Electrical and optical properties of fluorine-doped CdO films deposited by ultrasonic spray pyrolysis

The CdO:F samples have been deposited onto microscope glass substrates at 250 °C by ultrasonic spray pyrolysis method. With the incorporation of fluorine into CdO, the direct optical transition has shifted towards the shorter wavelengths, and the transparency of the material has increased at a given wavelength above the fundamental absorption edge. The shift in the absorption edge is explained by means of the Moss–Burstein effect, which is also supported with the results of the current–voltage characteristics. Here, a correlation has been established between the band broadening and the increase in conductivity due to the increase in carrier density.     

Pervaporation of organic compounds from aqueous mixtures using polydimethylsiloxane‐containing block copolymer membranes

Pervaporation of aqueous mixtures of ethanol, acetone, butanol, isobutanol, and furfural through polystyrene‐b‐polydimethylsiloxane‐b‐polystyrene (SDS) triblock copolymer membranes is reported. These mixtures are important for biofuel production from lignocellulosic feedstocks. Feedstock depolymerization results in the formation of furfural which must be removed before fermentation. Ethanol, butanol, isobutanol, and acetone are important fermentation biofuels. The membrane selectivity of SDS is about unity over a wide range of concentrations of aqueous ethanol mixtures, similar to the membrane selectivity of crosslinked polydimethylsiloxane (PDMS). The permeabilities of butanol, isobutanol, and furfural are larger than those of ethanol and acetone. The volatile organic compound permeability through SDS is similar to or higher than that through PDMS across a broad range of temperatures and feed concentrations is found. More selective and permeable membranes are needed to lower the cost of biofuel purification. The SDS membranes developed are but one step toward improved membranes. © 2015 American Institute of Chemical Engineers AIChE J, 61: 2789–2794, 2015     

Impact of module design on the performance of membrane bioreactors treating municipal wastewater

Membranes are located in a membrane module that physically seals and isolates the feed stream from the permeate flux in membrane bioreactors (MBRs). Therefore, module type, structure, and geometrical configuration are critical design considerations affecting membrane performance in MBRs. In this study, impact of membrane module design on treatment and filtration performance of MBRs was investigated. For this purpose, two flat sheet membrane modules with different outlet structures and module geometries, including rectangular- and D-shaped, were tested. In addition to the differences in outlet structure and module geometry, size of circular structures which supported membranes in rectangular- and D-shaped modules differed from each other. Considering the results, permeate quality was not affected from the change in the module design. However, the most remarkable impact of the module design was observed on the transmembrane pressure (TMP) evolution and fouling potential. D-shaped membrane module including smaller circular structures resulted in a decrease in fouling potential and thus, this module could be operated longer time in comparison to rectangular-shaped membrane module without a severe TMP increase. The observed differences in TMP increase and fouling potential lead to the hypothesis that module design is a critical factor affecting filtration performance in MBRs.     

Usability Problem Reports for Comparative Studies: Consistency and Inspectability

ABSTRACT

This study explores issues of consistency and inspectability in usability test data analysis processes and reports. Problem reports resulting from usability tests performed by three professional usability labs in three different countries are compared. Each of the labs conducted a usability test on the same product, applying an agreed test protocol that was collaboratively developed by the labs. Each lab first analyzed their own findings as they always do in their regular professional practice. A few weeks later, they again analyzed their findings, but then everyone applied the same method (SlimDEVAN: a simplified version of DEVAN, a method developed for facilitating comparison of findings from usability tests in an academic setting). It was found that levels of agreement between labs did not improve when they all used SlimDEVAN, suggesting that there was inherent subjectivity in their analyses. It was found that consistency of single analyst teams varied considerably and that a method like SlimDEVAN can help in making the analysis process and findings more inspectable. Inspectability is helpful in comparative studies based on identified usability problems because it allows for tracing back findings to original observations as well as for laying bare the subjective parts of the data analysis.     

Physical, antibacterial and antioxidant properties of chitosan films incorporated with thyme oil for potential wound healing applications

Chitosan films incorporated with thyme oil for potential applications of wound dressing were successfully prepared by solvent casting method. The water vapor permeability, oxygen transmission rate, and mechanical properties of the films were determined. Surface and cross-section morphologies and the film thicknesses were determined by Scanning Electron Microscopy (SEM). Fourier transform infrared (FT-IR) spectroscopy was conducted to determine functional group interactions between the chitosan and thyme oil. Thermal behaviors of the films were analyzed by Thermal Gravimetry (TGA) and Differential Scanning Calorimetry (DSC). In addition, the antimicrobial and the antioxidant activities of the films were investigated. The antimicrobial test was carried by agar diffusion method and the growth inhibition effects of the films including different amount of thyme oil were tested on the gram negative microorganisms of Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa and a gram positive microorganism of Staphylococcus aureus. The minimum thyme oil concentration in chitosan films showing the antimicrobial activity on all microorganisms used in the study was found as 1.2 % (v/v). In addition, this concentration showed the highest antioxidant activity due to mainly the carvacrol in thyme oil. Water vapor permeability and oxygen transmission rate of the films slightly increased, however, mechanical properties decreased with thyme oil incorporation. The results revealed that the thyme oil has a good potential to be incorporated into chitosan to make antibacterial and permeable films for wound healing applications.     

Empirical Correlations for Estimating Filtrate Volume of Water Based Drilling Fluids

Standard American Petroleum Institute (API) filter press is generally used for identifying the filtrate volume of drilling fluids and works only at very low pressures. In fact, during a drilling operation, at downhole conditions, the pressures encountered are significantly higher than what is used during standard API filter press tests. A relationship between the well-known fluid properties and the filtrate volume test is developed. In this study, experiments have been conducted for different water-clay mixtures with varying concentrations at different pressure values by using standard API filter press and HP&HT (high-pressure high-temperature) filter press. The relationship between physical and chemical properties of water-clay mixtures and filtrate volume is analyzed. An empirical correlation has been developed for estimating filtrate volume using basic information of the mud (i.e., rotational viscometer readings, density, pressure, cation exchange capacity, and chemical composition). The developed correlation can estimate filtrate volume with an error less than 20% for a wide range of pressure values.     

Hazardous waste management problem: The case for incineration

We define the hazardous waste management problem as the combined decisions of selecting the disposal method, siting the disposal plants and deciding on the waste flow structure. The hazardous waste management problem has additional requirements depending on the selected disposal method. In this paper we focus on incineration, for which the main additional requirement is to satisfy the air pollution standards imposed by the governmental restrictions. We propose a cost-based mathematical model in which the satisfaction of air pollution standards is also incorporated. We used the Gaussian Plume equation in measuring the air pollution concentrations at population centers. A large-scale implementation of the proposed model within Turkey is provided.