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1.
Summary A study was made of the degree of splitting of coconut and soybean oils by the Twitchell process at 35±0.1°C. with no shaking
or stirring, using an agent consisting mainly of tetrabutyl naphthalene sulfonic acid with water or dilute sulfuric acid.
The degree of splitting was greater with sulfuric acid than with water. In general, the degree of splitting of soybean oil
was greater when the sulfonic acid was dissolved in the oil layer than when it was in water. The reverse was true with coconut
oil. Although addition of glycerol had no effect on the degree of splitting, addition of glacial acetic acid to the coconut
oil system decreased fat splitting to a considerable extent. Addition of coconut fatty acids to the coconut oil system had
little effect, but soybean fatty acids added to the soybean oil system markedly increased the degree of splitting.
For the first time it has been demonstrated that, at 35±0.1°C., splitting of a fat by the Twitchell process occurs in a stepwise
way. Coconut oil in contact with 1N sulfuric acid containing the sulfonic acid, corresponding to 1% by the weight of the oil, was about 90% split in 15 to 30
days, depending on the area of contact of the two layers. The diglyceride concentration reached a maximum during the early
days of the reaction and then decreased somewhat. Monoglyceride concentration appeared to reach a maximum more slowly and
then continued at that level as the concentrations of free fatty acids and glycerol steadily increased.
Presented at the symposia on fat of the Chemical Society of Japan, Nov. 10, 1954, and Nov. 8, 1955, Nagoya, Japan; and the
8th annual meeting of the Chemical Society of Japan, Apr. 2, 1955, Tokyo, Japan. 相似文献
2.
Imoto Taiji; Ueda Tadashi; Tamura Tomohiro; Isakari Yoshimasa; Abe Yoshito; Inoue Makoto; Miki Takeyoshi; Kawano Keiichi; Yamada Hidenori 《Protein engineering, design & selection : PEDS》1994,7(6):743-748
Mutations around His15 which lie far away from the active site,stimulated glycol chitin activity of lysozyme at physiologicaltemperature. Del-Argl4Hisl5 lysozyme, a mutant lysozyme whoseArgl4 and Hisl5 were deleted together, and has the highest activityamong these mutant lysozymes, had a similar binding abilityto a trimer of N-acetyl-glucosamine, a substrate analogue, relativeto native lysozyme. This suggests that the increased activitywas due to an increased kcat in the catalysis reaction. TheH-D exchange rate of the N-1 proton in the Trp63 which is locatedin the active site cleft, was enhanced in the Del-Argl4Hisl5lysozyme, while 2-D proton NMR analysis revealed no conformationalchange around Trp63. We conclude that some sort of fluctuationat the active site might be required for the manifestation ofactivity. This theory is supported by the finding that the Del-Argl4Hisl5lysozyme showed a shift in temperature dependency of activityto lower temperatures compared with that of native lysozyme. 相似文献
3.
An acetylene flame was photographed with an SIT camera through optical filters, and the signals were Abel transformed to obtain two-dimensional emission-intensity profiles. It was found that the intensive emissions of CH* and C*2 are localized at the feather boundary, while the OH* emission is localized at the intermediate zone. The structure of the acetylene flame was made clear: it consists of a carbon-radical-rich feather and an oxygen-radical-rich intermediate zone. The carbon-radical concentrations are approximately in equilibrium near the burner exit while they decrease almost linearly via interdiffusion and reactions with the oxygen-radicals in the intermediate zone.Numerical simulations including detailed gaseous and surface reactions reproduced well previous preliminary calculations showing that CH4 is rapidly produced in the boundary layer near the substrate followed by an increase in CH3. This result satisfactorily explains the measured dependence of growth rate on the substrate temperature and
ratio. 相似文献
4.
Keiji Nagatani Seiga Kiribayashi Yoshito Okada Kazuki Otake Kazuya Yoshida Satoshi Tadokoro Takeshi Nishimura Tomoaki Yoshida Eiji Koyanagi Mineo Fukushima Shinji Kawatsuma 《野外机器人技术杂志》2013,30(1):44-63
On March 11, 2011, a massive earthquake (magnitude 9.0) and accompanying tsunami hit the Tohoku region of eastern Japan. Since then, the Fukushima Daiichi Nuclear Power Plants have been facing a crisis due to the loss of all power that resulted from the meltdown accidents. Three buildings housing nuclear reactors were seriously damaged from hydrogen explosions, and, in one building, the nuclear reactions became out of control. It was too dangerous for humans to enter the buildings to inspect the damage because radioactive materials were also being released. In response to this crisis, it was decided that mobile rescue robots would be used to carry out surveillance missions. The mobile rescue robots needed could not be delivered to the Tokyo Electric Power Company (TEPCO) until various technical issues were resolved. Those issues involved hardware reliability, communication functions, and the ability of the robots' electronic components to withstand radiation. Additional sensors and functionality that would enable the robots to respond effectively to the crisis were also needed. Available robots were therefore retrofitted for the disaster reponse missions. First, the radiation tolerance of the electronic componenets was checked by means of gamma ray irradiation tests, which were conducted using the facilities of the Japan Atomic Energy Agency (JAEA). The commercial electronic devices used in the original robot systems operated long enough (more than 100 h at a 10% safety margin) in the assumed environment (100 mGy/h). Next, the usability of wireless communication in the target environment was assessed. Such tests were not possible in the target environment itself, so they were performed at the Hamaoka Daiichi Nuclear Power Plants, which are similar to the target environment. As previously predicted, the test results indicated that robust wireless communication would not be possible in the reactor buildings. It was therefore determined that a wired communication device would need to be installed. After TEPCO's official urgent mission proposal was received, the team mounted additional devices to facilitate the installation of a water gauge in the basement of the reactor buildings to determine flooding levels. While these preparations were taking place, prospective robot operators from TEPCO trained in a laboratory environment. Finally, one of the robots was delivered to the Fukushima Daiichi Nuclear Power Plants on June 20, 2011, where it performed a number of important missions inside the buildings. In this paper, the requirements for the exploration mission in the Fukushima Daiichi Nuclear Power Plants are presented, the implementation is discussed, and the results of the mission are reported. 相似文献
5.
Yasunobu Hitaka Yoshito Tanaka Yutaka Tanaka Ken Ichiryu 《Artificial Life and Robotics》2009,14(4):494-497
A tripod parallel mechanism consists of three links of fixed length and a rigid platform, and these are connected by revolute
joints. The platform can achieve sixdegrees-of-freedom (6-DOF) motion by the coordinated movement of the bottom ends of the
three links on a horizontal plane. This mechanism has advantages over the more common six extendible parallel manipulators.
It has a much larger work space and a simple structure. In this article, we show that the vector analysis for this tripod
parallel mechanism and the derivation of the positions of the three bottom ends of the links in an arbitrary attitude of platform
can be found by inverse kinematics and the conditions of geometrical constraint. Then, by a numerical simulation, the trajectories
of the bottom ends of the three links are shown. 相似文献
6.
Greedy versus social: resource-competing oscillator network as a model of amoeba-based neurocomputer
A single-celled amoeboid organism, the true slime mold Physarum polycephalum, exhibits rich spatiotemporal oscillatory behavior and sophisticated computational capabilities. The authors previously created
a biocomputer that incorporates the organism as a computing substrate to search for solutions to combinatorial optimization
problems. With the assistance of optical feedback to implement a recurrent neural network model, the organism changes its
shape by alternately growing and withdrawing its photosensitive branches so that its body area can be maximized and the risk
of being illuminated can be minimized. In this way, the organism succeeded in finding the optimal solution to the four-city
traveling salesman problem with a high probability. However, it remains unclear how the organism collects, stores, and compares
information on light stimuli using the oscillatory dynamics. To study these points, we formulate an ordinary differential
equation model of the amoeba-based neurocomputer, considering the organism as a network of oscillators that compete for a
fixed amount of intracellular resource. The model, called the “Resource-Competing Oscillator Network (RCON) model,” reproduces
well the organism’s experimentally observed behavior, as it generates a number of spatiotemporal oscillation modes by keeping
the total sum of the resource constant. Designing the feedback rule properly, the RCON model comes to face a problem of optimizing
the allocation of the resource to its nodes. In the problem-solving process, “greedy” nodes having the highest competitiveness
are supposed to take more resource out of other nodes. However, the resource allocation pattern attained by the greedy nodes
cannot always achieve a “socially optimal” state in terms of the public cost. We prepare four test problems including a tricky
one in which the greedy pattern becomes “socially unfavorable” and investigate how the RCON model copes with these problems.
Comparing problem-solving performances of the oscillation modes, we show that there exist some modes often attain socially
favorable patterns without being trapped in the greedy one. 相似文献
7.
Amoeba-based Chaotic Neurocomputing: Combinatorial Optimization by Coupled Biological Oscillators 总被引:1,自引:0,他引:1
Masashi Aono Yoshito Hirata Masahiko Hara Kazuyuki Aihara 《New Generation Computing》2009,27(2):129-157
We demonstrate a neurocomputing system incorporating an amoeboid unicellular organism, the true slime mold Physarum, known to exhibit rich spatiotemporal oscillatory behavior and sophisticated computational capabilities. Introducing optical
feedback applied according to a recurrent neural network model, we induce that the amoeba’s photosensitive branches grow or
degenerate in a network-patterned chamber in search of an optimal solution to the traveling salesman problem (TSP), where
the solution corresponds to the amoeba’s stably relaxed configuration (shape), in which its body area is maximized while the
risk of being illuminated is minimized.Our system is capable of reaching the optimal solution of the four-city TSP with a
high probability. Moreover, our system can find more than one solution, because the amoeba can coordinate its branches’ oscillatory
movements to perform transitional behavior among multiple stable configurations by spontaneously switching between the stabilizing
and destabilizing modes. We show that the optimization capability is attributable to the amoeba’s fluctuating oscillatory
movements. Applying several surrogate data analyses, we present results suggesting that the amoeba can be characterized as
a set of coupled chaotic oscillators.
相似文献
Kazuyuki AiharaEmail: |
8.
The conjugate gradient method is an effective method for large-scale unconstrained optimization problems. Recent research has proposed conjugate gradient methods based on secant conditions to establish fast convergence of the methods. However, these methods do not always generate a descent search direction. In contrast, Y. Narushima, H. Yabe, and J.A. Ford [A three-term conjugate gradient method with sufficient descent property for unconstrained optimization, SIAM J. Optim. 21 (2011), pp. 212–230] proposed a three-term conjugate gradient method which always satisfies the sufficient descent condition. This paper makes use of both ideas to propose descent three-term conjugate gradient methods based on particular secant conditions, and then shows their global convergence properties. Finally, numerical results are given. 相似文献
9.
Teemu?Lepp?nenEmail author José?álvarez Lacasia Yoshito?Tobe Kaoru?Sezaki Jukka?Riekki 《Autonomous Agents and Multi-Agent Systems》2017,31(1):1-35
We introduce mobile agents for mobile crowdsensing. Crowdsensing campaigns are designed through different roles that are implemented as mobile agents. The role-based tasks of mobile agents include collecting data, analyzing data and sharing data in the campaign. Mobile agents execute and control the campaign autonomously as a multi-agent system and migrate in the opportunistic network of participants’ devices. Mobile agents take into account the available resources in the devices and match participants’ privacy requirements to the campaign requirements. Sharing of task results in real-time facilitates cooperation towards the campaign goal while maintaining a selected global measure, such as energy efficiency. We discuss current challenges in crowdsensing and propose mobile agent based solutions for campaign execution and monitoring, addressing data collection and participant-related issues. We present a software framework for mobile agents-based crowdsensing that is seamlessly integrated into the Web. A set of simulations are conducted to compare mobile agent-based campaigns with existing crowdsensing approaches. We implemented and evaluated a small-scale real-world mobile agent based campaign for pedestrian flock detection. The simulation and evaluation results show that mobile agent based campaigns produce comparable results with less energy consumption when the number of agents is relatively small and enables in-network data processing with sharing of data and task results with insignificant overhead. 相似文献
10.
Yoshito Ohta Author vitae 《Automatica》2011,47(5):1001-1006
This paper studies the system transformation using generalized orthonormal basis functions that include the Laguerre basis as a special case. The transformation of the deterministic systems is studied in the literature, which is called the Hambo transform. The aim of the paper is to develop a transformation theory for stochastic systems. The paper establishes the equivalence of continuous and transformed-discrete-time stochastic systems in terms of solutions. The method is applied to the continuous-time system identification problem. It is shown that using the transformed signals the PO-MOESP subspace identification algorithm yields consistent estimates for system matrices. An example is included to illustrate the efficacy of the proposed identification method, and to make a comparison with the method using the Laguerre filter. 相似文献