Improved formic acid oxidation using electrodeposited Pd–Cd electrocatalysts in sulfuric acid solution

In the present research, nanostructured Pd–Cd alloy electrocatalysts with different compositions were produced using the electrodeposition process. The morphology of the samples was studied by scanning electron microscopy analysis. Also, the elemental composition of the samples was determined by energy-dispersive X-ray spectroscopy and elemental mapping tests. Tafel polarization and electrochemical impedance spectroscopy methods were employed to determine the electrochemical corrosion properties of the synthesized samples in a solution containing 0.5 M sulfuric acid and 0.1 M formic acid. The linear sweep voltammetry, cyclic voltammetry, and chronoamperometry techniques were also employed to evaluate the electrocatalytic activity of prepared samples toward the oxidation of formic acid. In this respect, the influence of some factors such as formic acid and sulfuric acid concentrations and also potential scan rate was investigated. Compared to the pure Pd sample, the Pd–Cd samples were more reactive for the oxidation of formic acid. Besides, the sample with a lower amount of Pd (Pd_1·3Cd) demonstrated much higher electrocatalytic activity than the Pd_7·1Cd and Pd_2·1Cd samples. The observed high mass activity of 15.06 A mg^?1_Pd for the Pd_1·3Cd sample which is 21.1 times higher than Pd/C is an interesting result of this study.     

Semi-supervised model adaptation for statistical machine translation

Statistical machine translation systems are usually trained on large amounts of bilingual text (used to learn a translation model), and also large amounts of monolingual text in the target language (used to train a language model). In this article we explore the use of semi-supervised model adaptation methods for the effective use of monolingual data from the source language in order to improve translation quality. We propose several algorithms with this aim, and present the strengths and weaknesses of each one. We present detailed experimental evaluations on the French–English EuroParl data set and on data from the NIST Chinese–English large-data track. We show a significant improvement in translation quality on both tasks.     

Optimizing the Runoff Estimation with HEC-HMS Model Using Spatial Evapotranspiration by the SEBS Model

Most of the commonly used hydrological models do not account for the actual evapotranspiration (ETa) as a key contributor to water loss in semi-arid/arid regions. In this study, the HEC-HMS (Hydrologic Engineering Center Hydrologic Modeling System) model was calibrated, modified, and its performance in simulating runoff resulting from short-duration rainfall events was evaluated. The model modifications included integrating spatially distributed ETa, calculated using the surface energy balance system (SEBS), into the model. Evaluating the model’s performance in simulating runoff showed that the default HEC-HMS model underestimated the runoff with root mean squared error (RMSE) of 0.14 m³/s (R²?=?0.92) while incorporating SEBS ETa into the model reduced RMSE to 0.01 m³/s (R²?=?0.99). The integration of HECHMS and SEBS resulted in smaller and more realistic latent heat flux estimates translated into a lower water loss rate and a higher magnitude of runoff simulated by the HECHMS model. The difference between runoff simulations using the default and modified model translated into an average of 95,000 m³ runoff per rainfall event (equal to seasonal water requirement of ten-hectare winter wheat) that could be planned and triggered for agricultural purposes, flood harvesting, and groundwater recharge in the region. The effect of ETa on the simulated runoff volume is expected to be more pronounced during high evaporative demand periods, longer rainfall events, and larger catchments. The outcome of this study signifies the importance of implementing accurate estimates of evapotranspiration into a hydrological model.

     

Learning nonlinear dynamics with behavior ordinary/partial/system of the differential equations: looking through the lens of orthogonal neural networks

In this paper, size-dependent dynamic stability of axially loaded functionally graded (FG) composite truncated conical microshells with magnetostrictive facesheets surrounded by nonlinear viscoelastic foundations including a two-parameter Winkler–Pasternak medium augmented via a Kelvin–Voigt viscoelastic approach is analyzed considering nonlinear cubic stiffness. To this purpose, von Karman-type kinematic nonlinearity along with modified couple stress theory of elasticity was applied to third-order shear deformation conical shell theory in the presence of magnetic permeability tensor and magnetic fluxes. The numerical technique of generalized differential quadrature (GDQ) was used for the solution of microstructural-dependent dynamic stability responses of FG composite truncated conical microshells. It was seen that moving from prebuckling to postbuckling domain somehow increased the significance of couple stress type of size dependency on frequency. In addition, within both prebuckling and postbuckling regimes, an increase of material gradient index decreased the importance of couple stress type of size dependency on the frequency of an axially loaded FG composite truncated conical microshell. Furthermore, it was revealed that by applying a positive magnetic field to an axially loaded truncated conical microshell with magnetostrictive facesheets, its frequency at a specific axial load value was increased in prebuckling domain and decreased in postbuckling domain. However, this pattern was reversed by applying a negative magnetic field.

     

Application of ANFIS for modeling of layer thickness of chromium carbonitride coating

In the present work, layer thickness of duplex coating made from thermo-reactive deposition and diffusion has been predicted by Adaptive network-based fuzzy inference systems (ANFIS). A duplex surface treatment on five steels has been developed involving nitrocarburizing and followed by chromium thermo-reactive deposition (TRD) techniques. The TRD process was performed in molten salt bath at 550, 625 and 700 °C for 1–30 h. The process formed a thickness up to 9.5 μm of chromium carbonitride coatings on a hardened diffusion zone. A model based on ANFIS for predicting the layer thickness of duplex coating of the specimens has been presented. To build the model, training and testing using experimental results from 84 specimens were conducted. The data used as inputs in ANFIS models are arranged in a format of twelve parameters that cover the chemical composition (C, Mn, Si, Cr, Mo, V, W), the pre-nitriding time, ferro-chromium particle size, ferro-chromium weight percent, salt bath temperature and coating time. According to these input parameters, in the Adaptive network-based fuzzy inference system models, the layer thickness of duplex coating of each specimen was predicted. The training and testing results in ANFIS models have shown a strong potential for predicting the layer thickness of duplex coating.     

In‐stream construction‐induced suspended sediment in riverine ecosystems

Construction activities within the wetted‐perimeter of rivers, referred to as in‐stream construction, are prevalent economically and environmentally motivated activities having direct interactions with sensitive lotic environments. Currently, there is a paucity of research related to in‐stream construction activities and their effects on aquatic ecosystems. In‐stream construction‐induced suspended sediment may result in harmful effects to aquatic flora and fauna. Regulatory frameworks worldwide focus primarily on concentration, with limited consideration for duration and no consideration for spatial extents of suspended sediment exposures. This research develops theoretical concentration, duration, and spatial extent exposure risk relationships for riverine ecosystems to demonstrate the influence of each mechanism during typical in‐stream construction activities. To reduce exposure risk, concentration and duration may be considered pragmatically, based on anticipated activity characteristics and site conditions. Spatial exposure characteristics are important to consider, as illustrated by our finding that activities located near the channel centerline may result in greater exposure risk than similar activities conducted near the streambank. Current regulatory frameworks worldwide do not sufficiently consider all exposure risk mechanisms present during in‐stream construction‐induced suspended sediment releases, possibly inhibiting efforts to reduce adverse environmental effects. This research improves our understanding of suspended sediment in lotic environments and may help environmental managers better evaluate and manage in‐stream construction activities.     

A model to predict the solubility and permeability of gaseous penetrant in the glassy polymeric membrane at high pressure

In this work, the transport properties of gaseous penetrant through several dense glassy polymeric membranes are studied. The nonequilibrium lattice fluid (NELF) in conjunction with the modified Fick's law and dual mode sorption model was used to simulate the gas transport in glassy polymeric membranes. The approach is based on the sorption, diffusion, in which solubility is calculated based on the NELF model, and diffusion coefficient is obtained from the product thermodynamic coefficient and molecular mobility. The governing equation is solved by the finite element method using COMSOL multi-physics software. The developed model for gas permeability of glassy polymeric membrane can be applied in a wide range of pressure and temperature. The comparison of the calculated permeability and solubility of gasses with the experimental data represented the ability of the developed model. Increasing feed gas temperature increases the gas permeability, while this variation leads to lower gas solubility in the glassy polymeric membranes. The effect of feed temperature and pressure on permeability and solubility is investigated, and the experimental data from literature are described by the developed model. A good prediction of the experimental data can be observed over the considered condition.     

Abstraction and approximation in fuzzy temporal logics and models

Recently, by defining suitable fuzzy temporal logics, temporal properties of dynamic systems are specified during model checking process, yet a few numbers of fuzzy temporal logics along with capable corresponding models are developed and used in system design phase, moreover in case of having a suitable model, it suffers from the lack of a capable model checking approach. Having to deal with uncertainty in model checking paradigm, this paper introduces a fuzzy Kripke model (FzKripke) and then provides a verification approach using a novel logic called Fuzzy Computation Tree Logic* (FzCTL*). Not only state space explosion is handled using well-known concepts like abstraction and bisimulation, but an approximation method is also devised as a novel technique to deal with this problem. Fuzzy program graph, a generalization of program graph and FzKripke, is also introduced in this paper in consideration of higher level abstraction in model construction. Eventually modeling, and verification of a multi-valued flip-flop is studied in order to demonstrate capabilities of the proposed models.     

A C5 parallel robot identification and control

The paper proposes a controller scheme based on a priori identification for a C5 parallel robot. First we realize the identification of dynamic parameters of the robot using the Least Squares technique. Different data are used for this step of identification. The cross validation permitted to select and confirm the identified parameters. After, a control scheme (computed torque) is applied to control the C5 parallel robot. The functions of this control scheme are based on precedent identified parameters. In order to reduce the effect of the identification error, we have added a robustness term based on sliding mode technique. The stability of the system in closed loop is presented using the Lyapunov principle. Experimental results of identification and control are presented and show the effectiveness of our methodology.