Porosity-dependence of elastic properties and ultrasonic velocity in polycrystalline alumina — a model based on cylindrical pores

Effective elastic moduli and ultrasonic velocity of materials having aligned cylindrical pores have been derived using a series expansion in terms of the difference between the upper and lower bounds of elastic moduli obtained by the variational method. The theoretical results for polycrystalline alumina agree well with the experimental data, confirming the suggestion of previous researchers that a matrix containing parallel cylindrical pores orientated perpendicular to the applied stress, provide a better model than a spherical one in describing the porosity-dependence of elastic moduli in sintered specimens.     

Elastic properties of porous thermosetting polymers

A new equationE =E ₀ (1 –bp) ⁿ has been derived semi-empirically to describe the porosity dependence of elastic properties of thermosetting polymers. The material constantb is defined as a pore distribution geometry factor and the other material constantn is dependent on pore geometry. The equation shows good agreement with the data on porous polyester and epoxy resins.     

Young's modulus of porous brittle solids

A new equationE =E ₀ (1 –aP) ⁿ whereE andE ₀ are the Young's moduli at porosity,P, and zero, respectively, a andn are material constants, has been derived semi-empirically for describing the porosity dependence of Young's modulus of brittle solids. The equation satisfies quite well the exact theoretical solution for the values of Young's moduli at different porosities for model systems with ideal and non-ideal packing geometry. The equation shows excellent agreement with the data On- and-alumina over a wide range of porosity. Unlike the existing porosity-elastic modulus equations, the proposed equation satisfies the boundary conditions and is inherently capable of treating isometric closed pores as well as non-isometric interconnected pores. The parameters a and n provide information about the packing geometry and pore structure of the material.     

Evaluation of Concurrent Flaw Populations in Silicon Carbide in Terms of a Modified Weibull Distribution Function

Concurrent surface- and edge-flaw populations are often observed in strength testing of ceramics The overall strength distribution in such ceramic samples has been analyzed in terms of a modified Weibull distribution function. The junction provides an upper and lower strength limit and is characterized by two shape and location parameters. To evaluate the parameters of the distribution function, the type of flaw that causes failure need not be identified. The applicability of the function has been evaluated in terms of experimental results on SiC specimens. The analysis also shows that the relative values of shape parameters determine which flaw type dominates.     

Optical and structural properties of highly porous shell structured Fe doped TiO2 thin films

TiO2thin films with 0.2 wt%, 0.4 wt%, 0.6wt%, and 0.8 wt% Fe were prepared on glass and silicon substrates using sol–gel spin coating technique. The optical cut-off points are increasingly red-shifted and the absorption edge is shifted over the higher wavelength region with Fe content increasing. As Fe content increases, the optical band gap decreases from 3.03 to 2.48 eV whereas the tail width increases from 0.26 to 1.43 eV. The X-ray diffraction（XRD） patterns for doped films at 0.2 wt% and0.8 wt% Fe reveal no characteristic peaks, indicating that the film is amorphous whereas undoped TiO2exhibits（101） orientation with anatase phase. Thin films of higher Fe content exhibit a homogeneous, uniform, and nanostructured highly porous shell morphology.     

Disruption of ergosterol biosynthesis,growth, and the morphological transition in <Emphasis Type="Italic">Candida albicans</Emphasis> by sterol methyltransferase inhibitors containing sulfur at C-25 in the sterol side chain

The sterol substrate analog 25-thialanosterol and its corresponding sulfonium salt were evaluated for their ability to serve as antifungal agents and to inhibit sterol methyltransferase (SMT) activity in Candida albicans. Both compounds inhibited cell proliferation, were fungistatic, interrupted the yeastlike-form to germ-tube-form transition, and resulted in the accumulation of zymosterol and related Δ²⁴-sterols concurrent with a decrease in ergosterol, as was expected for the specific inhibition of SMT activity. Feedback on sterol synthesis was evidenced by elevated levels of cellular sterols in treated vs. control cultures. However, neither farnesol nor squalene accumulated in significant amounts in treated cultures, suggesting that carbon flux is channeled from the isoprenoid pathway to the sterol pathway with minor interruption or redirection until blockage at the C-methylation step. Activity assays using solubilized C. albicans SMT confirmed the inhibitors impair SMT action. Kinetic analysis indicated that 25-thialanosterol inhibited SMT with the properties of a time-dependent mechanismbased inactivator K _i of 5 =gmM and apparent k _inact of 0.013 min⁻¹, whereas the corresponding sulfonium salt was a reversible-type transition state analog exhibiting a K _i of 20 nM. The results are interpreted to imply changes in ergosterol homeostasis as influenced by SMT activity can control growth and the morphological transition in C. albicans, possibly affecting disease development.     

Estimation of Elastic Properties of Porous Ceramic Using Ultrasonic Longitudinal Wave Velocity Only

A method for estimation of the elastic moduli of porous ceramics solely based on ultrasonic longitudinal wave velocities is proposed. The method is based on a polynomial correlation between ultrasonic shear wave and longitudinal wave velocities of a given porous material. It is also shown that variations of Poisson's ratios for porous material with longitudinal wave velocities agree with the predictions of Mori-Tanaka mean field approach. The method provides a simplified route to quantitative non-destructive evaluation of the elastic moduli of porous material.     

The relations between the shear modulus, the bulk modulus and Young's modulus for porous isotropic ceramic materials

A relation between the shear modulus and Young's modulus of isotropic porous ceramics has been derived based on the Mori–Tanaka mean-field approach. The applicability of the relation has been evaluated using the experimental values available in the literature for the shear modulus, the bulk modulus and Young's modulus of porous ceramics prepared using various processing techniques and powder sizes. It is also shown that the ratio of the shear to Young's modulus of porous ceramics can be approximated by a constant value of 0.391.