Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present. 相似文献
The experimental researches on the chemical deposition of Ni-Mo-P amorphous alloys were carried out by adding Na2 MoO4 into acidic solutions. The optimum technology conditions were obtained by orthogonal design experiments. The structures and the relationship between compositions and their thermal stability were studied by energy spectrum (EC), scanning electron micrograph and X-ray diffraction spectrum. Compared with Ni-P amorphous alloys, the Ni-Mo-P amorphous alloys have high crystallization temperature and thermal stability, and the hardness reaches its peak when the annealing temperature is 500 ℃. With the increase of the heat treatment temperature, the surface morphology of the alloys changes. 相似文献
The rapid growth of video data demands both effective and efficient video summarization methods so that users are empowered to quickly browse and comprehend a large amount of video content. In this paper, we formulate the video summarization task with a novel minimum sparse reconstruction (MSR) problem. That is, the original video sequence can be best reconstructed with as few selected keyframes as possible. Different from the recently proposed convex relaxation based sparse dictionary selection method, our proposed method utilizes the true sparse constraint L0 norm, instead of the relaxed constraint L2,1 norm, such that keyframes are directly selected as a sparse dictionary that can well reconstruct all the video frames. An on-line version is further developed owing to the real-time efficiency of the proposed MSR principle. In addition, a percentage of reconstruction (POR) criterion is proposed to intuitively guide users in obtaining a summary with an appropriate length. Experimental results on two benchmark datasets with various types of videos demonstrate that the proposed methods outperform the state of the art. 相似文献
Bartels–Stewart algorithm is an effective and widely used method with an O(n3) time complexity for solving a static Sylvester equation. When applied to time-varying Sylvester equation, the computation burden increases intensively with the decrease of sampling period and cannot satisfy continuous realtime calculation requirements. Gradient-based recurrent neural network are able to solve the time-varying Sylvester equation in real time but there always exists an estimation error. In contrast, the recently proposed Zhang neural network has been proven to converge to the solution of the Sylvester equation ideally when time goes to infinity. However, this neural network with the suggested activation functions never converges to the desired value in finite time, which may limit its applications in realtime processing. To tackle this problem, a sign-bi-power activation function is proposed in this paper to accelerate Zhang neural network to finite-time convergence. The global convergence and finite-time convergence property are proven in theory. The upper bound of the convergence time is derived analytically. Simulations are performed to evaluate the performance of the neural network with the proposed activation function. In addition, the proposed strategy is applied to online calculating the pseudo-inverse of a matrix and nonlinear control of an inverted pendulum system. Both theoretical analysis and numerical simulations validate the effectiveness of proposed activation function. 相似文献
Computational Economics - The study aims to analyze and forecast Internet financial risks based on the model based on deep learning and the Back Propagation Neural Network (BPNN). First, the theory... 相似文献
Owing to the strong affinity of thiols to Au and Ag, they are often employed to modify the surfaces of nanoparticles (NPs). Recently, these strong ligand-interface interactions have been employed to control NP growth, and this technique has emerged as a unique modulation strategy for creating unconventional plasmonic hybrid nanostructures. In these systems, the roles of the non-mercapto components of the thiol molecules and their structures are still unknown. Therefore, we herein present our investigation into this phenomenon. Primary amino (–NH2) groups in thiols are found to play a key role in regulating growth kinetics, i.e., in accelerating Ag deposition on Au NPs. The–NH2 groups are thought to bring Ag ions to the particle surface by coordinating to them, and thereby assist their reduction. The effect of molecular structure is non-trivial and thus provides the possibility of selective thiol detection. Based on the dependence of kinetic modulation on the non-mercapto components and molecular structures of molecules, we demonstrate the highly sensitive and specific detection of cysteine (limit of detection: 6 nM) in a mixture of 19 natural amino acids based on Ag growth on Au nanospheres. In addition, based on this modulation effect, we reveal the entrapping of chiral thiols within the growth layer through their plasmonic circular dichroism (PCD) responses. We believe that thiol-based growth regulation has great potential for creating plasmonic nanostructures with novel functionalities.