Structure and electrical properties of Ca2+-doped (Na0.47Bi0.47Ba0.06)TiO3 lead-free piezoelectric ceramics

The lead-free piezoelectric ceramics (Na_.47Bi_.47Ba_.06)_1-xCa_xTiO₃ (x?=?0, 0.01, 0.02, 0.03, 0.05, and 0.08, abbreviated as BNBTC/0, BNBTC/1, BNBTC/2, BNBTC/3, BNBTC/5, and BNBTC/8, respectively) were obtained using the solid-state reaction method. The structure, electric conductivity, and dielectric, ferroelectric, and piezoelectric properties of the Ca²⁺-doped (Na_.47Bi_.47Ba_.06)TiO₃ ceramics were thoroughly investigated. The ceramics sintered at 1200?°C exhibit dense microstructures, having relative densities higher than 96%. The X-ray diffraction results demonstrate that all ceramics have a pure perovskite structure. The mean grain sizes of the ceramics are related to the Ca²⁺ quantity. A small quantity of Ca²⁺ ions (x?≤?0.03) improves the piezoelectric and ferroelectric properties of the samples. The dielectric behavior of the samples is sensitive to the Ca²⁺ content and electric poling. The results demonstrate that the electrical properties of the (Na_.47Bi_.47Ba_.06)TiO₃ lead-free ceramics can be well tuned by varying the Ca²⁺ quantity.     

GIS在深圳市三防指挥信息系统中的应用

深圳市三防指挥信息系统利用GIS技术,结合水利(水务)、防汛、抗旱的具体业务,建立了水情遥测数据处 理分系统、工况监测数据处理分系统、水务行业三防信息管理分系统、决策支持分系统、水源优化调度分 系统,提高了现代化管理水平。     

溶剂浸渍树脂的萃取分离性能研究

介绍了溶剂浸渍树脂的制备及性能,阐述了溶剂浸渍树脂在产物提纯和废水处理等分离过程中的应用,并对使用溶剂浸渍树脂处理含酚废水进行了初步研究.     

介孔分子筛SBA-15表面的胺基功能化

采用γ-胺丙基三甲氧基硅烷与表面硅羟基的反应,对介孔分子筛SBA-15进行了有机胺功能化,并对其进行了表征.XRD、SEM、比表面积测定、元素分析、TG和FT-IR的测定结果均表明,SBA-15表面成功地接枝上了有机胺功能基团,而六方结构特征基本保持.     

通信性能评估的仿真实验研究

研究了流量控制和差错控制对通信性能的综合影响，着重分析了停止-等待协议和连续ARQ协议的优缺点，讨论了信道利用率和帧长的关系。介绍了几种多点接人技术的基本原理，如CSMA和CSMA／CD，并给出了各自相应的性能仿真曲线。所设计的通信性能评估实验，仿真界面形象丰富，与实验知识点紧密结合，可以大大提高实验教学的效率和质量。     

起升中四腿落地式K型井架及底座的应力分析

针对在用四腿落地式K型井架在起升中井架与底座存在的问题,文章以JJ162/42-K型井架为例,采用I-DEAS有限元软件对起升过程中处于各角度时的井架及底座做了应力分析,并将其结果与两腿落地式K型井架进行了比较。分析表明,四腿落地式K型井架及底座在井架刚起升时,应力值较大,存在安全隐患。为了增强在井架起升过程中底座的安全性,建议在底座上井架2个铰支座之间加焊加强钢板,并加大井架前立柱铰支座的尺寸。     

Deformation evolution during initiation of transgranular stress corrosion cracking

Face centered cubic metals and alloys have multiple slip systems and are characterized by high dislocation velocities. Nevertheless, these materials suffer from transgranular stress corrosion cracking (T-SCC), that occurs by environmentally-induced cleavage. Since plasticity precedes fracture in all T-SCC phenomena, the evolution of deformation patterning during T-SCC is an important element of the local microfracture mode. Experimental observations show that the presence of the SCC-causing environment during straining is promoting localized plastic deformation at the near-surface region and producing an entirely different deformation pattern compared with that developing in laboratory air. The deformation evolving in the presence of the SCC electrolyte is highly localized, exhibiting closely spaced, coarse slip bands. The amount of localized strain developing at the near-surface region prior to nucleation of stress corrosion cracks is equivalent to the strain required for ductile fracture of the material in air, suggesting the existence of a fundamental fracture criterion. The above phenomenology of the deformation evolution is considered in relation to T-SCC initiation and propagation. The T-SCC is suggested to be a macroscopically brittle but microscopically ductile fracture occurring by localized plastic flow. An environment-induced deformation localization mechanism is described where the role of the environment involves generation of vacancies and subsequent dislocation nucleation from the near-surface region at loads well below those required for normal yielding. The evolution of the localized deformation pattern during T-SCC is suggested to be an outcome of nonuniformity and periodicity in the dissolution process.Presented at Fourth Greek National Congress on Mechanics, 26–29 June 1995, held at Xanthi, Greece.