The relationship between chemical structure and reactivity for thermal hydroprocessing was studied for five gas oils derived from Alberta bitumens. Chemical structure was characterized by combining data from 1 H and 13 C nuclear magnetic resonance spectroscopy, class fractionation, and elemental analysis to calculate structural parameters. Thermal hydrotreating was performed in a continuous-flow stirred reactor at 420 and 440°C, 13.9 MPa hydrogen pressure, and 1.5 h1 LHSV. Conversion of the 343–525°C boiling fraction of the gas oils was correlated with the concentration of naphthenic methylene groups in the feed. Formation of methane and ethane was dependent on the degree of condensation of the aromatic rings in the feed oils. Thermal desulfurization was highly correlated with the amount of saturates in the feed, and the aromaticity of the resin fraction. Hydrogen consumption increased with the aromaticity of the gas oil… 相似文献
X-ray photoelectron spectroscopy (XPS) has been employed to investigate the chemical nature of samples of dicadmium stannate (Cd2SnO4) in the as-fired, electrochemically reduced, and reoxidized states. The reduction of Cd2SnO4 was found to be associated with a dramatic color change from bright yellow to dark green, a phenomenon commonly known as the electrochromic effect. Both quantitative XPS results and binding energy measurements proved that, upon exposure of the reduced ceramic bodies to air, the Sn2+ to Sn4+ transition readily took place to produce the intermediate compound, Cd2SnO3 with divalent tin. Prolonged exposure to the atmosphere did not result in further progress of reoxidation extending to monovalent cadmium. However, complete reoxidation of the reduced samples was possible by annealing in air at 350°C for a short period of time, e.g., 3 h, by which the original features of the as-fired state such as color and electrical conductivity were restored. The results also showed that reoxidized samples at high temperature assume the same XPS characteristics as those of as-fired ceramics. 相似文献
To improve the performance of embedded processors, an effective technique is collapsing critical computation subgraphs as
application-specific instruction set extensions and executing them on custom functional units. The problem with this approach
is the immense cost and the long times required to design a new processor for each application. As a solution to this issue,
we propose an adaptive extensible processor in which custom instructions (CIs) are generated and added after chip-fabrication.
To support this feature, custom functional units are replaced by a reconfigurable matrix of functional units (FUs). A systematic
quantitative approach is used for determining the appropriate structure of the reconfigurable functional unit (RFU). We also
introduce an integrated framework for generating mappable CIs on the RFU. Using this architecture, performance is improved
by up to 1.33, with an average improvement of 1.16, compared to a 4-issue in-order RISC processor. By partitioning the configuration
memory, detecting similar/subset CIs and merging small CIs, the size of the configuration memory is reduced by 40%. 相似文献
Artificial Life and Robotics - This paper describes the design and performance evaluation of a flexible wearable haptic device that aims to realize full kinesthetic haptic feedback for application... 相似文献
The metaheuristic optimization algorithms are relatively new optimization algorithms introduced to solve optimization problems in recent years. For example, the firefly algorithm (FA) is one of the metaheuristic algorithms inspired by the fireflies' flashing behavior. However, its weakness in terms of exploration and early convergence has been pointed out. In this paper, two approaches were proposed to improve the FA. In the first proposed approach, a new improved opposition-based learning FA (IOFA) method was presented to accelerate the convergence and improve the FA's exploration capability. In the second proposed approach, a symbiotic organisms search (SOS) algorithm improved the exploration and exploitation of the first approach; two new parameters set these two goals, and the second approach was named IOFASOS. The purpose of the second method is that in the process of the SOS algorithm, the whole population is effective in the IOFA method to find solutions in the early stages of implementation, and with each iteration, fewer solutions are affected in the population. The experiments on 24 standard benchmark functions were conducted, and the first proposed approach showed a better performance in the small and medium dimensions and exhibited a relatively moderate performance in the higher dimensions. In contrast, the second proposed approach was better in increasing dimensions. In general, the empirical results showed that the two new approaches outperform other algorithms in most mathematical benchmarking functions. Thus, The IOFASOS model has more efficient solutions.
Achieving stability at the site of femoral neck fracture is an important factor for callus formation in the post-operative period. However, measuring interfragmentary movement in vivo is not currently possible as telemetric screws have not been manufactured for surgical use. Understanding how the implantation of the screws can affect the stability of the fracture allows the surgeon to tailor the procedure to the patient and produce the best possible outcome. Two techniques have been developed that measure interfragmentary movement between fractured surfaces. The first was a FEA model of the proximal femur with screws represented by nodal links. Movement was quantified by the amount of relative motion occurring between paired nodes either side of the fracture. The second was a mechanical compression test of a composite femur that allowed the motion analysis of paired markers on the external surface of the femur. Movement was digitised with markers selected and displacements calculated by transforming the global coordinate system to a local system relative to the fracture plane. 相似文献
Making optimal use of available resources has always been of interest to humankind, and different approaches have been used in an attempt to make maximum use of existing resources. Limitations of capital, manpower, energy, etc., have led managers to seek ways for optimally using such resources. In fact, being informed of the performance of the units under the supervision of a manager is the most important task with regard to making sensible decisions for managing them. Data envelopment analysis (DEA) suggests an appropriate method for evaluating the efficiency of homogeneous units with multiple inputs and multiple outputs. DEA models classify decision making units (DMUs) into efficient and inefficient ones. However, in most cases, managers and researchers are interested in ranking the units and selecting the best DMU. Various scientific models have been proposed by researchers for ranking DMUs. Each of these models has some weakness(es), which makes it difficult to select the appropriate ranking model. This paper presents a method for ranking efficient DMUs by the voting analytic hierarchy process (VAHP). The paper reviews some ranking models in DEA and discusses their strengths and weaknesses. Then, we provide the method for ranking efficient DMUs by VAHP. Finally we give an example to illustrate our approach and then the new method is employed to rank efficient units in a real world problem. 相似文献
The Persian language is one of the dominant languages in the Middle East, so there are significant amount of Persian documents available on the Web. Due to the different nature of the Persian language compared to the other languages such as English, the design of information retrieval systems in Persian requires special considerations. However, there are relatively few studies on retrieval of Persian documents in the literature and one of the main reasons is the lack of a standard test collection. In this paper, we introduce a standard Persian text collection, named Hamshahri, which is built from a large number of newspaper articles according to TREC specifications. Furthermore, statistical information about documents, queries and their relevance judgments are presented in this paper. We believe that this collection is the largest Persian text collection, so far. 相似文献