Fabrication of crescent-shaped ceramic microparticles based on single emulsion microfluidics

Ceramic microparticles have great potentials in various fields such as materials engineering, biotechnology, microelectromechanical systems, etc. Morphology of the microparticle performs an important role on their application. To date, it remains difficult to find an effective and controllable way for fabricating nonspherical ceramic microparticles with 3D features. This work demonstrates a method that combines UV light lithography and single emulsion opaque-droplet-templated microfluidic molding to prepare the crescent-shaped ceramic microparticles. By tailoring the intensity of UV light and flow rate of fluid, the shapes of microparticles are accordingly tuned. Therefore, varieties of crescent-shaped microparticles and their variations have been fabricated. After sintering, the crescent-shaped alumina ceramic microparticles were obtained. Benefitting from the light absorption and scattering behavior of most ceramic nanoparticles, this system can serve as a general platform to produce crescent-shaped microparticles made from different materials, and hold great potentials for applications in microrobotics, structural materials in MEMS, and biotechnology.     

25%小偏置碰撞策略及测试评估研究

随着汽车事故的增加,且小重叠碰撞事故死亡率居高不下,小偏置碰撞试验逐渐成为焦点。基于IIHS公布的最新车辆碰撞试验结果,统计超过100余款不同类型的25%小偏置碰撞车辆,建立碰撞转角与碰撞区域的数学模型,将25%小偏置碰撞归结为三种不同的碰撞策略,分别是吸能策略、掠过策略和掠过与吸能策略;并进行试验验证,对三种策略的优缺点进行分析。结果表明,小偏置碰撞试验可运用合理的碰撞策略达到法规要求,对25%小偏置碰撞试验具有一定的参考价值。     

Solution-Synthesized Multifunctional Janus Nanotree Microswimmer

Synthetic active matters are perfect model systems for non-equilibrium thermodynamics and of great potential for novel biomedical and environmental applications. However, most applications are limited by the complicated and low-yield preparation, while a scalable synthesis for highly functional microswimmers is highly desired. In this paper, an all-solution synthesis method is developed where the gold-loaded titania-silica nanotree can be produced as a multi-functional self-propulsion microswimmer. By applying light, heat, and electric field, the Janus nanotree demonstrated multi-mode self-propulsion, including photochemical self-electrophoresis by UV and visible light radiation, thermophoresis by near-infrared light radiation, and induced-charge electrophoresis under AC electric field. Due to the scalable synthesis, the Janus nanotree is further demonstrated as a high-efficiency, low-cost, active adsorbent for water decontamination, where the toxic mercury ions can be reclaimed with enhanced efficiency.     

超高效液相色谱-串联质谱法同时检测糕点中6种甜味剂

目的建立超高效液相色谱-串联质谱法同时测定糕点中6种常用合成甜味剂的分析方法。方法选用超纯水作为提取溶剂,涡旋和超声提取后,低温离心,取部分上清液加入正己烷除脂,Waters Atlantis■T3色谱柱、甲醇-5 mmol/L甲酸铵(含0.1%甲酸)作为流动相、亲水亲脂平衡型固相萃取柱HLB(hydrophile-lipophile balance)净化。结果6种甜味剂在质量浓度为10~200 ng/mL的曲线范围内呈良好线性关系,相关系数r均大于0.999,平均加标回收率在85.0%-98.2%之间,相对平均偏差(relative standard deviation,RSD)为1.3%~6.7%。结论该方法具有前处理简单、灵敏度高、检测速度快等优点,适合糖精钠、甜蜜素、三氯蔗糖、阿斯巴甜、阿力甜、纽甜的检测,但不适用于安赛蜜的检测。     

基于GNSS的广电发射塔状态监测技术研究

随着全球卫星导航系统(Global Navigation Satellite System,GNSS)技术的迅速发展,定位精度持续优化,其应用范围越来越广.为了突破单基站载波相位差分(Real Time Kinematic,RTK)技术带来的局限性,网络RTK技术应运而生.网络RTK技术使设备在基准站网络覆盖范围内实现精准定位,因此在各个传统行业中的应用越来越广泛.广播电视的信号发射环节非常重要,由于广电发射塔一般地处高山地区,维护维修不便.基于此,设计一种基于网络RTK定位技术的高精度发射塔状态监测方法,可以在保证广电信号安全优质播出方面发挥重要作用.     

中药桂枝总黄酮的提取工艺研究

优化桂枝总黄酮的提取工艺，建立桂枝的提取和含量测定方法。通过单因素试验，考察提取方法、提取溶剂浓度、提取体积、提取时间对药材总黄酮含量的影响，采用正交试验，优化提取工艺条件，筛选出桂枝总黄酮的最佳提取工艺。总黄酮最佳提取工艺为75%乙醇、料液比1:40、回流提取时间60 min。该方法能有效测定桂枝药材总黄酮的含量，为该药材的质量标准研究提供一定的科学依据。本方法重复性较好、方法稳定、可行。     

Influence of CO2 inleakage on the slight-alkalization of generator internal cooling water

The slight-alkalization of generator internal cooling water (GICW) is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator. CO₂ inleakage is increasingly identified as a potential security risk for GICW system. In this paper, the influence of CO₂ inleakage on the slight-alkalization of GICW was theoretically discussed. Based on the equilibriums of the CO₂-NaOH-H₂O system, CO₂ inleakage saturation was derived to quantify the amount of the dissolved CO₂ in GICW. This parameter can be directly calculated with the measured conductivity and the [Na⁺] of GICW. The influence of CO₂ inleakage on the slight-alkalization conditioning of GICW and the measurement of its water quality parameters were then analyzed. The more severe the inleakage, the narrower the water quality operation ranges of GICW, resulting in the more difficult the slight-alkalization conditioning of GICW. The temperature calibrations of the conductivity and the pH value of GICW show non-linear correlations with the amount of CO₂ inleakage and the NaOH dosage. This study provides insights into the influence of CO₂ inleakage on the slight-alkalization of GICW, which can serve as the theoretical basis for the actual slight-alkalization when CO₂ inleakage occurs.     

床温及SNCR脱硝对CFB锅炉NOx和N2O排放影响的试验研究

为了研究循环流化床（CFB）锅炉燃用无烟煤时床温及选择性非催化还原（SNCR）脱硝对于NO和N2O排放的影响，在1 MW CFB试验装置上开展了试验研究。结果表明:床温由880 ℃提高到970 ℃，NO排放质量浓度由119.5 mg/m3上升到226.0 mg/m3，N2O排放质量浓度由216.0 mg/m3降低到102.2 mg/m3；在氨氮摩尔比（NSR）为0~3.7之间，随着NSR的提高，脱硝效率从0上升到50.72%；进一步提高NSR到5.2，脱硝效率升至53.61%，增加较为缓慢；随着NSR从0提高到1.7，N2O排放质量浓度由84.3 mg/m3上升至118.3 mg/m3，增长较为缓慢；进一步提高NSR至2.0，N2O排放质量浓度上升至187.7 mg/m3，增长速度提高；继续提高NSR至5.2，N2O排放质量浓度上升至381.4 mg/m3；CFB锅炉采用以尿素为还原剂的SNCR脱硝工艺时，单纯通过加大NSR来提高脱硝效率不仅效果有限，过量喷入的还原剂会造成N2O排放量的显著提高。     

基于信号增强的缓慢泄漏检测方法

目前管道泄漏检测方法可有效检测突发泄漏，对于缓慢泄漏则存在检测灵敏度低、定位不准确等问题。基于此，提出了一种基于信号增强的缓慢泄漏检测方法。通过信号压缩（抽取及移位）克服缓慢泄漏压力信号下降平缓的缺点；根据声波信号具有波形尖锐突出、对突发泄漏敏感的优点，通过建立以压力为输入、虚拟声波为输出的声波信号变送器模型，将压力信号转换为声波信号，克服了泄漏压力信号容易被淹没在管道压力波动及背景噪声中的缺点，实现了缓慢泄漏信号的增强；利用临近插值方法重构虚拟声波信号，基于延时互相关分析实现了缓慢泄漏的准确定位。实验结果表明，该方法具有显著的信号增强效果和定位精度，实现了缓慢泄漏的准确检测。