Cobalt Ferrite in YSZ for Use as Reactive Material in Solar Thermochemical Water and Carbon Dioxide Splitting, Part II: Kinetic Modeling

The kinetics of 10 wt.% cobalt ferrite (CoFe₂O₄) in 8 mol.% yttria-stabilized zirconia, synthesized via the co-precipitation method and formed into a porous structure, are investigated in support of simulating the performance of a solar thermochemical reactor. Kinetic parameters for the thermal reduction (T-R) of CoFe₂O₄ at temperatures of 1325–1500°C were investigated by thermogravimetry. A nonlinear best fit of a uniform conversion model was used to determine kinetic parameters from experimental data. In the temperature range of 1375–1450°C, the activation energy and preexponential term were found to be 386 ± 13 kJ mol^?1 and 8.8 × 10⁹ ± 2.0 × 10⁸ min^?1, respectively, while increasing at higher temperatures. Simultaneous thermogravimetric analysis and differential scanning calorimetry studies showed an increase in the reaction rate of T-R upon the onset of melting (1440°C). Oxidation studies of the material using CO₂ yield an activation energy and preexponential term of 52.1 ± 6.8 kJ mol^?1 and 2.86 ± 0.2 min^?1, respectively, which is in good agreement with past work. The reaction order for CO₂ was determined to be 0.750 ± 0.08. The reaction kinetics for oxidation using CO₂ were best described by a 3-D diffusion Jander model.     

An investigation of the feasibility of utilizing GPS/TEC“signatures” for near-real time forecasting of auroral-Epropagation at high-HF and low-VHF frequencies

VHF propagation on ⩽5300 km polar paths has been documented during the maximum phase of sunspot cycle 19. Mode analysis on these polar paths has shown that auroral-E ionization (AEI) supported some modes. Electron densities and plasma frequencies which could support AEI modes at frequencies up to 46 MHz have also been measured. Long distance VHF propagation from AEI has also been reported by radio amateurs using frequencies in the 2 m band in a “sidescatter mode”. An AEI experiment has been in operation between Wales (Alaska) and Fairbanks (Alaska) where a 75-watt CW transmitter located in Wales transmits the Morse letter “R” every 5 s, and a receiver in Fairbanks detects the 25.5 MHz signal whenever AEI is present near the midpoint of the 960 km path. Another experiment is underway using a GPS total electron content (TEC) receiving station at Fairbanks also using AEI data from the Wales-Fairbanks experiment. From this, the authors examine 58 passes of GPS satellites whose E-layer penetration points lie close to the midpoint of the Wales-Fairbanks path and find that there is a threshold value of TEC above which auroral-E (AE) propagation occurs. They also find that AEI propagation is strongly correlated with large- and medium-scale E-region structures in TEC determined by the GPS measurements. When TEC ionospheric structures are not present near the Wales-Fairbanks path midpoint, no AEI signal is received. The authors tentatively conclude that the occurrence of these specific TEC signatures may be utilized as predictors of AEI forward propagation on paths within and parallel to the auroral oval     

A simple frequency-domain algorithm for early detection of damaged gear teeth

Fixed transducers often are used to monitor meshing gear pairs in order to detect tooth damage. A simple frequency-domain damage-detection algorithm is suggested for very early detection of such damage. Ratios of rotational-harmonic amplitudes computed from before and after potential damage are utilized to eliminate effects of transducer and structural-path-caused amplitude changes between tooth-meshing location and transducer output, to minimize attenuating effects of multiple-tooth contact, and thereby, to approximately equally weight rotational-harmonic amplitudes over a wide range of harmonics. Statistical averaging of absolute values of logarithmic ratios of rotational-harmonic amplitudes is used to minimize fluctuations caused by multiple-tooth contact and manufacturing errors on the subject gear. Synchronous averaging is employed to minimize effects of noise and manufacturing errors on the mating gear. Time-windowing tailored to contact ratios of mating gears is utilized to isolate individual tooth locations. Resultant windowing effects on availability of useful rotational harmonics are analyzed. Application of the algorithm to detection of seeded bending-fatigue faults on a planetary ring-gear tooth indicates that successful detections were achieved.     

Genotoxicity testing of extracts from aflatoxin-contaminated peanut meal, following chemical decontamination

One of the most important concerns in the decontamination of aflatoxin-containing feed commodities is the safety of the products for food-producing animals and for human consumption of products derived from these animals. A new method, based on the use of florisil and C18 solid phase extraction columns, was developed for the preparation of extracts from decontaminated peanut meal, which allowed testing with in vitro genotoxicity assays without interference of the residual aflatoxin B₁. Recovery of degradation products in the extracts was evaluated by the use of radiolabelled \[¹⁴C]-aflatoxin B₁ (AFB₁) added to naturallycontaminated peanut meal (3.5mg AFB₁/kg). The meal was treated by a small-scale version of an industrial decontamination process based on ammoniation. Following decontamination, more than 90% of the label could not be extracted from the meal. AFB₁ accounted for about 10% of the radiolabel present in the extractable fraction, indicating a total AFB reduction of more than 99%. Decontamination of the meal by a number of other small- and industrial-scale ammonia-based processes resulted in similar efficiencies. Application of the extraction procedure resulted in AFB₁-rich and AFB₁-poor fractions, the latter containing half of the extractable decontamination products but less than 1% of the residual AFB₁. Testing in the Salmonella /microsome mutagenicity assay (TA 100, with S9-mix) of the original crude extracts and AFB1 rich fractions prepared from non-treated and decontaminated meal, showed the positive results expected from the AFB₁ contents as determined by HPLC analysis. Analysis and testing of the AFB₁-poor fractions showed that the various decontamination processes not only resulted in a successful degradation of AFB₁ but also did not produce other potent mutagenic compounds. Slight positive results obtained with these extracts were similar for the untreated and treated meals and may be due to unknown compounds originally present in the meal. Results obtained with an unscheduled DNA synthesis (UDS) and Comet assay with rat hepatocytes supported this conclusion. Positive results obtained with the micronucleus assay, using immortalized mouse hepatocytes (GKB), did not clearly reflect the mycotoxin levels and require further examination. It is concluded that the newly developed extraction procedure yields highly reproducible fractions and hence is very suitable for examining the possible formation of less potent degradation products of aflatoxins in short-term genotoxicity tests.     

ADSORPTION OF ASPHALTS AND THEIR SIZE EXCLUSION CHROMATOGRAPHY FRACTIONS ON AGGREGATE SURFACES

The adsorption behavior of two asphalts and their size exclusion chromatography (SEC) fractions from toluene solution onto aggregate was investigated. The effect of the differences in chemistry and molecular size of the asphalt samples on their adsorption behavior on silica, granite and greywacke was determined. The adsorption of asphalts and SEC fractions on SI-1000 silica was well-represented by the Toth model, while the Radke-Prausnitz model better described their adsorption behavior on both granite and greywacke. Combining the adsorption models with the Gibbs adsorption equation of state gave the spreading pressure of each adsorbate species adsorbed on the aggregate surfaces. The spreading pressure predicted the competitive adsorptive edge of the asphalt fractions. The SEC I fractions, containing molecules of larger molecular size and higher heteroatom contents, showed higher spreading pressures than the SEC II fractions, which contained molecules of smaller molecular size and fewer heteroatoms. The asphalts yielded intermediate spreading pressures for SI-1000 silica and granite, but they gave the highest spreading pressure values for greywacke.     

Absorption, distribution and excretion of aflatoxin-derived ammoniation products in lactating cows

Peanut meal naturally contaminated with 3.5mg/kg aflatoxin B₁ (AFB₁) was spiked with radiolabelled AFB₁ (meal¹⁴C-I0) and decontaminated by a smallscale copy of an industrial ammoniation process (meal ¹⁴C-I1). During the process 15% of the radioactivity was lost, whereas 90% of the remaining radiolabel could not be extracted from the meal. In the extractable part, AFB₁ accounted for 10% of the radiolabel, consistent with a total AFB₁ reduction of more than 99%. No degradation products were observed in the extracts. Four lactating cows were fed with a diet containing 15% of either meal ¹⁴C-I0 or ¹⁴C-I1 for 10 days. On day 9 of this treatment, respectively 23 and 67% of the radiolabel was excreted in the urine and faeces of cows fed meal ¹⁴C-I0, as compared with 2 and 101% in the case of cows fed meal ¹⁴C-I1. Milk contained respectively 1.35 (meal ¹⁴C-I0) and 0.25% (meal ¹⁴C-I1) of the radiolabel. Milk samples taken during the equilibrium stage contained respectively 5 and 0.5 ng/ml of AFB₁-derived compounds. Aflatoxin M₁ (AFM₁) accounted for 50-80% of these compounds in the case of milk from cows fed ¹⁴C-I0, as compared with 6-20% in the case of ¹⁴C-I1. AFB₁ to AFM₁ carry-over rates for ¹⁴C-I0 or ¹⁴     

Control of nanoparticle size, reactivity and magnetic properties during the bioproduction of magnetite by Geobacter sulfurreducens

The bioproduction of nanoscale magnetite by Fe(III)-reducing bacteria offers a potentially tunable, environmentally benign route to magnetic nanoparticle synthesis. Here, we demonstrate that it is possible to control the size of magnetite nanoparticles produced by Geobacter sulfurreducens by adjusting the total biomass introduced at the start of the process. The particles have a narrow size distribution and can be controlled within the range of 10-50?nm. X-ray diffraction analysis indicates that controlled production of a number of different biominerals is possible via this method including goethite, magnetite and siderite, but their formation is strongly dependent upon the rate of Fe(III) reduction and total concentration and rate of Fe(II) produced by the bacteria during the reduction process. Relative cation distributions within the structure of the nanoparticles have been investigated by x-ray magnetic circular dichroism and indicate the presence of a highly reduced surface layer which is not observed when magnetite is produced through abiotic methods. The enhanced Fe(II)-rich surface, combined with small particle size, has important environmental applications such as in the reductive bioremediation of organics, radionuclides and metals. In the case of Cr(VI), as a model high-valence toxic metal, optimized biogenic magnetite is able to reduce and sequester the toxic hexavalent chromium very efficiently to the less harmful trivalent form.     

Plasma platelet-activating factor levels in newborn infants with and without perinatal asphyxia: is it an additional marker of perinatal asphyxia?

We report a case of severe hyperthermia in a 6-month-old boy with a single ventricle, dextrocardia, asplenia, and transposition of the great arteries, during induction of anesthesia on three separate occasions. To our knowledge, this is the first case reported of repeated intraoperative hyperthermia not related to malignant hyperthermia, infection, neuroendocrine tumor, or iatrogenic causes (e.g., anticholinergic blockade or warming devices). The severe hyperthermia may be secondary to the medications given before and during induction and/or the stress of the induction. Among the induction medications given during the three episodes, fentanyl is the most likely contributing drug. Human data indicate that opioids increase the sweating threshold and decrease the vasoconstriction and shivering thresholds. The medications could cause a widening in the thermoregulation interthreshold and the stress could induce nonshivering thermogenesis.     

Survey of food safety awareness among HIV positive individuals

Though opioids are known to have neuroprotective properties, little information is available on the functional state of opioidergic receptors following focal cerebral ischaemia. The present study investigated the evolution of the Bmax and Kd for [3H]DAMGO, [3H]DADLE, and [3H]U69,593, respectively, for the mu, delta, and kappa opioidergic receptors after permanent focal cerebral ischaemia in mice. While the various Kd were unchanged, mu and delta Bmax values were precociously decreased in frontoparietal cortices, earlier than kappa receptors, reflecting infarct extension with time. The Bmax values for mu and delta receptors were also altered in non-infarcted tissues, such as tissues at risk (e.g., temporal auditory cortex) and exofocal (e.g., contralateral and non-infarcted) cortices. These results suggest that, in non-infarcted areas, the observed changes reflect functional modifications to focal ischaemia.