石蜡光氯化合成氯蜡－70的研究──（Ⅲ）反应过程致色因素考察及生色机理研究

氯蜡－７０是—应用广泛、性能优良的精细化工产品，其色泽是—重要的技术指标，直接影响着产品的质量和应用。本文考察了合成反应过程导致生色的因素，指出原料中含有的少量环烷烃、芳烃、杂环有机物及少量无机杂质能影响产品的色泽，实验表明温度过高，光源波长选择不当也是致色的重要原因。研究了致色的过程，提出其生色历程是按照β－消除反应机理进行的，并做了具体描述。     

单井注水吞吐在塔河油田的应用

在塔河油田开发生产过程中，个别油井在修井作业中出现先漏后喷的现象。在修井完成后，产量较前期有大幅增加。针对这类油井进行单井注水吞吐采油试验，研究发现钻遇定容封闭性油藏的油井适合单井注水吞吐开采。一方面利用油水重力分异，抬升油水界面，增加采出量；另一方面注水补充地层能量，恢复地层压力。该方法在塔河油田实际应用中，取得了较好的效果和较高的经济效益，也为提高定容封闭性油藏油井的采收率提供了一个较好的方法。     

氯化法TiCl4氧化制备TiO2中气体混合研究

氯化法钛白生产中的核心技术是TiCl4气相氧化反应过程.氧化反应器是氯化法钛白生产中的核心设备,氧化反应器中射流环的开孔结构直接影响TiCl4与O2的混合效果.采用计算流体力学(CFD)的方法,研究了5种不同射流环结构对流体混合效果的影响,获得了TiCl4气体在反应管内的径向浓度分布情况,以及TiCl4与O2混合的不均匀度.结果表明,射流环开孔结构对物料的混合有显著的影响,组合开孔射流环的物料混合效果优于均匀开孔射流环,更有利于反应物流体TiCl4和O2实现快速均匀地混合.     

冬凌草硒多糖的制备及其抗氧化活性分析

以济源冬凌草为原料,水提得到冬凌草多糖,对多糖进行结构修饰制得冬凌草硒多糖.采用UV、FTIR、SEM、TGA、HPLC对冬凌草多糖以及硒多糖结构进行表征;通过1,1-二苯基-2-三硝基苯肼(DPPH)自由基法、2,2-联氮-二(3-乙基-苯并噻唑-6-磺酸)二铵盐(ABTS)自由基法、羟基自由基法以及还原能力测定4种方法对冬凌草多糖及其硒多糖的抗氧化活性进行探究.结果表明,冬凌草硒多糖中硒含量为1.35 mg/g.硒化修饰后,冬凌草多糖的基本骨架得到保留,单糖种类未发生改变,但分解温度降低、稳定性下降,多糖形貌也发生明显变化,球状与条状形貌增多,片状形貌减少.在体外抗氧化性实验中,当冬凌草硒多糖质量浓度为1.6 g/L时,对DPPH自由基、ABTS自由基、羟基自由基清除率分别为68.69％、86.90％、45.12％,均强于冬凌草多糖.     

1，1＇－二（1，3－二氧代长链烷基）二茂铁的合成与表征

用１，１＇－二乙酰基二茂铁与酯的Ｃｌａｉｓｅｎ缩合反应合成了５个新的１，１＇－二（１，３－二氧代长链烷基）二茂铁，其通式为Ｃ５Ｈ４ＦｅＣ５Ｈ４（ＣＯＣＨ２ＣＯＣｎＨ２ｎ＋１）２，ｎ＝５～９。通过元素分析、紫外－可见光谱、红外光谱、核磁共振氢谱和质谱对这些化合物进行了表征。结果表明，这些β－二酮仅以烯醇式存在。     

Study of thermally poled and corona charged poly(vinylidene fluoride) films

The effect of thermal poling and corona charging on the structure and characteristics of poly(vinylidene fluoride) films (PVDF) was investigated. The structure and chemical change of PVDF films with different polarizing treatments was examined using Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy, respectively. The characteristics including piezoelectric coefficients, ferroelectric hysteresis, and leakage current were measured. It was found that both polarized methods contribute to dramatic improvement on the piezoelectricity and ferroelectricity of PVDF films, while thermal poling leads to structure change with the generation of new carbon composition. The reason to cause leakage current was also analyzed. POLYM. ENG. SCI., 47:1344–1350, 2007. © 2007 Society of Plastics Engineers     

A comparative analysis of evolutionary and memetic algorithms for community detection from signed social networks

To detect communities in signed networks consisting of both positive and negative links, two new evolutionary algorithms (EAs) and two new memetic algorithms (MAs) are proposed and compared. Furthermore, two measures, namely the improved modularity Q and the improved modularity density D-value, are used as the objective functions. The improved measures not only preserve all properties of the original ones, but also have the ability of dealing with negative links. Moreover, D-value can also control the partition to different resolutions. To fully investigate the performance of these four algorithms and the two objective functions, benchmark social networks and various large-scale randomly generated signed networks are used in the experiments. The experimental results not only show the capability and high efficiency of the four algorithms in successfully detecting communities from signed networks, but also indicate that the two MAs outperform the two EAs in terms of the solution quality and the computational cost. Moreover, by tuning the parameter in D-value, the four algorithms have the multi-resolution ability.     

基于跨场景推理的事件关系检测方法

事件关系检测是一项面向事件之间逻辑关系的自然语言处理技术。事件关系识别的核心任务是以事件为基本语义单元,通过分析事件的篇章结构信息及语义特征,实现事件逻辑关系的深层检测。该文首次建立一套事件关系检测的任务和研究体系,包括任务定义、关系体系划分、语料采集与标注、评价方法等。同时,该文提出了一种跨场景推理的事件关系检测方法,该方法认为,具有相同事件场景的“事件对”,往往具有相同的事件关系类型。该文提出的基于跨场景推理的事件关系检测方法在针对四大类事件关系类型的检测精确率为54.21%。