酯化反应偶联渗透汽化膜过程模型(Ⅰ)催化剂的影响

1 INTRODUCTION In former report, the kinetic model for anesterification process coupled by pervaporation wasestablished and the modeling result agreed well withthe experimental result[1].     

压缩真空库中原子系统的偶极压缩特性

运用密度算符方法并结合数值计算,研究了处于压缩真空库中的原子系统的偶极压缩特性,讨论了原子初始态、衰减常数Γ及压缩参量r对原子偶极压缩特性的影响,并给出了相关结论。     

一种基于图像的光学系统测角精度检测方法

测角精度是光学系统的重要技术指标。针对传统的电子经纬仪测角精度检测方法测量数据少、扫描方向单一导致测量结果不准确,提出了一种改进的检测方法。调整电子经纬仪,使电子经纬仪发射的电十字通过光学系统成像在CCD视场中,旋转电子经纬仪以点阵形式,对光学系统各个方向进行扫描,计算机实时采集电十字图像。对采集的电十字图像,通过基于小波变换的变分Retinex算法增强图像对比度,采用OTSU阈值分割背景和目标,采用投影算法及二项式曲线拟合将电十字中心定位到亚像素级。对最终获取的电十字中心点阵数据通过径向基函数进行曲面插值,解算出基于整个CCD像面的测角精度。实验结果表明：该方法的测量精度达到0.1μrad,测得的光学系统测角精度提高了0.01mrad,检测的测角精度更加准确。     

Fluorescence enhancement and cofluorescence in complexes of terbium(III) with trimellitic acid

1. Introduction Rare earth elements have an important function inlife process. The fluorescence enhancement of lan-thanides in aqueous solutions has therefore becomean area of active study in trace-level estimation oflanthanides using spectrofluorimetry [1]. Its possiblemechanism and application as fluorescence probesin biological systems have also attracted attention inrecent years [2]. Generally, fluorescence enhance-ment can be achieved through ligand sensitization.Various ligands have bee…     

Fluorescence enhancement and cofluorescence in complexes of terbium(Ⅲ) with trimellitic acid

The fluorescence of terbium (Ⅲ) was enhanced by about three orders of magnitude in the presence of trimellitic acid (benzene-l, 2, 4-tricarboxylic acid (TLA)) in aqueous solution at pH 6. The fluorescence intensity could be greatly increased when the system of Tb3+-TLA was treated with La3+ (or Gd3+) and TritonX- 100. The addition of La3+ (or Gd3+) enhances the fluorescence of the system by about two orders of magnitude due to cofluorescence, and the TritonX-100 micellar medium plays an important role for stabilization of the system. Both the intermolecular energy transfer mode and intramolecular energy transfer mode are responsible for the mechanism of fluorescence enhancement. In the optimum conditions, the fluorescence intensity is a linear function of Tb3+ concentration in the range of 7.8 × 10-9-3.6 × 10-6 mol/L for the system Tb3+-La3+-TLA and 1.0 × 10-8-4.7 × 10-6 mol/L for the system Tb3+-Gd3+-TLA, and the limits of detection are 4.6 ×10-10 mol/L and 6.0 × 10-10 mol/L, respectively.     

计算机遗传病毒运作模式剖析

遗传病毒是指通过病毒自身的学习机制,反复地经选择、交叉、变异等步骤,进化出的能够适应环境的新病毒.此种病毒种类,较为复杂,且具有较高的变异能力,因此防杀也较为困难.该病毒很难依照固定特征或行为模式来侦测及清除.此类病毒的进化方式,不需创造出完整的病毒,只需是可用的新元件,再通过自身进化出新一代病毒.研究的目的,在于提出遗传病毒的进化模型,供研究人员思考对其的防治.     

适用于Ad Hoc网络的混合认证机制

分析了Ad Hoc网络的特点及其对身份认证机制的安全需求,采用椭圆曲线和对称密钥两种认证体制并结合自证明公钥原理,提出了一种适用于Ad Hoc网络的混合认证机制.该机制中门限方案增强了系统的健壮性,基于自证明公钥的双向认证协议确保了交互节点身份的真实性,刷新认证协议保证了节点身份的持续可信,分布式自证明公钥撤销方案可将恶意节点快速从系统中分离出去.分析结果表明,该认证机制具有较高的安全性,同时对系统存储空间、网络通信量和计算开销的要求都很少,有着较高的效率.     

Feed-direction ultrasonic vibration−assisted milling surface texture formation

The formation mechanism of surface texture for feed-direction ultrasonic vibration?assisted milling (UVAM) was investigated in this study by establishing a kinematic model and a pressing model of UVAM. The kinematic model showed that the cutter tip, which was supposed to be totally sharp, produced closed scratches by crossed trajectories. The variation trends of the interval for closed textures were of sine function. A comparative experiment was carried out by UVAM and conventional milling. A dividing line close to the X coordinate divides the surface feature into two parts. The pressing model showed that the tool minor cutting edge left clear traces with certain width because of the tool minor cutting edge angle. Scratches by tool minor cutting edge were intermittent and regularly varied when feed-direction vibration was introduced. All the surface feature changes are in the radial direction and the trajectory intersections shall always be the scratch grooves or ridges. The ratio between ultrasonic vibration frequency and spindle speed, tool radius, and the located cutter rotation angle affected the changing rule of scratches by tool minor cutting edge. The analytical models and the experimental results proved to each other reasonable.     

Influence of Sn and Mo on corrosion behavior of ferrite-pearlite steel in the simulated bottom plate environment of cargo oil tank

This work investigated the influence of Sn and Mo on corrosion behavior of ferrite-pearlite steel in the simulated bottom plate environment of cargo oil tank. The results indicate that the corrosion rate of three ferrite-pearlite steels increased with extending the immersion time due to the continuous accumulation of the residual Fe_3C. However, the addition of Sn or the combined addition of Sn and Mo could reduce the corrosion rate of Sn containing steel and Sn-Mo containing steel to 37.5% and 20% of that of carbon steel, respectively. Moreover, the cathodic reaction of Sn containing steel and Sn-Mo containing steel was always controlled by the charge transfer step during the whole immersion test, while that of carbon steel was gradually transformed into the diffusion-controlled process. These results were mainly related with the deposition of metallic Sn and Mo on the steel surface. The metallic Sn and Mo with uniform distribution restrained the galvanic effect through suppressing both the anodic dissolution of ferrite and cathodic hydrogen evolution reaction on the residual Fe_3C.     

基于DSP数字心电图机的设计

介绍12导联数字心电图机研制开发,采用双CPU架构,包括数字信号处理TMS320F206和微控制器AT89C55.该仪器利用数字信号处理器TMS320F206PZ实现实时对心电信号进行滤波和心电参数计算;热敏打印心电图形和检测结果;存储病人的心电数据,心电图形的回放打印,与PC机进行数据通主,建立病人的心电数据库,进一步研究分析.