Transesterification of Palm-based Methyl Palmitate into Esteramine Catalyzed by Calcium Oxide Catalyst

The technology for transesterification reactions between methyl esters and alcohols is well established by using classical homogeneous alkaline catalysts, which provide high conversion of methyl esters to specialty or nonindigenous esters. However, in certain products where the purity of the esters is of concern, the removal of homogeneous catalysts after the completion of the reaction is a challenge in terms of production cost and water footprint. Therefore, a study to investigate the potential of heterogeneous catalysts was conducted on reactions between methyl palmitate and triethanolamine. The degree of basicity and active surface area of calcium oxide (CaO), zinc oxide (ZnO), and magnesium oxide (MgO) were first characterized by using temperature-programmed desorption (TPD-CO₂) and Brunauere–Emmett–Teller (BET), respectively. Among the metal oxides investigated, the CaO catalyst showed the best catalytic activity toward the transesterification process as it gave the highest conversion of methyl palmitate and yielded fatty esteramine compositions similar to the conventional homogeneous catalyst. The optimum transesterification condition by using the CaO catalyst utilized a lower vacuum system of approximately 200 mbar, which could minimize a considerable amount of energy consumption. Furthermore, low CaO dosage of 0.1% was able to give a conversion of 94.5% methyl ester and formed esteramine at 170 °C for 2 h. Therefore, the production of esterquats from esteramine may become more economically feasible through the methyl ester route by using the CaO catalyst, which can be recycled three times.     

Polyesters from renewable resources: Preparation and characterization

Polyesters were synthesized with monoglycerides prepared from rubber seed oil, a renewable resource. Monoglycerides were obtained by an alcoholysis method from the oil, which was neat or modified by treatments with different amounts of maleic anhydride at 230°C. The polyester resins were subsequently prepared by the condensation polymerization of the monoglycerides with phthalic anhydride. The monoglycerides and resins were characterized by spectroscopic analysis and measurements of the physicochemical properties. The chemical resistance of the polyesters was also studied. The results revealed that the polyesters prepared from the modified monoglycerides possessed better properties. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3748–3755, 2006     

Characterising and exploiting workloads of highly interactive video-on-demand

This paper presents a detailed characterisation of user behaviour for a series of interactive video experiments over a 12 month period, in which we served popular sporting and musical content. In addition to generic VCR-like features, our custom-built video-on-demand application provides advanced interactivity features such as bookmarking. The dramatic impact of such functionality on how users consume content is studied and analysed. We discuss in detail how this user behaviour can be exploited by content distributors to improve user experience. Specifically, we study how simple dynamic bookmark placement and interactivity-aware content pre-fetching and replication can reduce the impact of highly interactive media on CDN performance.     

Production planning in automotive powertrain plants: a case study

Based on a real case study from the automotive industry, this paper deals with production planning in powertrain plants. We present an overview of the production planning process and propose a mixed integer linear programme to determine the production quantities of each product over a planning horizon of several days. Then, using real data of an engine assembly line, we simulate the performance obtained through the proposed model within a rolling horizon planning process. We perform multiple tests in order to evaluate the impact of two parameters involved in this process: planning frequency and frozen horizon length. Furthermore, in order to illustrate the value of improving coordination between engine plants and their customers, we evaluate the impact of the quality of demand information (orders and forecasts). We analyse the simulation results and provide insights and recommendations in order to achieve a good trade-off between service level, inventory, and planning stability.     

Multislip and Soret–Dufour influence on nonlinear convection flow of MHD dissipative Casson fluid over a slendering stretching sheet with generalized heat flux phenomenon

In the present investigation, Soret–Dufour and multislip's impact on magnetohydrodynamics (MHD) Casson fluid flow encompassing variable thermophysical features in the nonlinear convection process is analyzed. It is believed that to any effective heat and mass transfer enhancement, the relaxation of such fluid and material time along with the thermo-physical features, are well estimated. In this model, a magnetic field of nonuniform strength is applied perpendicular to the slendering sheet with variable thickness, and nonlinear convection flow is considered in this generalized heat flux examination. An appropriate similarity variable is implemented on the governing equations embedding the variable viscosity, thermal conductivity, and generalized Fourier's law to drive ordinary differential equations. Galerkin weighted residual approach is utilized to calculate the flow field among other flow characteristics. The novel flow features are discussed therein. Modified Fourier and multislip's parameters are seen to have downsized the velocity and temperature field greatly. Thermal and solutal buoyancy effects are more pronounced in nonlinear form compared to the linear model. Dufour number influences both velocity and energy fields positively but negates the concentration field, while the Soret number gives an opposing characterization.     

On the Refinement Mechanism of Silicon in Al-Si-Cu-Zn Alloy with Addition of Bismuth

Obtained results of micro and nano studies reveal that bismuth refines the silicon in which the flake silicon changed to lamellar structure with reduction in twin spacing from 160 to 75 nm. Bismuth segregates towards the inter-dendritic regions and decreases the Al-Si contact angle resulting in suppression of the silicon growth causing refinement of the eutectic structure. Increased recalescence temperature and time confirmed that the refinement effect is attributed to the growth stage.     

Processing Effects on Chemical,Functional and Pasting Properties of Cowpea Flour from Different Varieties

Cowpea varieties (IT88D-867-11, IT89KD-288 and MALA) were boiled, roasted, dehulled and later milled into powder. The proximate composition, functional and pasting properties as well as anti-nutritional contents (Tannin) of the product was subsequently determined. The result of the study revealed significant increase (P < 0.05) in the crude protein, crude ash, swelling power and water absorption capacity. Conversely, significant decrease (P < 0.05) was observed in crude fat, starch content, moisture content, solubility and peak viscosity. Boiled samples have significantly higher (P < 0.05) crude protein, swelling power, water absorption capacity, with concomitantly lower solubility and tannin content. Crude ash, moisture, solubility and tannin content of dehulled samples decreased significantly with an increase in protein, swelling power and water absorption capacity. However, IT89KD-288 has the highest protein content irrespective of the processing used. But raw IT89KD-288 showed highest percentage of swelling power, solubility, water absorption capacity and Tannin content. The result revealed that both boiling and dehulling will greatly reduce tannin content of cowpea.     

A new acylated and oleanane-type triterpenoid saponin from Gypsophila arrostii roots

A new acylated and triterpenoidal saponin, named GS1, was isolated from the roots of Gypsophila arrostii Guss. On the basis of acid hydrolysis, comprehensive spectroscopic analyses and comparison with spectral data of known compounds, its structure was established as 3-O-β-D-xylopyranosyl-(1→2)-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyranosyl-{21-O-[(E)-3,4,5trimethoxycinnamoyl]}21-hydroxygypsogenin 28-O-β-D-glucopyranosyl-(1→2)- [β-D-arabinopyranosyl-(1→3)]-β-D-xylopyranosyl-(1→3]-α-L-rhamnopyranosyl ester. This article deals with the isolation and structural elucidation of new acylated and oleanane-type saponin.