Frequency dependence of the complex dielectric constant of sodium carboxymethyl cellulose

The dielectric constant, ε′, and dielectric loss, ε″, were determined for three solid carboxymethyl cellulose samples having different levels of substitution and different degrees of polymerization over a frequency range of 0.1 – 10 000 kHz at temperatures from 10–60°C. In contrast to the two relaxation processes, γ and β, previously observed in native cotton cellulose, only one relaxation process within a frequency range of 0.1 – 1 kHz was identified. It was found that the dielectric properties do not only depend on the degree of substitution, but also on the weight-average degree of polymerization and uniformity of distribution.     

Iterative interference cancellation for high spectral efficiencysatellite communications

The problem of efficient utilization of the frequency spectrum for satellite systems is investigated; one which results as a consequence of highly crowding adjacent channels. An analytical characterization of the resulting interference channel is introduced and then exploited for interference cancellation. Two classes of cancelers are investigated. The first approach does not benefit from the forward error control (FEC) coding information which limits the performance gain. This motivates the second approach where a joint implementation of interference cancellation and decoding is developed using soft-input-soft-output (SISO) modules along with the iterative structure. It is shown that iterative interference cancellation techniques can achieve significant gains compared with the single-user matched filter receiver     

Physicochemical investigation of the decomposition products of ammonium metal carboxylates: ammonium ferric citrate hydrate

The thermal decomposition up to 400 °C of ammonium ferric citrate hydrate, of unknown structure and formula weight, was studied by thermogravimetry, differential thermal analysis, infrared (IR) spectroscopy and X-ray diffractometry. The possible identities of the formula weight and the intermediate products of calcination are discussed. The results revealed that the parent material is amorphous and contains two moles of water and two moles of ammonia. Decomposition takes place via six weight-loss processes, three endothermic (90–230 °C) and three exothermic (240–298 °C), leading eventually to the formation of Fe₂O₃. The intermediate solid products are mainly unstable amorphous oxycarbonates, as indicated by X-ray and IR spectroscopies. The gas-phase decomposition products identified by IR spectroscopy are NH₃, CO₂, CO, CH₃COCH₃, CH₄ and NH₄OH. Surface area measurement and scanning electron microscopy showed that Fe₂O₃, the final product at 400 °C, hada surface area of 40 m²/g and good crystalline and porous character.     

Modification of sandy soil using water‐borne polymer

A new polymeric system has been applied for structural modification of (noncompactable) sandy soils. The system is based on a water‐borne styrene acrylic polymeric formulation (emulsion) containing varying amounts of solid polymer. The present work deals with system optimization and measurements designed to examine the effects of polymer content on hydraulic conductivity and compressive strength. Samples were prepared from prescribed amounts of polymer, water, and sand by using two different preparations methods (mixing and spraying). Measurements of hydraulic conductivity for both sets of samples were conducted in a flexible membrane test apparatus. For the first set of samples, the permeability coefficient of the sand was noted to be reduced 10‐fold (from 10^?5 to 10^?6 m s^?1) upon the incorporation of about 2% polymer. In the second set (samples prepared with the spraying method), the hydraulic conductivity was further reduced to 7.2 × 10^?7 at a polymer concentration of about 2%. Stress–strain measurements made on dry cylindrical specimens disclosed remarkable enhancement in the mechanical behavior of the system. For both types of preparation methods, the compressive strength and modulus of elasticity increased linearly with the polymer concentration in the sample. Scanning electron microscopic examination revealed that the dramatic reduction in the permeability and the improved mechanical properties are attributed to the polymer coverage of the sand particles and the development of interconnecting ties between them. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2484–2491, 2003     

An efficient IoT based smart farming system using machine learning algorithms

Multimedia Tools and Applications - This paper suggests an IoT based smart farming system along with an efficient prediction method called WPART based on machine learning techniques to predict crop...     

Active XML-based Web data integration

Today, the Web is the largest source of information worldwide. There is currently a strong trend for decision-making applications such as Data Warehousing (DW) and Business Intelligence (BI) to move onto the Web, especially in the cloud. Integrating data into DW/BI applications is a critical and time-consuming task. To make better decisions in DW/BI applications, next generation data integration poses new requirements to data integration systems, over those posed by traditional data integration. In this paper, we propose a generic, metadata-based, service-oriented, and event-driven approach for integrating Web data timely and autonomously. Beside handling data heterogeneity, distribution and interoperability, our approach satisfies near real-time requirements and realize active data integration. For this sake, we design and develop a framework that utilizes Web standards (e.g., XML and Web services) for tackling data heterogeneity, distribution and interoperability issues. Moreover, our framework utilizes Active XML (AXML) to warehouse passive data as well as services to integrate active and dynamic data on-the-fly. AXML embedded services and changes detection services ensure near real-time data integration. Furthermore, the idea of integrating Web data actively and autonomously revolves around mining events logged by the data integration environment. Therefore, we propose an incremental XML-based algorithm for mining association rules from logged events. Then, we define active rules dynamically upon mined data to automate and reactivate integration tasks. Finally, as a proof of concept, we implement a framework prototype as a Web application using open-source tools.     

Image Super Resolution and Enhancement Using E-spline

E-splines （Exponential spline） polynomials represent the best smooth transition between continuous and discrete domains. As they are constructed from convolution of exponential segments, there are many degrees of freedom to optimally choose the most convenient E-spline, suitable for a specific application. In this paper, the parameters of these E-splines were optimally chosen, to enhance the performance of image zooming and interpolation schemes. The proposed technique is based on minimizing the total variation function of the detail coefficients of the E-spline based wavelet decomposition. In zooming applications, the quality of interpolated images are further improved and sharpened by applying ICA technique to them, in order to remove any dependency. Illustrative examples are given to verify image enhancement of the proposed E-spline scheme, when compared with the existing approaches.     

Royal Crown Shaped Polarization Insensitive Perfect Metamaterial Absorber for C-, X-, and Ku-Band Applications

This study proposed a new royal crown-shaped polarisation insensitive double negative triple band microwave range electromagnetic metamaterial absorber (MA). The primary purpose of this study is to utilise the exotic characteristics of this perfect metamaterial absorber (PMA) for microwave wireless communications. The fundamental unit cell of the proposed MA consists of two pentagonal-shaped resonators and two inverse C-shaped metallic components surrounded by a split ring resonator (SRR). The bottom thin copper deposit and upper metallic resonator surface are disjoined by an FR-4 dielectric substrate with 1.6 mm thickness. The CST MW studio, a high-frequency electromagnetic simulator has been deployed for numerical simulation of the unit cell in the frequency range of 4 to 14 GHz. In the TE mode, the offered MA structure demonstrated three different absorption peaks at 6.85 GHz (C-band), 8.87 GHz (X-band), and 12.03 GHz (Ku-band), with 96.82%, 99.24%, and 99.43% absorptivity, respectively. The electric field, magnetic field, and surface current distribution were analysed using Maxwell’s-Curl equations, whereas the angle sensitivity was investigated to comprehend the absorption mechanism of the proposed absorber. The numerical results were verified using the Ansys HFSS (high-frequency structure simulator) and ADS (advanced design system) for equivalent circuit models. Moreover, the proposed MA is polarisation and incident angle independent. Hence, the application of this MA can be extended to a great extent, including airborne radar applications, defence, and stealth-coating technology.     

Inhibition effect of a synthesized N, N＇-bis（2-hydroxybenzaldehyde）- 1, 3-propandiimine on corrosion of mild steel in HC1

The corrosion inhibition of mild steel in 1 mol/L HCl by N, N′-bis (2-hydroxybenzaldehyde)-1, 3-propandiimine (2-HBP) has been investigated by using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and chronoamperometry measurements. The experimental results suggest that this compound is an excellent corrosion inhibitor for mild steel and the inhibition efficiency increases with the increase in inhibitor concentration. Polarization curves reveal that this organic compound is a mixed type inhibitor. The effect of temperature on the corrosion behavior of mild steel with the addition of the Schiff base was studied in the temperature range from 25℃ to 65℃. The experimentally obtained adsorption isotherms follow the Langmuir equation. Activation and thermodynamic adsorption parameters such as E a , ΔH, ΔS, K ads and ΔG ads were calculated by the corrosion currents at different temperatures and using the adsorption isotherm. The morphology of mild steel surface in the absence and presence of 2-HBP was examined by atomic force microscope (AFM) images.