Synthesis of heterocyclic metal complexes and their evaluation as marine antifoulants

4-Amino-3-thio-1,24-triazolidine (L₁) and 4-amino-5-thio-1,3,4-thiadiazole (L_II) as well as their metal complexes of the general formulae ML_I·2H₂O and ML_IICl (M; Pb(II), Cd(II) and Zn(II)) were prepared. With Sn(II), we obtained Sn(L_I)₂·2H₂O and SnL_IICl, respectively. The structures of the compounds were identified through elemental analysis, and IR and UV spectra measurements, in addition to thermal analysis in case of the metal complexes. The antifouling properties of the compounds were tested by their incorporation into paint formulations which were applied to PVC substrates and tested in water from Alexandria western harbour. When the compounds were added at 17·5% by volume, the coated panels were fouled after 3 months of immersion. The addition of 6·7% by volume of tributyltin oxide to 15·8% of the prepared compounds in one formulation elevated the paint efficiency and prevented fouling for 11 months. Paint containing solely tributyltin oxide at the same concentration was inactive against algae.     

Effect of functional group of ferrocene redox substance on the transport properties of newly designed ion exchange membrane prepared from polymer gel

A different newly designed cationic exchange polymer membrane and anionic exchange polymer membrane were introduced, and also the transport properties of these polymeric membranes were investigated in this study. The transport properties of these polymer membranes in contact with ferrocene redox derivatives were estimated by using electrochemical techniques such as cyclicvoltammetry, chronopotentiometry, and chronoamperometry techniques, respectively. The used ferrocene redox substances, which have different functional groups, were (Ferrocenylmethyl) trimethylamonium iodide, FcMA, Ferrocenedimethanol, FcDM, and Ferrocene carboxylic acid, FcCA. It indicated that the performance of a membrane depended on the content of polymer gel, anionic exchange polymer site (20 wt % and 50 wt %) or cationic polymer exchange site (20 wt % and 50 wt %), and the efficiency of the functional groups of cationic and anionic exchange polymer site as well. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Water and salt permeability of reinforcement polymer‐gel composite membrane

The charged mosaic polymer membrane (CMM) without reinforcement and the composite charged mosaic polymer membrane (CCMM) with reinforcement were investigated in terms of salt and water transport (permeability). The composite charged mosaic polymer membrane (CCMM) with reinforcement showed a unique transport behavior such as preferential material transport L_p and ω. Water permeability coefficient, L_p and salt permeability coefficient, ω were estimated by taking account of active layer thickness of composite polymer gel. The L_p and ω values of CCMM with reinforcement were larger than those of CMM without reinforcement. On the other hand, the reflection coefficient of CCMM, σ, showed negative value, which suggested preferential material transport to solvent transport. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Hash key-based image encryption using crossover operator and chaos

This paper proposes a color image encryption scheme using one-time keys based on crossover operator, chaos and the Secure Hash Algorithm(SHA-2). The (SHA-2) is employed to generate a 256-bit hash value from both the plain-image and the secret hash keys to make the key stream change in each encryption process. The SHA-2 value is employed to generate three initial values of the chaotic system. The permutation-diffusion process is based on the crossover operator and XOR operator, respectively. Experimental results and security analysis show that the scheme can achieve good encryption result through only one round encryption process, the key space is large enough to resist against common attacks,so the scheme is reliable to be applied in image encryption and secure communication.     

Fuzzy fault tolerant predictive control for a diesel engine air path

This paper proposes a Fuzzy Fault Tolerant Predictive Control (FFTPC) with integral action method for a class of nonlinear systems. The Takagi-Sugeno (T-S) fuzzy approach is introduced as a modelling technique in order to consider the active control methods adapted to linear models. The proposed control strategy is based on a combination between Parallel Distributed Compensation (PDC) control law and Model Predictive Control (MPC) where the T-S fuzzy aspect uses the Unmeasurable Premise Variables (UPV). A T-S fuzzy observer provides an L2 norm estimation of system state vector and faults. The controller and observer gains are obtained by solving Linear Matrix Inequalities (LMIs) derived from the Lyapunov theory. The validity of the proposed Fault Tolerant Control (FTC) strategy is illustrated through an application to a Diesel Engine Air Path (DEAP) system.     

Trust-based authentication scheme with user rating for low-resource devices in smart environments

In smart environments, pervasive computing contributes in improving daily life activities for dependent people by providing personalized services. Nevertheless, those environments do not guarantee a satisfactory level for protecting the user privacy and ensuring the trust between communicating entities. In this study, we propose a trust evaluation model based on user past and present behavior. This model is associated with a lightweight authentication key agreement protocol (Elliptic Curve-based Simple Authentication Key Agreement). The aim is to enable the communicating entities to establish a level of trust and then succeed in a mutual authentication using a scheme suitable for low-resource devices in smart environments. An innovation in our trust model is that it uses an accurate approach to calculate trust in different situations and includes a human-based feature for trust feedback, which is user rating. Finally, we tested and implemented our scheme on Android mobile phones in a smart environment dedicated for handicapped people.     

Numerical modeling of ZnSnO/CZTS based solar cells

Numerical simulation has been performed to improve the performance of Cu2ZnSnS4 (CZTS) solar cells by replacing CdS with Zn1–xSnxO buffer layer. The influences of thickness, donor concentration and defect density of buffer layers on the performance of CZTS solar cells were investigated. It has been found that Zn1–xSnxO buffer layer for Sn content of 0.20 is better for CZTS solar cell. A higher efficiency can be achieved with thinner buffer layer. The optimized solar cell demonstrated a maximum power conversion efficiency of 13%.     

An Efficient Schema Transformation Technique for Data Migration from Relational to Column-Oriented Databases

Data transformation is the core process in migrating database from relational database to NoSQL database such as column-oriented database. However, there is no standard guideline for data transformation from relational database to NoSQL database. A number of schema transformation techniques have been proposed to improve data transformation process and resulted better query processing time when compared to the relational database query processing time. However, these approaches produced redundant tables in the resulted schema that in turn consume large unnecessary storage size and produce high query processing time due to the generated schema with redundant column families in the transformed column-oriented database. In this paper, an efficient data transformation technique from relational database to column-oriented database is proposed. The proposed schema transformation technique is based on the combination of denormalization approach, data access pattern and multiple-nested schema. In order to validate the proposed work, the proposed technique is implemented by transforming data from MySQL database to HBase database. A benchmark transformation technique is also performed in which the query processing time and the storage size are compared. Based on the experimental results, the proposed transformation technique showed significant improvement in terms query processing time and storage space usage due to the reduced number of column families in the column-oriented database.     

Multi-Zone-Wise Blockchain Based Intrusion Detection and Prevention System for IoT Environment

Blockchain merges technology with the Internet of Things (IoT) for addressing security and privacy-related issues. However, conventional blockchain suffers from scalability issues due to its linear structure, which increases the storage overhead, and Intrusion detection performed was limited with attack severity, leading to performance degradation. To overcome these issues, we proposed MZWB (Multi-Zone-Wise Blockchain) model. Initially, all the authenticated IoT nodes in the network ensure their legitimacy by using the Enhanced Blowfish Algorithm (EBA), considering several metrics. Then, the legitimately considered nodes for network construction for managing the network using Bayesian-Direct Acyclic Graph (B-DAG), which considers several metrics. The intrusion detection is performed based on two tiers. In the first tier, a Deep Convolution Neural Network (DCNN) analyzes the data packets by extracting packet flow features to classify the packets as normal, malicious, and suspicious. In the second tier, the suspicious packets are classified as normal or malicious using the Generative Adversarial Network (GAN). Finally, intrusion scenario performed reconstruction to reduce the severity of attacks in which Improved Monkey Optimization (IMO) is used for attack path discovery by considering several metrics, and the Graph cut utilized algorithm for attack scenario reconstruction (ASR). UNSW-NB15 and BoT-IoT utilized datasets for the MZWB method simulated using a Network simulator (NS-3.26). Compared with previous performance metrics such as energy consumption, storage overhead accuracy, response time, attack detection rate, precision, recall, and F-measure. The simulation result shows that the proposed MZWB method achieves high performance than existing works     

A Navigation Aid for Blind People

This paper presents a navigation aid for the blind based on a microcontroller with synthetic speech output. The system consists of two vibrators, two ultrasonic sensors mounted on the user??s shoulders and another one integrated into the cane. It is able to give information to the blind about urban walking routes and to provide real-time information on the distance of over-hanging obstacles within 6 m along the travel path ahead of the user. The suggested system can then sense the surrounding environment via sonar sensors and sending vibro-tactile feedback to the user of the position of the closest obstacles in range. For the ultrasonic cane, it is used to detect any obstacle on the ground. Experimental results show the effectiveness of the proposed system for blind navigation.