Rapid Synthesis of Cobalt Metal Organic Framework

Metal-organic framework (MOF) has been shown to potential applications due to the high porous hybrid structure. Cobalt MOF was synthesized rapidly by ultrasound energy with about 3,000 m²/g surface area by BET method. Furthermore, this component is crystalline with significant thermal stability, on account of X-ray diffraction and thermal analysis, respectively. Based on high roughness, crystallinity, and unreported type of FTIR spectrum, a new structure of Co-MOF structure was proposed.     

A new nickel metal organic framework (Ni-MOF) porous nanostructure as a potential novel electrochemical sensor for detecting glucose

Journal of Porous Materials - A Ni-MOF-based novel electrochemical sensor was synthesized with high surface area of 1381 m2/g, significant porosity of 1.14–9.6 nm and average...     

An efficient and controllable ultrasonic-assisted microwave route for flower-like Ta(V)–MOF nanostructures: preparation,fractional factorial design,DFT calculations,and high-performance N<Subscript>2</Subscript> adsorption

With respect to different applications of metal–organic framework (MOF) in the medical, industrial and environmental fields, it is very important to choose a new structure that can be synthesized by fast, eco-friendly and affordable methods with distinctive properties so that the properties could be systematically controlled. In this study, new Ta–MOF nanostructures are synthesized by novel methods of microwave (Mw) and ultrasonic assisted microwave (UAMw) in environmental conditions. The final products are characterized by relevant techniques. Although in the both methods, the synthesized products have favourable properties; the use of the UAMw method would produce samples with distinct features such as high thermal stability of 240 °C, average particle size distribution (PSD) of 23 nm and significant specific surface area (SSA) of 2012 m²/g. For a better comprehension of the Ta–MOF formation, computational studies are performed using DFT calculations. In order to investigate the effect of the synthesis parameters on different features of the products, the fractional factorial design is used. The results of analysis of variance confirm that the parameters such as Mw power, Mw duration, ultrasonic temperature, ultrasonic power and ultrasonic duration have a significant effect on PSD and SSA of Ta–MOF samples. Due to the fractional factorial design of the experiments, response surface methodology would optimize the probability of producing samples with the small PSD of 15 nm and high SSA of 2588 m²/g; this desirable amount would provide situations to use these compounds in diverse fields.     

Synthesis of a novel Zn-MOF/PVA nanofibrous composite as bioorganic material: Design,systematic study and an efficient arsenic removal

Metal organic framework (Zn-MOF)/polyvinyl alcohol (PVA) nanofibrous composite new material has been fabricated using electrospinning and is characterized by a variety of physicochemical analyses, including Fourier transmitting infrared spectroscopy, X-ray powder diffraction (XRD), scanning electron microscopy-energy dispersive spectroscopy, nitrogen adsorption surface, and thermo gravimetric-derivative of thermogravimetry. In this study, the effects of a systematic study including a fractional factorial design were studied for arsenic removal. The results showed that although conventional methods have a high level of arsenic removal, the fractional factor method results in a relatively high level of absorption of arsenic. This high level of arsenic removal allows the potential use of nano adsorbents in various environmental fields. The systematic study developed in this study can be used as a novel protocol to eradicate pollution from different areas, including water, air, and soil.     

Sol–gel synthesis of silicon carbide on silicon pyramids: a promising candidate for supercapacitor electrodes

In this study, Si porous pyramids nanostructures were synthesized by the metal-assisted chemical etching technique. Different KOH concentrations were used to develop high surface area Si porous pyramids for application as supercapacitor electrodes. Field-emission scanning electron microscope (FE-SEM) studies showed that 5% KOH solution will lead to high surface area Si pyramids with a specific capacitance of 90.3 F/cm². Silicon carbide (SiC) thin film was coated on Si pyramids (SiC@Si) using a facile sol–gel method followed by a carbothermal reduction process. Tetraethylorthosilicate and sugar were used as carbon sources. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and FE-SEM analysis were used to characterize the developed SiC@Si samples. The developed SiC@ Si electrode exhibited a high specific capacitance of 135.5 F/cm² at a scan rate of 10 mV/s (in 1 M NaOH electrolyte). The supercapacitor capability of this SiC@Si structure is significantly higher than classical materials. Because of its facile, controllable and efficient synthesis technique, this novel SiC@Si can be considered a very promising candidate for power sources applications.

     

Modeling and Stimulating Node Cooperation in Wireless Ad Hoc Networks

In wireless networks, cooperation is necessary for many protocols, such as routing, clock synchronization, and security. It is known that cooperator nodes suffer greatly from problems such as increasing energy consumption. Therefore, rational nodes have no incentive to cooperatively forward traffic for others. A rational node is different from a malicious node. It is a node that makes the best decision in each state (cooperate or non‐cooperate). In this paper, game theory is used to analyze the cooperation between nodes. An evolutionary game has been investigated using two nodes, and their strategies have been compared to find the best one. Subsequently, two approaches, one based on a genetic algorithm (GA) and the other on learning automata (LA), are presented to incite nodes for cooperating in a noisy environment. As you will see later, the GA strategy is able to disable the effect of noise by using a big enough chromosome; however, it cannot persuade nodes to cooperate in a noise‐free environment. Unlike the GA strategy, the LA strategy shows good results in a noise‐free environment because it has good agreement in cooperation‐based strategies in both types of environment (noise‐free and noisy).     

A new method of Bi-MOF nanostructures production using UAIM procedure for efficient electrocatalytic oxidation of aminophenol: a controllable systematic study

Journal of Applied Electrochemistry - Inverse micelle (IM) and ultrasound-assisted inverse micelle (UAIM) techniques were used to fabricate new Bi-MOF nanostructures. The results showed that the...     

A novel ultrasonic assisted-reverse micelle procedure to synthesize Eu-MOF nanostructure with high sono/sonophotocatalytic activity: a systematic study for brilliant green dye removal

Journal of Materials Science: Materials in Electronics - In recent years, one of the growing environmental concerns has been contamination of water sources by dyes. For solving this problem,...     

Optimization of the Length of Silicon Nanowires Prepared from MACE Method Using Gene Expression Programming and Genetic Algorithm

Silicon - Metal-assisted chemical etching (MACE) of silicon is used in this study to fabricate silicon nanowire arrays (SiNWs) of different length. This method was modeled using gene expression...     

Selecting the Appropriate Carbon Source in the Synthesis of SiC Nano-Powders Using an Optimized Fuzzy Model

Silicon - In this study, different sources of carbon in the synthesis of silicon carbide were evaluated using a multi-attribute group decision-making fuzzy model including IF-MAGDM method. In this...