Effect of fly ash on drying shrinkage of thermal insulation mortar with glazed hollow beads

Drying shrinkage of thermal insulation mortar with glazed hollow beads was measured by a vertical length comparator, and the influences of fly ash with different contents (0, 18%, 36%, and 54% were used) on the long-term drying shrinkage were discussed. The mass loss was measured by the weighting method and the pore structure was characterized using three different methods, including the light microscopy, the mercury intrusion porosimetry (MIP), and the nitrogen adsorption/desorption (NAD) experiments, and the correlations among them were researched. The results show that drying shrinkage process of thermal insulation mortar includes three steps with increasing curing time: the acceleration period (before 7 d), the deceleration period (7-365 d), and the metastable period (after 365 d). Drying shrinkage in the first stage (7 d before) increases quickly owing to the fast water loss, and its development in the last two stages is attributed to the increment of the pore volume of mortar with the radius below 50 nm, especially the increment of the pore volume fraction of the pore radius within the size range between 7.3 nm and 12.3 nm. There is no change in the drying shrinkage development trend of mortar with fly ash addition, and three steps in the service life, but fly ash addition in the mortar restrains its value. There is a linear relationship between the drying shrinkage and fly ash content, which means that drying shrinkage reduces with fly ash addition.     

Effect of calcium aluminate cement variety on the hydration of portland cement in blended system

Two kinds of CACs with different monocalcium aluminate（CA） contents were used in the PC/CAC（PAC） mixtures. Effects of CA and CACs on the properties of PAC were analyzed by setting times and the compressive strength tests, and also by means of calorimetry, XRD, DTA-TG and ESEM. The experimental results show that the compressive strength of the PAC mortars decreases with increasing content of CAC while it declines sharply with a higher content of CA in CAC. Compared with neat PC paste, the content of calcium hydroxide in hydrates of PAC paste decreases significantly, and the hydration time of PC is prominently prolonged. Additionally, the higher the content of CA in CAC, the more obviously the hydration of PC is delayed, confi rming that the CA phase in CAC plays an important role in the delay of PC hydration.     

我国商品砂浆技术发展现状及展望

从历史回顾、产品分类、生产技术、应用技术、支撑体系(标准制定、科学研究、学术交流)等方面论述了我国商品砂浆的发展、技术现状及展望,并针对我国商品砂浆产业在技术上存在的问题,提出了研发方向和建议。     

苯丙乳液水泥砂浆横向变形与压折比及其关系

采用横向变形和压折比这2种方法表征了苯丙乳液水泥砂浆的韧性,研究了苯丙乳液对水泥砂浆韧性的影响,并着重探讨了这2种表征方法的关系.结果表明:苯丙乳液改变了水泥砂浆的断裂特性,使其断裂行为由典型的脆性转变为一定塑性,即改善了水泥砂浆的韧性;横向变形量和压折比都可以表征苯丙乳液水泥砂浆的韧性,只是二者在不同韧性范围内的敏感性不同,横向变形量随韧性的增加呈直线增大,试验范围内敏感程度不变;而压折比则呈曲线变化,韧性较大时其敏感性下降.     

中国干混砂浆的应用研究概况

从干混砂浆的性能、组分以及聚合物干粉对其性能影响和作用机理等方面论述了干混砂浆在中国的研究进展.中国国内目前关于干混砂浆的理论研究主要集中在聚合物共混改性水泥砂浆,无机矿物外加剂和聚合物种类、成分、掺量等对水泥砂浆性能影响方面. 干混砂浆所用聚合物种类和掺量对干混砂浆的各种性能影响显著.对聚合物的作用机理研究几乎还是空白.     

煤矸石-Ca(OH)2-H2O体系反应动力学初探

通过测定不同龄期煤矸石地酸溶出量,对不同温度热激活下的煤矸石在煤矸石-Ca(OH)2-H2O体系中的反应速率进行了研究,并在此基础上建立了煤矸石火山灰反应动力学模型.该模型表明:煤矸石的反应速率(v)主要取决于煤矸石的火山灰活性(v),值大则煤矸石的火山灰活性高,反应速率常数k值大则煤矸石的火山灰反应活性高,最后采用Ca(OH)2的吸收实验来验证本模型的正确性.     

聚丙烯纤维和丁苯乳液对水泥砂浆性能的影响

研究了掺量为0~0.3%(体积分数)的聚丙烯纤维,掺量为0~12%(质量分数)的丁苯乳液在单掺、复掺情况下对水泥砂浆3,28,90 d抗压、抗折强度,以及28 d龄期时磨损、冲击性能等的影响.研究结果表明,纤维的掺入大幅度提高了丁苯乳液砂浆的抗冲击和抗磨损性能,提高丁苯乳液砂浆抗磨损性能的最佳纤维掺量为0.1%;纤维掺量越大,对提高丁苯乳液砂浆的抗冲击性能越有利.丁苯乳液的掺入改善了聚丙烯纤维与基体之间的界面粘结,增强了掺纤维砂浆的长期力学性能.丁苯乳液、聚丙烯纤维的复掺效果优于这两者单掺的情况,复掺对水泥砂浆起到了双重改性的效果.     

纤维素醚在水泥颗粒表面的吸附性能EI北大核心CSCD

用动态光散射测定了溶液中纤维素醚分子的尺寸、用总有机碳含量(TOC)方法测定了纤维素醚在水泥中的吸附量。结果表明:溶液中纤维素醚的粒径随浓度提高而减小,并趋于恒定值,称之为无扰直径。用无扰直径和水泥的Blaine比表面积计算其在水泥颗粒表面单层紧密堆积的量,其与TOC测定的吸附量存在良好相关性,说明纤维素醚以其无扰直径大小吸附在水泥颗粒表面,且与水泥种类无关。     

水泥-煤矸石复合体系水化进程研究

通过净浆强度和化学结合水含量的测定研究了煤矸石的活化方式以及水泥C3S含量对水泥-煤矸石复合体系水化进程的影响。并通过对体系中Ca（OH）2含量定量测试分析了影响机理。试验结果表明，同龄期复合体系浆体的净浆强度以C3S含量较高的水泥＋复合活化煤矸石体系最佳，同时其化学结合水含量最高；Ca（OH）2含量测试结果表明活化后煤矸石对复合体系中的Ca（OH）2有着显著的吸收效果，同时水泥中较高含量的C3S能更好的促进煤矸石与Ca（OH）2的二次反应。     

天然硬石膏的活性激发及改性

选取硫酸钾作为激发剂对天然硬石膏进行活性激发,并分别掺入硅酸盐水泥与半水石膏进行改性。研究了这些组分对天然硬石膏力学性能及耐水性能的影响规律,实验结果表明,硫酸钾对强度提高显著,硅酸盐水泥对强度与软化系数均有很大的改善作用,而半水石膏对强度与软化系数也有一定程度的影响。