exposed crystal planes, and exhibits a promising prospect for personalized applications.     

Improving the structural stability of Li-rich cathode materials via reservation of cations in the Li-slab for Li-ion batteries

High-capacity Li-rich cathode materials can significantly improve the energy density of lithium-ion batteries, which is the key limitation to miniaturization of electronic devices and further improvement of electrical-vehicle mileage. However, severe voltage decay hinders the further commercialization of these materials. Insights into the relationship between the inherent structural stability and external appearance of the voltage decay in high-energy Li-rich cathode materials are critical to solve this problem. Here, we demonstrate that structural evolution can be significantly inhibited by the intentional introduction of certain adventive cations (such as Ni²⁺) or by premeditated reservation of some of the original Li⁺ ions in the Li slab in the delithiated state. The voltage decay of Li-rich cathode materials over 100 cycles decreased from 500 to 90 or 40 mV upon introducing Ni²⁺ or retaining some Li⁺ ions in the Li slab, respectively. The cations in the Li slab can serve as stabilizers to reduce the repulsion between the two neighboring oxygen layers, leading to improved thermodynamic stability. Meanwhile, the cations also suppress transition metal ion migration into the Li slab, thereby inhibiting structural evolution and mitigating voltage decay. These findings provide insights into the origin of voltage decay in Li-rich cathode materials and set new guidelines for designing these materials for high-energy-density Li-ion batteries.

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Delay-dependent stability analysis for Markovian jump systems with interval time-varying-delays

This paper proposes improved stochastic stability conditions for Markovian jump systems with interval time-varying delays. In terms of linear matrix inequalities (LMIs), less conservative delay-range-dependent stability conditions for Markovian jump systems are proposed by constructing a different Lyapunov-Krasovskii function. The resulting criteria have advantages over some previous ones in that they involve fewer matrix variables but have less conservatism. Numerical examples are provided to demonstrate the efficiency and reduced conservatism of the results in this paper.     

基于自适应延迟切割的三角网格布尔运算优化

规则化的布尔运算被广泛应用在三维建模系统中.近年来,随着图形硬件的发展,基于三角网格的规则化布尔算法由于输出结果能直接被图形硬件处理,表现出了明显的优势.但是传统的算法由于采用CSG树局部评估策略,使得面片在相交测试中反复被切割,并且由于面片分类在切割后的模型之间直接进行,导致算法无法在保证鲁棒性的同时实现高性能.为了避免这些问题,本文呈现了一种CSG树全局评估算法来统一执行单次和连续布尔运算.算法由两部分组成：自适应的延迟切割和全局化面片分类.在自适应的延迟切割阶段,算法通过仔细处理多个三角面片相交导致的各种情况使得延迟切割被扩展到整个CSG树来避免由于面片的反复切割带来的数值误差累积并利用自适应的八叉树使得相交测试能在线性时间内完成.在全局化面片分类阶段,算法通过分治法使得分类始终在切割后的面片和原始输入模型之间进行来保证分类的精度;通过结合组分类策略和自适应的八叉树来进一步优化了分类性能。实验结果表明,本文提出的算法无论是在执行单次或连续布尔运算时都能在保证鲁棒性同时性能优于其他的算法,因此本文算法可广泛应用于交互式建模系统中,如数字雕刻、计算机辅助设计和制造（CAD/CAM）等.     

嵌入式通讯管理机在企业电能管理系统中的应用

将嵌入式通讯管理机应用于电能管理系统中,可以有效解决电能管理系统中实时通信和组网的问题．本文分析了采用嵌入式通讯管理机构建电能管理系统的优点,给出了基于MPC860T处理器平台和NucleusPLUS操作系统的通讯管理机方案,介绍了硬件系统组成原理和软件设计方案,最后给出了基于通讯管理机的电能管理系统的设计与实现,调试结果表明该方案符合实际应用需求．     

基于加权总广义变差的Mumford-Shah模型

给出了加权总广义变差(Total generalized variation, TGV)的定义. 利用图像的2阶加权TGV半范作为正则项, 利用水平集函数的2阶加权TGV半范近似边界长度, 提出了基于加权TGV的Mumford-Shah模型. 对未知函数分别利用交替Split-Bregman方法、Fenchel对偶方法及FISTA (Fast iterative shrinkage-thresholding algorithm)给出数值计算模型. 仿真实验结果表明, 利用图像的2阶加权TGV半范的去噪效果优于常用的梯度模2范数和加权TV (Total variation)半范正则化; 利用水平集函数的2阶加权TGV半范近似边界长度的边缘检测效果优于传统的TV半范和加权TV半范约束.     

单相串励电动机制造过程常见故障分析

简述了单相串励电动机的用途、性能与结构特点。分析了制造过程中常见故障产生的原因，从而提出纠正和预防措施．以避免形成文中列举的过程失效模式。     

Microstructure and performance of multi-dimensional WC-CoCr coating sprayed by HVOF

WC-based coatings deposited by high velocity oxy-fuel (HVOF) spraying have been widely used in many industrial fields, where mechanical components are subjected to severe abrasive wear. Much attention has been especially paid to nanostructured and multimodal WC-based coatings due to their excellent abrasive wear resistance. In this study, a new kind of multi-dimensional WC-10Co4Cr coating, composed of nano, submicron, micron WC particles and CoCr alloy, was developed by HVOF. The microstructure, porosity, microhardness, fracture toughness, and electrochemical properties of the coating were investigated in comparison with nanostructured WC-10Co4Cr coating deposited by HVOF. Abrasive wear resistance of both WC-10Co4Cr coatings was evaluated on wet sand rubber wheel abrasion tester. The results show that the multi-dimensional coating possesses low porosity (0.31 ± 0.09%), excellent microhardness (1126 ± 115 HV_0.3), fracture toughness (4.66 ± 0.51 MPa m^1/2), and outstanding electrochemical properties. Moreover, the multi-dimensional coating demonstrates approximately 36% wet abrasive resistance enhancement than the nanostructured coating. The superior abrasive wear resistance originates from the coating’s multi-dimensional structure and excellent mechanical and electrochemical properties.     

低熔点合金在复合材料注射成型工艺中的应用

针对熔芯注射成型的工艺特点,提出复合熔芯注射成型的基本原理,介绍低熔点合金熔芯材料的选择以及复合熔芯的特点和结构设计准则;并应用于实际生产,取得良好效果。