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2.
M. Lamirand J. -L. Bonnentien S. Guérin G. Ferrière J. -P. Chevalier 《Metallurgical and Materials Transactions A》2006,37(8):2369-2378
The effect of added oxygen in the range of 1000 to 4000 wt ppm on the microstructures of a Ti-48Al-2Cr-2Nb alloy has been
investigated and compared to the microstructures for a high-purity alloy. For specimens cooled from theα phase, interstitial oxygen stabilizes the lamellar microstructure with respect toγ grains, with higher than equilibrium values for theα
2 volume fraction. For specimens cooled from theα +γ phase field, the lamellar microstructure still tends to be favored by oxygen, but it is found that the phase volume fractions
are not significantly different from equilibrium values. This suggests that interstitial O essentially reduces the kinetics
of theα toα +γ transformation. Thus, interstitial oxygen will have a strong effect on microstructures obtained by continuous cooling fromα, but significantly less on those, such as the duplex microstructure, obtained by long treatment in theα +γ phase field. In general, increased O content is well correlated with reduced ductility. Finally, the role of interstitial
oxygen on this phase transformation is discussed. 相似文献
3.
New equiatomic ternary silicides MIrSi (M = Y, Ti, Zr, Hf) crystallizing with the TiNiSi-type structure (anti-PbCl2) have been prepared. Those with Y(Tcr = 2.70 K), Zr(Tcr = 2.04 K) and Hf(Tcr = 3.50 K) are the first superconducting ternary silicides having such a structure. The titanium compound has not been found to be superconducting above 1.7 K. 相似文献
4.
L.Q. Xing P. Ochin M. Harmelin F. Faudot J. Bigot J.P. Chevalier 《Materials Science and Engineering: A》1996,220(1-2)
Cylindrical bulk amorphous samples with diameters up to 10 mm have been prepared by casting ZrTiAlCuNi alloys in a copper mould. In order to rank glass-forming ability as a function of alloy composition, alloys were also cast into wedge-shaped moulds; to a first approximation, the thickness of the amorphous region obtained can be taken as an indication of glass-forming ability. The compositions which lead to the production of bulk glasses all have reduced glass transition temperatures in excess of 0.65 and the extremely high glass-forming ability of these compositions is discussed. We suggest that both the Al and Ti contents are determining factors for the production of bulk amorphous samples and these are believed to reduce the driving force for, and hence the rate of, crystallisation. These amorphous alloys have been found to display high thermal stability and can be annealed for several minutes in the supercooled liquid region. They are ductile at room temperature and have a high value of yield stress. 相似文献
5.
Macwan Richard Benezeth Yannick Mansouri Alamin 《Journal of Mathematical Imaging and Vision》2021,63(7):807-820
Journal of Mathematical Imaging and Vision - Remote photoplethysmography (rPPG) has been at the forefront recently, thanks to its capacity in estimating non-contact physiological parameters such as... 相似文献
6.
Seung Bum Kil Yannick Augros Yves Leterrier Jan‐Anders E. Mnson Andreas Christel Camille Borer 《Polymer Engineering and Science》2003,43(2):329-343
The rheological properties in solution, in shear and in uniaxial elongation of poly(ethylene terephthalate) (PET) reacted together with hyperbranched polymers (HBPs) were investigated. Two different PET grades, of low and high molecular weights, were compounded with sub‐ to over‐stoichiometric concentrations of HBPs of second and fourth pseudo‐generation, and subsequently subjected to a solid‐state polycondensation (SSP). The formation of microgels, which occurs at high HBP concentration, gave rise to a large increase in melt elasticity and a related decrease in melt strength. At low HBP concentrations, the complex viscosity of the unreacted HBP/PET was considerably reduced, thus demonstrating a lubrication effect of the HBP molecules. During SSP, the intrinsic and shear viscosities exhibited a gradual increase, which was similar for both PET and HBP/PET blends, and was correlated to an increase in molecular weight, through linear‐chain extension and branching reactions. The elongational viscosity of the reactive blends was also increased as a function of reaction time, and this increase was much larger in the case of the HBP/PET blends. A 400% increase in melt strength of the PET was obtained by combining SSP and trace amounts of an HBP of second generation, without any decrease in drawability. 相似文献
7.
Today parametric associative CAD systems must help companies to create more efficient virtual development processes. While dealing with complex parts (e.g. the number of surfaces of the solid) no CAD modeling methodology is existing. Based on the analysis of industrial designers' practices as well as student practices on CAD, we identified key factors that lead to better performance. Our objective in this article is to propose a practical method for complex parts modeling in parametric CAD system. An illustration of the performances and the results obtained by this method are presented comparing the traditional method with the proposed one while using an academic case and then an industrial case. 相似文献
8.
Chateau Marie-Elise Galet Laurence Soudais Yannick Fages Jacques 《Journal of surfactants and detergents》2004,7(4):355-362
A new test was developed to assess the efficiency of no-wiping hard-surface cleaning. The test allows cleaner comparisons
according to their ability to remove greasy soils. The chosen approach minimizes the mechanical forces applied while cleaning
so that the interactions between a detergent solution and the soil to be removed can be characterized. For this, immersion
cleaning was chosen, with coated stainless steel as substrate and pigmented oils as the model soil. Several parameters were
studied in defined ranges using the Experimental Design method and systematic comparisons. The test shows high reliability
on degreasing assessments and is there-fore especially suited to optimization of nonionic surfactant mixes. The originality
of the test lies in the possibility of keeping a visual trace of the cleaned substrate appearance by imprinting it on a piece
of paper. The validation of the test leads to corroboration of several practical observations. Temperature and agitation play
a major role in cleaning efficiency. Detergent solution concentration is a more relevant parameter than pH. Sodium carbonate
is shown to have a higher buffering effect than pentahydrated sodium metasilicate. The test is easy to set up, highly sensitive,
and can be adapted to solve the problems encountered by formulators of detergent cleaners, such as screening the best ethoxylated
fatty alcohol mix for better degreasing properties. 相似文献
9.
Amphiphilic block copolymers have been investigated for their utilization in emulsion polymerization of butyl methacrylate. Special attention has been paid to the adsorption mechanism of the block copolymers from systematic measurements of equilibrium adsorption isotherms. A series of well-defined water-soluble amphiphilic block copolymers, composed of poly(butyl methacrylate) and poly(sodium methacrylate) blocks, were synthesized by anionic polymerization of butyl methacrylate and tert-butyl methacrylate followed by the thermal deprotection of the tert-butyl ester groups and final hydrolysis. The number density of emulsion polymer particles NP varied as [copolymer]α, α lying between 0.44 and 0.73 according to the hydrophilic content of the copolymers. In contrast with SDS taken as a reference emulsifier, the adsorption of the copolymers was very strong and this provided quite an efficient stabilization of the polymer particles during emulsion polymerization, even at low concentrations (<10−4 mol L−1) and low coverages (<10% of the interfacial area). 相似文献
10.
Male and female weanling rats that were born to dams fed a diet low in linolenic acid received diets of 15% lipids by weight
containing 45% elaidic acid (as trielaidin) and 8.5% or 0.1% linolenic acid for 10 weeks. Four other groups, in which palmitic
or oleic acid replaced elaidic acid in the diet, served as controls. The fatty acid profiles of several lipid classes were
determined in adipose tissue, adrenals, testes, heart and brain. Elaidic acid was incorporated into tissue lipids in varying
degrees, depending on the organ and on the lipid class. Feeding elaidic acid induced no changes in the polyunsaturated fatty
acid (PUFA) profiles of testes lipids but resulted in definite modifications of the PUFA patterns of heart phosphatidylcholine
(PC) and phosphatidylethanolamine (PE). In linolenic acid-deprived rats, arachidonic acid was decreased in PC and linoleic
acid was increased in both PC and PE; 22∶5n−6 was strongly depressed in both PC and PE. In linolenic acid-fed rats, 22∶6n−3
was decreased in PC and PE. These changes, on the whole, were more evident in females, and some also were observed in adrenal
cholesteryl esters but only slightly in brain phospholipids. the apparent inhibition of the biosynthesis of PUFA induced by
dietary elaidic acid appeared to be complex and of greater intensity in the n−6 fatty acid series than in their n−3 homologues. 相似文献