Thermomechanical properties of alumina-filled plasticized polylactic acid: Effect of alumina loading percentage

Polylactic acid (PLA) is one of the most widely studied renewable and biodegradable polyesters and is expected to replace petrochemical-based synthetic polymers. In this study, we investigated the effect of the alumina volume fraction on the thermal and mechanical properties of polyethylene glycol (PEG)-plasticized PLA. The alumina particles were treated with maleic acid to improve their interaction with the PLA matrix. The field-emission scanning electron microscopy results revealed that the addition of alumina eliminated voids, leading to improved interfacial interactions between the PLA and alumina particles. The thermal conductivity of the neat PLA increased from 0.278 to 0.66?wm^?1 k^?1 with the addition of 30% alumina, which accounts for 137% increase. The tensile strength and Young's modulus of the neat PLA dropped by 52% and 56%, respectively, on the addition of 15% PEG plasticizer. However, the elongation at break increased from 5.4% to 207%, which was associated with a drop on the glass transition temperature values. The dynamic mechanical analysis results showed a drop in the storage modulus and height of the tan δ peak, revealing the increased flexibility of the composite after the inclusion of the plasticizer. The addition of 30% alumina exhibited a 41.6% increase on the stiffness of the PEG-blended PLA.     

Techno-economic analysis of photovoltaic pumping system for rural water supply in Ethiopia

The diesel-driven water pumping systems have a great impact on rural water supply in Ethiopia in past decades due to the lack of access to grid electricity and associated capital intensive nature of grid expansion to rural areas. However, the requirement of diesel generator for frequent maintenance and soaring fuel cost encourages the government and concerned bodies such as NGO to go for most reliable and cost-effective alternatives. In this paper, direct coupled photovoltaic (PV) pumping system has been designed for hypothetical rural village in southern region near Arba Minch (latitude 6.02^″N, Longitude 37.54^″E) to show techno-economic feasibility of the technology. The result shows that direct coupled PV pumping system is cost-effective in terms of life cycle cost and technologically feasible for rural water supply by virtue of its very low running cost and high reliability of the component and the system as a whole.     

The dynamics of urban expansion and land use/land cover changes using remote sensing and spatial metrics: the case of Mekelle City of northern Ethiopia

Information on the rate and pattern of urban expansion is required by urban planners to devise proper urban planning and management policy directions. This study evaluated the dynamics and spatial pattern of Mekelle City’s expansion in the past three decades (1984–2014). Multi-temporal Landsat images and Maximum Likelihood Classifier were used to produce decadal land use/land cover (LULC) maps. Changes in LULC and spatial pattern of urban expansion were analysed by post-classification change detection and spatial metrics, respectively. The results showed that in the periods 1984–1994, 1994–2004, and 2004–2014, the built-up area increased annually by 10%, 9%, and 8%, respectively; with an average annual increment of 19% (100 ha year^?1), from 531 ha in 1984 to 3524 ha in 2014. Between 1984 and 2014, about 88% of the gain in built-up area was from conversion of agricultural lands, which decreased by 39%. Extension of existing urban areas was the dominant growth type, which accounted for 54%, 75%, and 81% of the total new development during 1984–1994, 1994–2004, and 2004–2014, respectively. The spatial metrics analyses revealed urban sprawl, with increased heterogeneity and gradual dispersion in the outskirts of the city. The per capita land consumption rate (ha per person) increased from 0.009 in 1984 to 0.014 in 2014, indicating low density urban growth. Based on the prediction result, the current (2014) built-up area will double by 2035, and this is likely to have multiple socioeconomic and environmental consequences unless sustainable urban planning and development policies are devised.     

Experimental study on combustion of torrefied palm kernel shell (PKS) in oxy‐fuel environment

Oxy‐combustion of biomass can be a major candidate to achieve negative emission of CO₂ from a pulverized fuel (pf)‐firing power generation plants. Understanding combustion behavior of biomass fuels in oxy‐firing conditions is a key for design of oxy‐combustion retrofit of pulverized fuel power plant. This study aims to investigate a lab‐scale combustion behavior of torrefied palm kernel shell (PKS) in oxy‐combustion environments in comparison with the reference bituminous coal. A 20 kW_th‐scale, down‐firing furnace was used to conduct the experiments using both air (conventional) and O₂/CO₂ (30 vol% for O₂) as an oxidant. A bituminous coal (Sebuku coal) was also combusted in both air‐ and oxy‐firing condition with the same conditions of oxidizers and thermal heat inputs. Distributions of gas temperature, unburned carbon, and NO_x concentration were measured through sampling of gases and particles along axial directions. Moreover, the concentrations of SO_x and HCl were measured at the exit of the furnace. Experimental results showed that burnout rate was enhanced during oxy‐fuel combustion. The unburnt carbon in the flue gas was reduced considerably (~75%) during combustion of torrefied PKS in oxy‐fuel environment as compared with air‐firing condition. In addition, NO emission was reduced by 16.5% during combustion of PKS in oxy‐fuel environment as compared with air‐firing condition.     

Effects of coal characteristics to performance of a highly efficient thermal power generation system based on pressurized oxy‐fuel combustion

Because of its fuel flexibility and high efficiency, pressurized oxy‐fuel combustion has recently emerged as a promising approach for efficient carbon capture and storage. One of the important options to design the pressurized oxy‐combustion is to determine method of coal (or other solid fuels) feeding: dry feeding or wet (coal slurry) feeding as well as grade of coals. The main aim of this research is to investigate effects of coal characteristics including wet or dry feeding on the performance of thermal power plant based on the pressurized oxy‐combustion with CO₂ capture versus atmospheric oxy‐combustion. A commercial process simulation tool (gCCS: the general carbon capture and storage) was used to simulate and analyze an advanced ultra‐supercritical(A‐USC) coal power plant under pressurized and atmospheric oxy‐fuel conditions. The design concept is based on using pure oxygen as an oxidant in a pressurized system to maximize the heat recovery through process integration and to reduce the efficiency penalty because of compression and purification units. The results indicate that the pressurized case efficiency at 30 bars was greater than the atmospheric oxy‐fuel combustion (base line case) by 6.02% when using lignite coal firing. Similarly, efficiency improvements in the case of subbituminous and bituminous coals were around 3% and 2.61%, respectively. The purity of CO₂ increased from 53.4% to 94% after compression and purification. In addition, the study observed the effects of coal‐water slurry using bituminous coal under atmospheric conditions, determining that the net plant efficiency decreased by 3.7% when the water content in the slurry increased from 11.12% to 54%. Copyright © 2016 John Wiley & Sons, Ltd.     

Contrasting Uncertainties in Estimating Floods and Low Flow Extremes

Water Resources Management - Evaluation of possible sources of uncertainty and their influence on water resource planning and extreme hydrological characteristics are very important for extreme...     

Effect of surface-modified Al2O3 on the thermomechanical properties of polybutylene succinate/Al2O3 composites

This study investigates the effect of the incorporation of alumina particles on the thermomechanical properties of polybutylene succinate (PBS)/Al₂O₃ composites. The alumina surface was modified with the carboxylic groups of maleic acid through simple acid-base and in situ polymerization reactions. Scanning electron microscope (SEM) results revealed the introduction of maleic acid treated alumina significantly affect the morphology of the PBS/Al₂O₃ composites as compared to the neat PBS. The thermal conductivity of the composite (0.411?W?m^?1 K^?1) was more than twice that of neat PBS. The composite containing polymerization-modified alumina showed a 50% increase in storage modulus compared with that of neat PBS. In addition, universal testing machine (UTM) and differential scanning calorimetry (DSC) measurements indicated an increase in the tensile strength and degree of crystallinity after the incorporation of modified alumina in the PBS/Al₂O₃ composite.