Enhanced strains of Nb-doped BNKT-4ST piezoelectric ceramics via phase boundary and domain design

A strategy that constructs the morphotropic phase boundary and manipulates the domain structure has been used to design the component of 0.96[Bi_0.5(Na_0.84K_0.16)_0.5Ti_(1-x)Nb_xO₃]-0.04SrTiO₃ (BNKT-4ST-100xNb) to enhance the strain properties for actuator application. Non-equivalent Nb⁵⁺ donor doping modulates the phase transition from the mixture of rhombohedral and tetragonal phases to the pseudocubic phase and results in the coexistence of multiple phases. Moreover, the high-resolution TEM confirms the existence of polar nano regions that contribute to the macroscopic relaxor behaviour. The size of the domains is reduced with increasing Nb⁵⁺, resulting in an enhanced relaxor behaviour. The ferroelectric-relaxor transition temperature decreases from 85 to below 30 °C, implying a non-ergodic to ergodic relaxor transition. An improved strain of 0.56% and a giant normalized strain of 1120 pm/V were achieved for BNKT-4ST-1.5Nb, which were attributed to the unique domain structure in which nanodomains are embedded in an undistorted cubic matrix. Ferroelectric, antiferroelectric, and relaxor phases coexist. As the electric field is large enough, a reversible phase transition occurs. Furthermore, good temperature stability was obtained due to the stability of the nanodomains, and no degradation in strains was observed even after 10⁴ cycles, which may originate from the reversible phase transition and dynamic domain wall. The results show that this design strategy offers a reference way to improve the strain behaviour and that BNKT-4ST-100xNb ceramics could be a potential material for high-displacement actuator applications.     

用于远程激光测距机的板条激光器

研制了用于远程激光脉冲测距机的板条激光器。使用半导体泵浦的MOPA激光结构实现了大于250 mJ的脉冲激光输出,输出脉冲宽度为12.83 ns,最终输出激光光束束散角为0.18 mrad。该激光测照器可应用于远程激光测距。对激光测距机的测距与照射能力进行了理论计算与分析。理论分析表明,应用于机载平台时,该激光测照器能够实现50 km距离的激光测距。该型激光测距机具有测距距离远,重量轻,结构紧凑等特点,具有广泛的应用前景。     

0Cr20Mn21Ni2N奥氏体不锈钢锻件组织性能研究

研究了无磁钻铤用0Cr20Mn21Ni2N奥氏体不锈钢圆棒锻件横截面的室温强度、硬度和韧性等力学性能,并从微观角度进行了分析。在圆棒表层区域观察到了锻造变形态晶粒组织,而直径四分之一区域为再结晶组织,平均晶粒尺寸为80μm,芯部再结晶晶粒尺寸粗化为150μm,这些差异是由不同的变形温度和降温速度造成的。这种组织差异导致的室温拉伸性能和冲击韧性也有相应的变化趋势。研究结果表明,在900、1000℃以0.5 s-1的应变速率压缩的0Cr20Mn21Ni2N试验钢样品,其应力应变曲线具有一定的加工硬化特征,其芯部硬度比应变速率为0.1 s-1的样品分别提升了28、15 HB。在700、800℃以20%以上的变形量进行压缩时,峰值抗力显著提高,而在900、1000℃以10%~50%的变形量进行压缩时,峰值抗力均无明显提高,可保证顺利的变形过程。     

PVC树脂聚合用有机过氧化物引发剂

介绍了目前国内外引发剂的使用及开发方向,并对引发剂的选择及其对树脂质量的影响进行了讨论。     

Preparation of a pitch-based activated carbon with a high specific surface area

Pitch based activated carbons (PAC) with a high specific surface area were produced by a direct chemical activation route in which oxidative stabilized pitch derived from ethylene tar oil was reacted with potassium hydroxide under various activation conditions. It was found that PACs with a surface area of around 2600–3600 m² g^-1 could be obtained under suitable activation conditions. N₂ adsorption (at 77 K) and X-ray photoelectron spectroscopy experiments showed that the PAC has a uniformly developed micropore structure and a narrow pore size distribution (radius 0.8–1.6 nm). Abundant oxygen-containing functional groups (such as C–OH, C–O–C, C=O, COOR etc.) were found to exist on its surface. Compared with a commercially available activated carbon (AC) and also a pitch based activated carbon fibre, PAC has a quicker adsorption–desorption velocity and a larger adsorptive capacity to benzene due to its higher surface area. Clear surface differences between PAC and AC were observed by transmission electron microscopy. This revised version was published online in November 2006 with corrections to the Cover Date.     

食品中病原菌检测技术研究进展

介绍了许多食品安全检测新技术和新方法,包括生化检测技术、免疫学技术、PCR检测技术、生物芯片技术、传感器技术、流式细胞术和基因探针技术,并且阐述了食品安全检测技术的发展趋势,这些技术的发展将会在食品卫生检验方面起到越来越重要的作用,最终将达到预防肠道传染病和食物中毒发生的目的。     

基于基尼系数的Web社区稳定性度量

Web社区是互联网中自组织程度较高的部分,它不是一个孤立系统,而是一个耗散系统,很多时候涨落无法耗散摔,导致社区运行不稳定.基尼系数可以用来衡量Web社区稳定性,通过基尼系数的简易计算公式计算社区内部成员积分或者其它参数,可以得出Web社区稳定性的度量.该度量对于研究和利用Web社区具有重要参考意义.     

CARR水平孔道的设计特点

介绍了中国先进研究堆(CARR)水平孔道的用途、在堆本体的布置、水平孔道结构设计及设计方面的特点。     

Rational Design of Ag/ZnO Hybrid Nanoparticles on Sericin/Agarose Composite Film for Enhanced Antimicrobial Applications

Silver-based hybrid nanomaterials are receiving increasing attention as potential alternatives for traditional antimicrobial agents. Here, we proposed a simple and eco-friendly strategy to efficiently assemble zinc oxide nanoparticles (ZnO) and silver nanoparticles (AgNPs) on sericin-agarose composite film to impart superior antimicrobial activity. Based on a layer-by-layer self-assembly strategy, AgNPs and ZnO were immobilized on sericin-agarose films using the adhesion property of polydopamine. Scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray powder diffraction spectroscopy were used to show the morphology of AgNPs and ZnO on the surface of the composite film and analyze the composition and structure of AgNPs and ZnO, respectively. Water contact angle, swelling ratio, and mechanical property were determined to characterize the hydrophilicity, water absorption ability, and mechanical properties of the composite films. In addition, the antibacterial activity of the composite film was evaluated against Gram-positive and Gram-negative bacteria. The results showed that the composite film not only has desirable hydrophilicity, high water absorption ability, and favorable mechanical properties but also exhibits excellent antimicrobial activity against both Gram-positive and Gram-negative bacteria. It has shown great potential as a novel antimicrobial biomaterial for wound dressing, artificial skin, and tissue engineering.     

基于虚拟相引入的CHB整流器控制策略

以三级式电力电子变压器的输入端级联H桥整流器为研究对象,针对系统运行的稳定性,借鉴双环控制思想,提出CHB整流器的双环控制方法。同时,针对其无功损耗、能量传输效率问题,提出一种基于虚拟相引入的共同占空比控制策略。在Matlab/Simulink平台搭建仿真模型,对所提出的CHB整流器的双环控制方法和基于虚拟相引入的共同占空比控制策略,与传统的控制策略进行对比分析,结果表明,所提策略可以有效减少谐波含量、降低无功损耗,提高系统运行的稳定性,改善系统的动态性能。