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排序方式: 共有134条查询结果,搜索用时 15 毫秒
1.
Iryna Smokovych Manja Krüger Michael Scheffler 《Journal of the European Ceramic Society》2019,39(13):3634-3642
Silica-based coating systems were developed using polymer derived ceramics (PDCs) technology. Ceramic composites on the base of a SiO2 and SiNO matrix and homogeneously distributed Mo5SiB2, SiB6, Si and B fillers were manufactured. The coating systems have low porosity and provide a high oxidation resistance up to 100 h at 800 °C and 1100 °C in air. The influence of temperature and atmosphere of pyrolysis on the polymer precursor, the volume fraction of filler materials on the chemical composition of compacts as well as their high-temperature oxidation protection was investigated. 相似文献
2.
V. S. Tsyganenko N. V. Lityuga T. V. Dubovik G. K. Kozina A. A. Rogozinskaya V. M. Panashenko 《Powder Metallurgy and Metal Ceramics》2006,45(9-10):441-444
The properties of AlN-based materials with additives of 5–50 mass% Al2O3 are investigated. It is established that addition of Al2O3 to AlN increases the oxidation resistance of the materials as well as their mechanical strength and thermal resistance while preserving their electroinsulating properties and corrosion resistance to molten metals. AlN-Al2O3 composites may be used in high-temperature technology as refractory materials, electrical insulators, as well as radio-transparent materials. 相似文献
3.
Vadim S. Mikulich Alexander A. Muravsky Anatoli A. Murauski Iryna N. Kukhta Vladimir E. Agabekov Rashid Altamimi 《Journal of the Society for Information Display》2014,22(1):29-34
There are many photoaligned azo dyes that can be used for orientation of liquid crystals in various display devices. However, the structure of these compounds needs to be optimized to increase the rate of the process of molecule photoalignment, as well as to spread the application of these compounds. The main coordination metal that presents in the molecules of azo dyes is sodium derivatives. The use of other alkali metals remains an open question. We used quantum‐chemical computation methods and reversible intermolecular bonding model to determine the effect of metal coordination on the velocity of photoalignment. The theoretical predictions were experimentally verified using sodium, potassium, lithium, and cesium salts of the model azo dye synthesized by us. We conclude that potassium azo derivatives are the fastest, ceteris paribus. 相似文献
4.
A. B. Lysenko N. N. Kozina T. V. Gulyaeva V. V. Shibaev A. G. Glushkov 《Metal Science and Heat Treatment》1991,33(3):169-172
1. | In all the investigated steels saturation with boron leads to the formation of a heterophase structure characterized by dispersity of the structural components, chemical and structural inhomogeneity. In a thin surface layer of the treated zone metallography reveals molten boron particles which did not have time to react with the liquid metal. |
2. | In dependence on the marque of steel the boronized layers have different phase composition, and in addition to - and -solid solutions they contain iron boride Fe2B and also complex boron carbides with different stoichiometric composition. Metastable crystalline phases were not discovered in the investigated specimens. |
3. | Laser boronizing increases microhardness because of the more complex phase composition as well as other changes of the structure connected with the high cooling rates of the alloyed layers. |
5.
Productive wetland systems at land-water interfaces that provide unique ecosystem services are challenging to study because of water dynamics, complex surface cover and constrained field access. We applied object-based image analysis and supervised classification to four 32-m Beijing-1 microsatellite images to examine broad-scale surface cover composition and its change during November 2007-March 2008 low water season at Poyang Lake, the largest freshwater lake-wetland system in China (> 4000 km2). We proposed a novel method for semi-automated selection of training objects in this heterogeneous landscape using extreme values of spectral indices (SIs) estimated from satellite data. Dynamics of the major wetland cover types (Water, Mudflat, Vegetation and Sand) were investigated both as transitions among primary classes based on maximum membership value, and as changes in memberships to all classes even under no change in a primary class. Fuzzy classification accuracy was evaluated as match frequencies between classification outcome and a) the best reference candidate class (MAX function) and b) any acceptable reference class (RIGHT function). MAX-based accuracy was relatively high for Vegetation (≥ 90%), Water (≥ 82%), Mudflat (≥ 76%) and the smallest-area Sand (≥ 75%) in all scenes; these scores improved with the RIGHT function to 87-100%. Classification uncertainty assessed as the proportion of fuzzy object area within a class at a given fuzzy threshold value was the highest for all classes in November 2007, and consistently higher for Mudflat than for other classes in all scenes. Vegetation was the dominant class in all scenes, occupying 41.2-49.3% of the study area. Object memberships to Vegetation mostly declined from November 2007 to February 2008 and increased substantially only in February-March 2008, possibly reflecting growing season conditions and grazing. Spatial extent of Water both declined and increased during the study period, reflecting precipitation and hydrological events. The “fuzziest” Mudflat class was involved in major detected transitions among classes and declined in classification accuracy by March 2008, representing a key target for finer-scale research. Future work should introduce Vegetation sub-classes reflecting differences in phenology and alternative methods to discriminate Mudflat from other classes. Results can be used to guide field sampling and top-down landscape analyses in this wetland. 相似文献
6.
Stepan Kudria Iryna Ivanchenko Borys Tuchynskyi Kateryna Petrenko Oleksii Karmazin Oleksandr Riepkin 《International Journal of Hydrogen Energy》2021,46(1):157-168
The paper provides an assessment of the current wind energy potential in Ukraine, and discusses developmental prospects for wind-hydrogen power generation in the country. Hydrogen utilization is a highly promising option for Ukraine's energy system, environment, and business. In Ukraine, an optimal way towards clean zero-carbon energy production is through the development of the wind-hydrogen sector. In order to make it possible, the energy potential of industrial hydrogen production and use has to be studied thoroughly.Ukraine possesses huge resources for wind energy supply. At the beginning of 2020, the total installed capacity of Ukrainian wind farms was 1.17 GW. Wind power generation in Ukraine has significant advantages in comparison to the use of traditional sources such as thermal and nuclear energy.In this work, an assessment of the wind resource potential in Ukraine is made via the geographical approach suggested by the authors, and according to the «Methodical guidelines for the assessment of average annual power generation by a wind turbine based on the long-term wind speed observation data». The paper analyses the long-term dynamics of average annual wind speed at 40 Ukrainian weather stations that provide valid data. The parameter for the vertical wind profile model is calculated based on the data reanalysis for 10 m and 50 m altitudes. The capacity factor (CF) for modern wind turbine generators is determined. The CF spatial distribution for an average 3 MW wind turbine and the power generation potential for the wind power plants across the territory of Ukraine are mapped.Based on the wind energy potential assessment, the equivalent possible production of water electrolysis-derived green hydrogen is estimated. The potential average annual production of green hydrogen across the territory of Ukraine is mapped.It is concluded that Ukraine can potentially establish wind power plants with a total capacity of 688 GW on its territory. The average annual electricity production of this system is supposed to reach up to 2174 bln kWh. Thus, it can provide an average annual production of 483 billion Nm3 (43 million tons) of green hydrogen by electrolysis. The social efficiency of investments in wind-hydrogen electricity is presented. 相似文献
7.
Statistical and electrical properties of the conduction electrons of a silver or gold sphere with a radius from 1 to 2 nm are shown to differ drastically from the properties of electrons in a bulk metal sample. If the radius of a noble metal sphere decreases from 10 to 1 nm, its conductivity oscillates around the bulk metal value with increasing amplitude and drops at the ''magic’ numbers of electrons. These numbers are equal to 186, 198, 254, 338, 440, 556, 676, 832, 912, 1,284, 1,502, and 1,760, in agreement with various experimental data. We show that the conductivity and capacitance of a metal nanosphere can be changed by several orders of magnitude by adding or removing just a few electrons. 相似文献
8.
9.
Dielectric and thermal studies of segmental dynamics in silica/PDMS and silica/titania/PDMS nanocomposites 下载免费PDF全文
Iryna Sulym Panagiotis Klonos Mykola Borysenko Polycarpos Pissis Vladimir M. Gun'ko 《应用聚合物科学杂志》2014,131(23)
Effects of silica and silica/titania nanoparticles on glass transition and segmental dynamics of poly(dimethylsiloxane) (PDMS) were studied for composites of a core–shell type using differential scanning calorimetry, thermally stimulated depolarization current, and dielectric relaxation spectroscopy techniques. Strong interactions between the filler and the polymer suppress crystallinity (Tc, Xc) and affect significantly the evolution of the glass transition in the nanocomposites. The segmental relaxation associated with the glass transition consists of three contributions, arising, in the order of decreasing mobility, from the bulk (unaffected) amorphous polymer fraction (α relaxation), from polymer chains restricted between condensed crystal regions (αc relaxation), and from the semi‐bound polymers in an interfacial layer with strongly reduced mobility due to interactions with surface hydroxyls of silica and silica/titania nanoparticles (α′ relaxation). The evolution of surface affected CH3 groups, as well as the degree of interaction of PDMS molecules with surface hydroxyl groups as a function of treatment temperature, was assessed by Fourier transform infrared spectroscopy, thermogravimetry and differential thermal analysis. The effectiveness of silica/PDMS and silica/titania/PDMS nanocomposites as hydrophobic coatings was investigated by static contact angle measurements. It was shown that the presence of titania nanoparticles and adsorbed PDMS promotes the hydrophobic properties of the PDMS coating after treatment in the 80–650°C range. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41154. 相似文献
10.
Adel AA Mohdaly Mohamed A Sarhan Iryna Smetanska Awad Mahmoud 《Journal of the science of food and agriculture》2010,90(2):218-226
BACKGROUND: Growing interest in the replacement of synthetic food antioxidants by natural ones has fostered research on vegetable sources and screening of raw materials to identify new antioxidants. The food‐processing industry generates substantial quantities of phenolic‐rich by‐products that could be valuable natural sources of antioxidants. In this study the antioxidant properties and total phenolic, flavonoid and flavonol contents of three industrial by‐products, sugar beet pulp, sesame cake and potato peel, extracted with various solvents were examined. Since different antioxidant compounds have different mechanisms of action, several methods were used to assess the antioxidant efficacy of extracts. RESULTS: Among the six solvents tested, methanol gave the highest extract yield of potato peel and sugar beet pulp, while diethyl ether gave the highest extract yield of sesame cake. Methanol exhibited the highest extraction ability for phenolic compounds, with total phenolics amounting to 2.91, 1.79 and 0.81 mg gallic acid equivalent g?1 dry weight in potato peel, sugar beet pulp and sesame cake extracts respectively, and also showed the strongest antioxidant capacity in the three assays used. All three methods proved that potato peel extract had the highest antioxidant activity owing to its high content of phenolic compounds and flavonoids. CONCLUSION: On the basis of the results obtained, potato peel, sugar beet pulp and sesame cake extracts could serve as natural antioxidants owing to their significant antioxidant activity. Therefore they could be used as preservative ingredients in the food and/or pharmaceutical industries. Copyright © 2009 Society of Chemical Industry 相似文献