Probing the thermal decomposition process of layered double hydroxides through in situ <Superscript>57</Superscript>Fe Mössbauer and in situ X-ray diffraction experiments

The thermal decomposition properties of Mg–Fe hydrotalcites were studied through in situ ⁵⁷Fe Mössbauer spectroscopy and in situ X-ray diffraction. Abrupt changes in the quadrupolar splitting measured in the Mössbauer spectra revealed a phase transition from the starting lamellar structure to a new crystalline arrangement. By analyzing the Mössbauer parameters we show that the material is highly disordered in the 300–400 °C temperature range. This hypothesis is confirmed by the X-ray results whose diffractograms indicated the collapse of the lamellar structure and the formation of a solid solution.     

The risk of seroconversion in surgeons of the hepatitis B, hepatitis C and human immunodeficiency viruses (in a specific surgical population)

The prevalence of hepatitis B surface antigen (HBs Ag) and antibody to hepatitis C virus (HCV) and human immunodeficiency virus (HIV) was determined in the serum specimens of 288 patients treated surgically in the orthopaedic department of an urban public teaching hospital. The cumulative risk of HBV, HCV and HIV seroconversion for an orthopaedic surgeon during the surgical career span was calculated. We found that 1.4%, 3.1% and 1.7% of patients were seropositive for HBsAg, HCV antibody and HIV antibody, respectively. Seropositivity was neither associated with age nor with trauma, whereas male patients had a greater likelihood of seropositivity. Risk factor assessment did not prove to be discriminating in identifying which patients may pose a potential exposure risk. This study supports the concept of universal infection control precautions for orthopaedic surgeons regardless of the patients' risk factor or serologic status.     

Landsat-7 ETM+ on-orbit reflective-band radiometric stability and absolute calibration

Launched in April 1999, the Landsat-7 Enhanced Thematic Mapper Plus (ETM+) instrument is in its sixth year of operation. The ETM+ instrument has been the most stable of any of the Landsat instruments. To date, the best onboard calibration source for the reflective bands has been the Full Aperture Solar Calibrator, a solar-diffuser-based system, which has indicated changes of between 1% to 2% per year in the ETM+ gain for bands 1-4 and 8 and less than 0.5%/year for bands 5 and 7. However, most of this change is believed to be caused by changes in the solar diffuser panel, as opposed to a change in the instrument's gain. This belief is based partially on vicarious calibrations and observations of "invariant sites", hyperarid sites of the Sahara and Arabia. Weighted average slopes determined from these datasets suggest changes of 0.0% to 0.4% per year for bands 1-4 and 8 and 0.4% to 0.5% per year for bands 5 and 7. Absolute calibration of the reflective bands of the ETM+ is consistent with vicarious observations and other sensors generally at the 5% level, though there appear to be some systematic differences.     

Link quality estimation in wireless multi-hop networks using Kernel based methods

A new approach for link modelling in wireless multi-hop networks is described for portable devices, based on Kernel Regression Statistics. A non-parametric estimation of errors in the wireless medium provides an efficient and accurate model of link errors between any two nodes. This estimation results from the analysis of the inter-arrival time between any periodically sent packets. The obtained results prove that it is possible to infer on link quality without having unrealistic assumptions or additional overhead, by using Kernel Methods. Moreover, similar performances were achieved for different scenarios, without requiring model recalculations. The presented results show that the proposed link quality estimation can be used in order to improve wireless connectivity and ubiquity in future networks.     

Modeling and solving the rooted distance-constrained minimum spanning tree problem

In this paper we discuss models and methods for solving the rooted distance constrained minimum spanning tree problem which is defined as follows: given a graph G=(V,E)$G=(V,E)$ with node set V={0,1,…,n}$V=\{0,1,\dots ,n\}$ and edge set E$E$, two integer weights, a cost _ce$c_e$ and a delay _we$w_e$ associated with each edge e$e$ of E$E$, and a natural (time limit) number H$H$, we wish to find a spanning tree T$T$ of the graph with minimum total cost and such that the unique path from a specified root node, node 0, to any other node has total delay not greater than H$H$. This problem generalizes the well known hop-constrained spanning tree problem and arises in the design of centralized networks with quality of service constraints and also in package shipment with service guarantee constraints. We present three theoretically equivalent modeling approaches, a column generation scheme, a Lagrangian relaxation combined with subgradient optimization procedure, both based on a path formulation of the problem, and a shortest path (compact) reformulation of the problem which views the underlying subproblem as defined in a layered extended graph. We present results for complete graph instances with up to 40 nodes. Our results indicate that the layered graph path reformulation model is still quite good when the arc weights are reasonably small. Lagrangian relaxation combined with subgradient optimization procedure appears to work much better than column generation and seems to be a quite reasonable approach to the problem for large weight, and even small weight, instances.     

A comparison of directed formulations for the capacitated minimal spanning tree problem

In this paper, we compare linear integer programming directed formulations for the capacitated minimal spanning tree (CMST) problem. This problem is directly related to network design and consists of finding the cheapest way to link a set of terminals at different locations with a central node (a computer site, for instance). The present work focuses on a single commodity flow formulation presented in [3,4]. This formulation includes two sets of variables and, hence, it also must include coupling constraints between the two sets of variables. These coupling constraints can be defined in several ways. The main result of this work establishes that when the strongest form of the coupling constraints is used in the flow formulation (as in [4]), the equivalent formulation using only theX _ij variables satisfies the so-called multistar constraints. These constraints are shown to be stronger than the weakest form of the generalized subtour breaking constraints and, hence, our result improves on the characterization given in [5] for the flow formulation presented in [4]. For certain parameters, the multistar constraints induce facets of the non-directed CMST polytope (see [2]). We also show that it is not possible to compare the linear relaxations of a formulation that involves the multistar constraints with one that involves the generalized subtour breaking constraints.     

Scientific productivity paradox: The case of China's S&T system

Summary In 1985 China began the reform of its Science & Technology (S&T) sector inherited from the planned economy. To disclose the impact of the drawn-out reform on the efficiency of the whole sector, we measure the scientific productivity of China's S&T institutes. The analysis is based on R&D input and output data at the country aggregate and provincial level. We utilize Polynomial Distributed Lag model to uncover the structure of the lag between R&D input and output. The findings reveal that the growth rate of scientific productivity of China's S&T institutes has been negative since the 1990s.     

A review on egomotion by means of differential epipolar geometry applied to the movement of a mobile robot

The estimation of camera egomotion is an old problem in computer vision. Since the 1980s, many approaches based on both the discrete and the differential epipolar constraint have been proposed. The discrete case is used mainly in self-calibrated stereoscopic systems, whereas the differential case deals with a single moving camera. This article surveys several methods for 3D motion estimation unifying the mathematics convention which are then adapted to the common case of a mobile robot moving on a plane. Experimental results are given on synthetic data covering more than 0.5 million estimations. These surveyed algorithms have been programmed and are available on the Internet.     

Product mix strategy and manufacturing flexibility

The manufacturing industry is facing a turbulent and constantly changing environment, with growing complexity and high levels of customisation. Any investment solution should address these problems for a dynamic market and within limited budget boundaries, so that companies try to remain competitive. The authors propose a real options model to support firms making important investment decisions, specifically decisions associated with the acquisition of new equipment aimed at allowing firms to increase their manufacturing flexibility for the production of both standard and customized products. This paper is partially based on a real operating experience related to visual finishing technology features in an industrial company that conforms to the definitions of the product mix. The authors’ motivation for this work is driven by firms’ desire to satisfy specific customer needs, and to respond to them quickly under uncertain demand. Our goal, using theories from finance, production management, and product offering management, is to conclude that there is a relevant difference between the evaluation of the technology that is to be chosen, and the potential value due to product mix adaptations that are able to provide the maximum return from investment. We address problems related to standard and customized production systems, and the decision to invest in a set of resources that will enable this choice.