Design of a Web Based Underwater Acoustic Communication Testbed and Simulation Platform

Wireless Personal Communications - Underwater Wireless Sensor Networks (UWSNs) are playing a vital role in exploring the unseen underwater (UW) natural resources. However, performance evaluation of...     

Synthesis and thermomechanical characterization of polyurethane elastomers extended with α,ω‐alkane diols

A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, ¹H‐NMR, and ¹³C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Alkaline fuel cells: contemporary advancement and limitations

ZeTek Power recently introduced mass manufacturable and cost effective alkaline fuel cells on the market. Today's research is focused on further improvement both in terms of performance increase and cost reduction. This research is classically performed using small (4 cm²) experimental electrodes in the half-cell configuration. This allows the primary electrochemical losses in an anode or cathode to be determined independently. Additional performance losses occur when one integrates large electrodes into a module of 24 cells and in a stack comprised of many modules. By comparing the performance of half-cell experiments to that of modules, these losses can be distinguished and addressed. The information thus obtained, both for the small electrodes and in up-scaling is vital if one is to identify the key areas in which improvement is possible and where to focus future research. Furthermore, the identification of the losses in a module and system allows us to predict the final performance from half-cell measurements of a new laboratory scale experimental electrode.     

Semi- and fully interpenetrating polymer networks based on polyurethane–polyacrylate systems. VI. Polyurethane–poly(methyl acrylate-co-ethyl acrylate) semi-1-interpenetrating polymer networks

Dynamic mechanical and longitudinal sonic velocity measurements have been made on a series of semi-1-IPNs in which the network component is a polyurethane and the linear constituent a copolymer of methyl acrylate and ethyl acrylate. Dynamic mechanical analysis reveals phase separation. The shifting of the polyurethane glass transition in both the tan δ? and the E″–temperature plots indicates that some mixing occurs. The longitudinal sonic velocity results indicate that the polyurethane is present as a continuous phase in all the materials investigated.     

Direct analysis of annealing of nodular crystals in isotactic polypropylene by atomic force microscopy, and its correlation with calorimetric data

The process of isothermal annealing of nodular monoclinic crystals of isotactic polypropylene (iPP) was analyzed by atomic force microscopy (AFM) and temperature-modulated differential scanning calorimetry (TMDSC). Initially nodular and mesomorphic domains were obtained by controlled melt-crystallization at high cooling rate. Subsequent heating triggers transition from mesomorphic to monoclinic structure, and melting of unstable nodules. Annealing allows re-crystallization, which is recognized by enlargement of domains from initially about 20 nm to about 35 and 55 nm after annealing at 393 and 433 K, respectively. Furthermore, the re-crystallization process is connected with a slight change of the aspect ratio of crystals. The isothermal re-crystallization of the liquid is superimposed by aggregation of crystals, to yield blocky, and string-like objects. The direct analysis of structure on isothermal annealing by AFM is for the first time compared with the isothermal decrease of the apparent specific heat capacity, or change of enthalpy, monitored by TMDSC. The apparent specific heat capacity decreases during annealing with an identical non-linear time dependence as the directly observed growth of the crystal size. Analysis of the annealing processes at different temperatures yields proportionality between the increase of the crystal size and the reduction of the apparent specific heat capacity.     

DeepClassRooms: a deep learning based digital twin framework for on-campus class rooms

Neural Computing and Applications - A lot of different methods are being opted for improving the educational standards through monitoring of the classrooms. The developed world uses Smart...     

Abiotic stress of ZnO‐PEG,ZnO‐PVP,CuO‐PEG and CuO‐PVP nanoparticles enhance growth,sweetener compounds and antioxidant activities in shoots of Stevia rebaudiana Bertoni

Nanoparticles are known to play remarkable role as abiotic stress elicitors in plants. This study reports the comparative analysis of effects produced by capped [zinc oxide (ZnO)‐polyethylene glycol (PEG), ZnO‐polyvinyl pyrrolidone (PVP), copper oxide (CuO)‐PEG, CuO‐PVP] and uncapped (ZnO and CuO) nanoparticles on the medicinal plant, Stevia rebaudiana raised in vitro for the production of commercially important sweetener compounds. In context of shoot organogenesis, ZnO‐PEG, ZnO‐PVP, CuO‐PEG, CuO‐PVP were employed to the growth medium that resulted in increased growth parameters, and larger content of steviol glycosides as compared to the shoots raised in medium containing ZnO and CuO, revealed by high‐performance liquid chromatography. In the meanwhile, non‐enzymatic antioxidant activities including total phenolic content, total flavonoid content, total antioxidant capacity, total reducing power and 2,2‐diphenyl‐1‐picryl hydrazyl‐free radical scavenging activity were calculated and showed comparatively greater amounts in shoots grown in medium containing capped ZnO or CuO nanoparticles. Furthermore, the ZnO and its derivatives revealed to be more reactive at 1 mg/l of concentration. Whereas, the CuO and its derivatives produced greater response on Stevia at 10 mg/l concentration of nanoparticles. This study paves the way for more such studies encompassing capped and uncapped nanoparticles and their ultimate effect on in‐vitro grown plant tissues for the production of active metabolites on industrial scale.Inspec keywords: nanoparticles, chromatography, resins, polymers, zinc compounds, copper compounds, food technology, agricultureOther keywords: nanoparticles, sweetener compounds, antioxidant activities, Stevia rebaudiana Bertoni, abiotic stress elicitors, zinc oxide‐polyethylene glycol, zinc oxide‐polyvinyl pyrrolidone, copper oxide‐polyethylene glycol, medicinal plant, shoot organogenesis, steviol glycosides, high‐performance liquid chromatography, nonenzymatic antioxidant activities, total phenolic content, total flavonoid content, total antioxidant capacity, total reducing power, 2,2‐diphenyl‐1‐picryl hydrazylfree radical scavenging activity, derivatives, active metabolite production, copper oxide‐polyvinyl pyrrolidone     

Biofilm reduction,cell proliferation,anthelmintic and cytotoxicity effect of green synthesised silver nanoparticle using Artemisia vulgaris extract

Infectious diseases are caused by etiological agents. Nanotechnology has been used to minimise the effect of clinical pathogens which have resistance to antibiotics. In current research synthesis, characterisation and biological activities of green synthesised nanoparticles using Artemisia vulgaris extract have been done. The characterisation of AgNPs was carried out using Fourier transform infrared spectroscopy, UV‐Vis spectrophotometry, and scanning electron microscopy. Anti‐biofilm, cell viability, antibacterial, brine shrimp lethality, and deoxyribonucleic acid protection effects have been screened. UV‐Vis spectra showed the absorption peak of synthesised nanoparticles at 400 nm. FT‐IR indicated the involvement of the functional group in the preparation of AgNPs. SEM showed the spherical shape of AgNPs with 30 nm diameter. Biological screening results revealed the antibacterial effect against clinical bacterial pathogens. Biofilm reduction and cell viability assay also supported the antibacterial effect. Cytotoxicity effect was recorded as 100% at 200 μg/ml through brine shrimp lethality assay. Protein kinase inhibition zones recorded for AgNPs (16 mm bald) compared with A. vulgaris extract (11 mm bald). It has been concluded that green synthesised AgNPs are more effective against infectious pathogens and could be used as a potential source for therapeutic drugs.Inspec keywords: cellular biophysics, toxicology, silver, nanoparticles, nanomedicine, diseases, microorganisms, ultraviolet spectra, visible spectra, Fourier transform infrared spectra, enzymes, molecular biophysicsOther keywords: biofilm reduction, cell proliferation, anthelmintic effect, cytotoxicity effect, green synthesised silver nanoparticle, Artemisia vulgaris extract, infectious diseases, aetiological agents, Fourier transform infrared spectroscopy, UV‐Vis spectrophotometry, scanning electron microscopy, SEM, antibiofilm, cell viability, brine shrimp lethality, deoxyribonucleic acid protection effects, AgNP, cytotoxicity, protein kinase inhibition zones, therapeutic drugs