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A NEW SIMULATION APPROACH TO THE ENTROPY-RELATED PROPERTIES OF FLUIDS——CHEMICAL POTENTIAL AND HELMHOLTZ FREE ENERGY OF HARD SPHERE FLUIDS 下载免费PDF全文
A new approach to the computation of entropy-related properties of fluids has been pre-sented.Application of the new technique to hard sphere fluids shows that it is capable of providingreliable estimates of such properties as the chemical potential and Helmholtz free energy,even athigh density where other existing methods are hardly applicable.The chemical potential of an infinitedilute component in hard sphere systems has been estimated,and compared with that calculated fromthe Carnahan-Starling equation. 相似文献
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CORRELATION OF DIFFUSION COEFFICIENTS FOR LIQUIDS AND DENSE FLUIDS WITH TEMPERATURE AND PRESSURE 下载免费PDF全文
On the basis of the free volume theory and activation energy concept,a fundamental equation whichtakes into account the effects of temperature and pressure has been developed.By introducing differentexpressions for the free volume and activation energy,several equations for fluid diffusion coefficients were derivedaccordingly.With the van der Waals free volume and intermal energy formula,a three-parameter model for fluiddiffusion coeffficients at moderate pressure was obtained.The grand average absolute deviation percent of 345data points (44 systems)for self-and infinite dilute inter-diffusivities is 2.32,against the results of the model ofCohen and Turnbull,4.13.In particular,by means of the modified Carnahan-Starling free volume equation,afour-parameter model with average abosolute deviation percent 2.64(30 systems,644 data points)for theestimation of dense fluid inter-and self-diffusivities at high pressures and in supercritical conditions was derived.The derived model is superior to the method of L 相似文献
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Four ZSM-5 zeolite catalysts with different Si/Al ratios for the catalytic cracking of C4 fractions to produce ethylene and propylene were prepared in this study.First,the adsorption isotherms of pure n-butane and butene-1 and their mixtures on these catalysts at 300K and p=0—100kPa were measured using the intelligent gravimetric analyzer.The experimental results indicate that the presence of Al can significantly affect the adsorption of butene-1 than that of n-butane on ZSM-5 zeolites.Then,the double Langmuir(DL)model was applied to study the pure gas adsorption on ZSM-5 zeolites for pure n-butane and butene-1.By combining the DL model with the ideal adsorbed solution theory(IAST),the IAST-DL model was applied to model the butene-1(1)/n-butane(2)binary mixture adsorption on ZSM-5 zeolites with different Si/Al ratios.The calculated results are in good agreement with the experimental data,indicating that the IAST-DL model is effective for the present systems.Finally,the adsorption over a wide range of variables was predicted at low pressure and 300K by the model proposed.It is found that the selectivity of butene-1 over n-butane increases linearly with the decrease of Si/Al ratio.A correlation between the selectivity and Si/Al ratio of the sample was proposed at 300K and p=0.08MPa. 相似文献
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Diffusion of pure H2, CO, N2,O2 and CH4 gases through nanoporous carbon membrane is investigated by carrying out non-equilibrium molecular dynamics (NEMD) simulations. The flux, transport diffusivity and activation energy for the pure gases diffusing through carbon membranes with various pore widths were investigated. The simulation results reveal that transport diffusivity increases with temperature and pore width, and its values have a magnitude of 10^-7 m^2·s^-1 for pore widths of about 0.80 to 1.21 nm at 273 to 300 K. The activation energies for the gases diffusion through the membrane with various pore widths are about 1-5 kJ·mol^-1, The results of transport diffusivities are comparable with that of Rao and Sircar (J. Membr. Sci., 1996), indicating the NEMD simulation method is a good tool for predicting the transport diffusivities for gases in porous materials, which is always difficult to be accurately measured by experiments. 相似文献
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本文简要评述了汽-液相平衡中估算和预测活度系数的方法的进展。对目前流行的局部组成模型,讨论了其分布函数和晶格理论,并为建立新的模型,介绍了计算机模拟结果。着重讨论了很多学者在提出具有多重推算功能的模型时所遇到的困难。最后指出:对于理论有效活度系数模型的建立,各种数据的测定、收集、编撰,无论是现在还是将来,都至关重要。 相似文献
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