Microstructure and Mechanical Properties of Hot-Pressed Silicon Carbide-Aluminum Nitride Compositions

A flexural strength of up to 1 GPa was achieved in SiC-AIN materials and is attributed to a dense, equiaxial grain structure of the 2H(δ) SiC-AIN solid solution, with a relatively uniform grain size of ∼ 1 μm. The strength was found to decrease with increasing grain size. While the β→α phase transformation and the formation of various metastable polytypes make microstructural control difficult in SiC materials, excellent control is facilitated in SiC-AIN materials as a result of the stable 2H solid solution. Several mechanisms of grain refinement during the β→ 2H transition were observed, most notably the direct formation of several 2H grains from a single β grain. In addition, grain growth is limited by the diffusion-controlled nature of the transition. These mechanisms could be utilized to achieve even higher strength values, with potentially higher reliability of the materials in structural applications.     

Formation of β-SiAION as an Intermediate Oxidation Product of SiC–AIN Ceramics

The oxidation mechanisms in SiC-AlN solid solutions, exposed at 1370°C for 200 h in air, have been investigated by scanning electron microscopy (SEM), analytical and high-resolution electron microscopy (HREM), and X-ray diffraction techniques. Five hot-pressed compositions, including pure SiC and pure AIN, were examined. Assuming parabolic rate behavior, the values of the parabolic rate constants based on oxide layer thickness increased by over 2 orders of magnitude by increasing AIN contents from 0% to 62%. A continuous amorphous phase containing cristobalite and mullite crystallites was present at the oxide layer in 13% AIN and 27% AIN samples. Two reaction layers were found in the oxidized SiC–62% AIN solid solution. The inner layer consisted of a mixture of β-SiAION and graphite phases, while the outer layer consisted of mullite as a major phase and cristobalite as a minor phase. The oxidation proceeded in two stages: a partial oxidation of SiC–AIN to β-SiAION and carbon (graphite), and a final oxidation of β-SiAION to mullite + SiO₂.     

Static and Cyclic Fatigue of Alumina at High Temperatures: II, Failure Analysis

Failure mechanisms of an alumina, tested at 1200°C under static and various cyclic loading conditions, were examined. Slow crack growth of a single crack is the dominant mechanism for the failure in specimens under cyclic loading with a short duration of maximum stress at all applied stress levels, as well as at high applied loads for static loading and cyclic loading with a longer hold time at maximum stress. At low stress levels, failure of static loading and cyclic loading with a longer hold time at maximum stress might occur by formation and/or growth of multiple macrocracks. More importantly, for all the given loading conditions. The viscous glassy phase behind the crack tip could have a bridging effect on the crack surfaces. A simplified model for calculating effective stress intensity factor at the crack tip under static and various cyclic loading demonstrated a trend consistent with the stress–life data.     

Microstructure and Microchemistry of Polymer-Derived Crystalline SiC Fibers

Stoichiometric and near-stoichiometric silicon carbide fibers, derived from the polymer polycarbosilane, have been characterized by scanning Auger and transmission electron microscope techniques. Excess carbon usually appeared in the fibers, but it could be eliminated by controlling processing conditions. The fibers consisted mainly of submicrometer-sized SiC microcrystals, with a considerably twinned and stacking-faulted β-SiC structure. Free carbon, which appeared in the form of graphite, was the only detectable intergranular phase in the nonstoichioinetric SiC fibers, while the stoichiometric SiC fibers contained no detectable second phase whatsoever.     

Microchemistry and microstructure of a multiphase aluminosilicate ceramic

The microstructure and microchemistry of a sintered (≈ 1700° C) aluminosilicate ceramic (60 wt % Al₂O₃-40 wt% SiO₂) was investigated by optical, scanning (SEM and EDAX), and analytical electron microscopy (TEM and STEM). The microstructural features of the fired ceramic consisted of unreacted Al₂O₃, glass, porosity, and equilibrium and metastable mullite phases. Residual Al₂O₃ agglomerates (≈ 15 to 30 μm in size) were surrounded by a ≈ 6 μm layer of equilibrium mullite (≈ 71.3 to 73.5 wt% Al₂O₃). The unreacted Al₂O₃-equilibrium mullite assembly formed islands embedded in a silica rich glass (≈ 4.5 to 14wt% Al₂O₃) which also contained 2 to 3 μm thick metastable mullite needles (≈ 70 to 77 wt% Al₂O₃). Phase separation and alumina rich glass compositions (≈ 57 to 59 wt% Al₂O₃) were also observed in some areas of the microstructure.     

A method for monitoring insolation in remote regions

A method is proposed for measuring the beam and diffuse components of solar radiation via the use of a set of fixed pyranometers tilted in various orientations. A detailed error analysis is performed for the two cases of three and four pyranometers, and it is shown how orientations may be found such that the resultant errors on the derived beam and diffuse components may be expected to be of a magnitude comparable to the errors associated with the pyranometers themselves. Attention is drawn to the fact that certain anisotropic models for the diffuse component may be recast—via the definition of “effective” beam and diffuse components—in such a manner that they take on the mathematical simplicity of an isotropic model.     

A five-level model of intervention: School psychology and guidance counseling in Israel.

Provides a conceptual framework for a division of labor between school psychologists and counselors in Israel, based on a 5-level model of intervention (wellness optimization, anticipatory guidance, primary prevention, secondary prevention, and tertiary prevention) for the school setting. It is suggested that the counselor assume a more active role with regard to the promotion of wellness and anticipatory intervention, whereas the psychologist should be more active in the secondary prevention level of intervention; thus, their work would become complementary. (41 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Microstructural Studies in Alkoxide-Derived Mullite/Zirconia/Silicon Carbide-Whisker Composites

Mullite composites toughened with ZrO₂ (with or without a MgO or Y₂O₃ stabilizer) and/or SiC whiskers (SiC( w )) were fabricated by hot-pressing powders prepared from Al, Si, Zr, and Mg(Y) alkoxide precursors by a sol–gel process. Micro-structures were studied by using XRD. SEM, and analytical STEM. Pure mullite samples contained prismatic, preferentially oriented mullite grains. However, the addition of ZrO₂, as well as the hot-pressing temperature, affected the morphology and grain size in the composites; a fine, uniform, equiaxed microstructure was obtained. The effect of SiC( W ) was less pronounced than that of ZrO₂. Glassy phases were present in mullite and mullite/SiC( W ) composites, but were rarely observed in Al₂O₃-rich or ZrO₂-containing samples. The formation of zircon due to the reaction between ZrO₂ and SiO₂ and the considerable solid solution of SiO₂ in ZrO₂ prevented the formation of the glassy phase, whereas the reaction between Al₂O₃ and MgO in MgO-containing samples formed a spinel phase and also deprived the ZrO₂ phase of the stabilizer. Intergranular ZrO₂ particles were either monoclinic or tetragonal, depending on size and stabilizer content; small intragranular ZrO₂ inclusions were usually tetragonal in structure.     

Effects of participant modeling on information acquisition and skill utilization.

Assessed the contribution of active participant modeling in coping skills training by evaluating 2 critical process variables: the retention of information about the threatening events and how to cope with them, and the visceral component of imaginal rehearsal. 38 8–13 yr old children, highly fearful of dentists (the Dental subscale of the Children's Fear Survey Schedule), were shown a videotape of 2 children practicing controlled respiration and imagery techniques while undergoing dental treatment. The participant modeling group was encouraged to practice these as they watched the film, whereas the symbolic modeling group was told that this might help them during their own dental treatment, which immediately followed videotape preparation. Ss who had the active participant instructions obtained more information from the videotape, reported greater reduction in dental anxiety, and showed lower respiratory rates as they watched the videotape. They reported greater use of imagery techniques and enhanced self-control. The degree of disruptiveness was significantly lower during subsequent actual dental treatment in Ss from the active practice group. (33 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)