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排序方式: 共有133条查询结果,搜索用时 31 毫秒
1.
A series of new polyamides 3a–d containing aryl-azo, ether and sulfone groups in the main chain were synthesized from bis[4-(4-aminophenoxy)phenyl sulfone]
1 and several azo aromatic diacyl chlorides 2a–d by the low temperature solution polycondensation technique. FTIR spectroscopy, nuclear magnetic resonance (NMR) and elemental
analyses confirmed the structure of these polymers. Owing to the aryl and amide groups in the main chain, these polymers exhibit
photochromic properties as well as excellent thermal stabilities. The transition temperatures (T
g) are between 242 and 265 °C, and the char yields at 800 °C in nitrogen atmosphere were above 39%. Based on incorporation
of flexible ether linkages and polar sulfone groups, the polyamides show desirable solubility in organic solvents such as
DMAc, N,N-dimethylformamide (DMF), N-methyl-2-pyrroidinone (NMP) and dimethylsulfoxide (DMSO). And it is exemplified that
polyamide containing 2 and 2′ substitutes performed better solubility.
Funded by the National Natural Science Foundation of China (No. 50572081) 相似文献
2.
PbTiO3/PVDF复合材料介电性能及压电性能研究 总被引:1,自引:0,他引:1
实验制备了 Pb Ti O3/ PVDF复合材料 ,测试了频率对复合材料介电性能的影响 ,并分析了 Pb Ti O3的体积分数与复合材料介电性能的关系 ;研究了复合材料的压电性能 ;并对样品微观形态进行了分析。 相似文献
3.
利用溶液复合技术制备了超微细Al2O3粒子与聚甲基丙烯酸甲酯(PMMA)的复合材料。SEM证示采用乙酸乙酯作溶剂,可以将超微细Al2O3很好地分散于PMMA基体中,力学性能测试结果表明超微细Al2O3对PM-MA具有很好的增韧增强作用,当Al2O3用量为10%,粒子半径为0.05μm时,PMMA的拉伸强度增加3倍,缺口冲击强度增加了10倍。差热分析结果说明超微细Al2O3加入PMMA后,提高了PMMA的热分解温度,降低了Al2O3的相转变温度,预示超微细Al2O3与PMMA可能发生了化学结合。 相似文献
4.
熊传溪 《武汉理工大学学报(材料科学英文版)》1997,(3)
With the aid of a slip-disentanglement theo-ry,a reological equation has been deduced about the compos-ite system of solid-state low melting point metal and poly-mer. By measuring some rheological properties of the compos-ite system composed of low melt point metal and polypropy-lene (LMPM/PP),the results show that LMPM has a pro-moter flow action upon PP when using a small amount ofLMPM and , if some coupled agents are added,the promoterflow action will be remarkable. Moreover, while LMPM beingadded into the composite,the temperature sensitivity of systemwill go up. This indicates that the system’s viscosity will dropfurther if its temperature is increased. 相似文献
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The influences of various kinds of UV-absorbers,antioxidants and their mixtures on UV-aging resis-tance of transparent unsaturated polyester FRP arestudied by artificial aocelerating aging test.Theresults show that the UV-aging resistance of com-bined stabilizers is better than single stabilizer.It is concluded that the cooperative effect of UV-absorbers is caused bg the increase of wave leng-th and intensity of the absorption light the coopora-tive effect of UV-absorbers and antioxidants iscaused by Dreventing the photo-oxidantion. 相似文献