Preparation of Silver Nanowires via a Rapid,Scalable and Green Pathway

Rapid synthesis of silver nanowires(Ag NWs) with high quality and a broad processing window is challenging because of the low selectivity of the formation of multiply twinned particles at the nucleation stage for subsequent Ag NWs growth.Herein we report a systematic study of the water-involved heterogeneous nucleation of Ag NWs with high rate(less than 20 min) in a simple and scalable preparation method.Using glycerol as a reducing agent and a solvent with a high boiling point,the reaction is rapidly heated to 210 ℃ in air to synthesize Ag NWs with a very high yield in gram level.It is noted that the addition of a small dose of water plays a key role for obtaining highly pure Ag NWs in high yield,and the optimal water/glycerol ratio is0.25%.After investigating a series of forming factors including reaction temperature and dose of catalysts,the formation kinetics and mechanism of the Ag NWs are proposed.Compared to other preparation methods,our strategy is simple and reproducible.These Ag NWs show a strong Raman enhancement effect for organic molecules on their surface.     

金属镱低压吸氘研究

在真空系统中的氘压低于0.1 MPa条件下研究了金属镱的吸氘性能,并对不同原子比的氘化物的物相进行了分析.在常压、300 ℃下,金属镱吸氘不明显;400 ℃时,金属镱经较长时间活化后吸附一定量的氘;500 ℃时,镱升华.400 ℃时的吸氘实验结果表明:从活化至开始吸氘直至吸附平衡需很长时间;氘/镱原子比的高低与吸氘时间有关,饱和吸氘时的原子比最大为2.00;金属镱为面心立方(fcc)结构,a0=0.549 2 nm.具有不同原子比的氘化镱的X射线衍射(XRD)分析结果显示:氘化镱有2种结构,即面心立方结构(a0=0.524 nm)和正交结构(a0=0.588 nm、b0=0.358 nm、c0=0.678 nm);金属镱吸氘后,立方结构氘化镱晶格常数及晶胞体积均发生收缩现象,收缩率分别约为4%和11%.正交结构氘化镱晶胞体积收缩约14%.     

小眼井最优水力学设计及分析

在充分考虑小眼井钻井特点和合理确定环空压耗的基础上，将喷射钻井理论和环空携岩理论有机结合起来，导出了在两种工作方式下优化设计小眼井钻井水力参数模型，并开发了应用软件。通过实例计算，提出了在小眼井最优水力学设计中采用最大水功率工作方式的重要性，并建议在大眼井的水力参数设计中考虑钻柱的偏心、旋转和钻杆接头对环空压耗的影响。     

Exact solution of elasto-plastic stresses in a metal-matrix composite beam of arbitrary orientation subjected to transverse loads

An analytical elasto-plastic stress analysis is presented for a metal-matrix composite beam of arbitrary orientation subjected to a single transverse force applied to the free end of the beam and a uniformly distributed load. The material is assumed to be perfectly plastic in the elasto-plastic solution. A composite consisting of stainless-steel-reinforced aluminum was produced for this work. Sample problems are given for various orientation angles. Elastic, elastoplastic and residual normal and shear stresses are calculated. The location of the elasto-plastic boundary of the beam is obtained according to the x coordinates of the beam.     

热塑性塑料管材抗蠕变性能评价

描述了热塑性塑料管材的抗蠕变性及其有关的评价方法，介绍了几种标准测试方法。     

Identification environment and robust forecasting for nonlinear time series

In this paper, the methods of time series for nonlinearity are briefly surveyed, with particular attention paid to a new test design based on a neural network specification. The proposed integrated expert system contains two main components: an identification environment and a robust forecasting design. The identification environment can be viewed as a integrated dynamic design in which cognitive capabilities arise as a direct consequence of their self-organizational properties. The integrated framework used for discussing the similarities and differences in the nonlinear time series behavior is presented. Moreover, its performance in prediction proves to be superior than the former work. For the investigation of robust forecasting, we perform a simulation study to demonstrate the applicability and the forecasting performance.     

Effect of a crack on strength of fibre-reinforced plastics

In unidirectionally reinforced composites with an elastic-plastic matrix, there is a plastic zone with lengthY ₀ proportional to the crack lengthC (Y ₀ C) at the tip of a crack. This results in a new logarithmic dependence of glass and aramid PABI fibre-reinforced plastics (FRP) on crack length and non-fulfilment of the Griffith criterion. In glass and PABI FRP without an artificial notch, defects already exist equivalent to a crack with a length depending on composite fabrication practice. In GFRP, the epoxy matrix shear yield stress grows 2.0 to 2.5 times, compared to the yield in thin films due to fibre constraint of matrix yielding. The stress distribution in front of a crack in a highly anisotropic composite with an elastic-plastic matrix is derived. The stress concentration at the tip of a crack grows with increasing matrix yield stress, resulting in a change of failure mode from accumulation of fibre breaks at low matrix strength, to brittle failure at high matrix strength. The following factors lead to composite embrittlement: (1) increase of matrix yield stress and composite shear strength; (2) decrease of temperature; (3) increase of Young's modulus of the fibre; (4) reduction of fibre strength. The dependence of aramid PPTA FRP strength on temperature exhibits a maximum. Epoxy matrix plastification leads to some increase of aramid PPTA FRP strength.     

连锁快餐企业的顾客满意度评价模型

从品牌、产品、服务和环境等方面建立基于证据推理的连锁快餐企业顾客满意度评价模型。为反映不同店面顾客满意度的差异,依据营业额设定店面权重,将各店面的评价结果作为证据集结出总体满意度。抽样调查安徽省某知名连锁快餐企业的七家分店,获取其一周的问卷数据。通过仿真试验,验证了模型的有效性和实用性,对比两种模型的试验结果,并对企业经营提出了一些建议。     

Zr对Cu—Zn—Al形状记忆合金相变的影响

采用示差扫描热分析(DSC)、X射线衍射及透射电镜,研究了Zr对Cu-Zn-Al合金高温相变、马氏体正逆转变以及形状记忆效应的影响。结果表明,添加Zr0.35wt-％时,能有效地抑制α,γ相析出,促进β_2→DO_3→18RM转变。(M_s-M_f)及(A_s-A_f)温度区间较窄,马氏体相变激活能最低,马氏体变体间界面的可动性好,形状记忆效应最佳。