A new approach to the learning effect: Beyond the learning curve restrictions

In this paper, we bring into the scheduling field a new model of the learning effect, where in two ways the existing approach is generalized. First we relax one of the rigorous constraints, and thus in our model each job can provide different experience to the processor. Second we formulate the job processing time as a non-increasing k-stepwise function, that, in general, is not restricted to a certain learning curve, thereby it can accurately fit every possible shape of a learning function. Furthermore, we prove that the problem of makespan minimization with the considered model is polynomially solvable if every job provides the same experience to the processor, and it becomes NP-hard if the experiences are diversified. The most essential result is a pseudopolynomial time algorithm that solves optimally the makespan minimization problem with any function of an experience-based learning model reduced into the form of the k-stepwise function.     

Structural and electrical properties of Cr-doped SrTiO3 porous materials

Series of single-phase materials with assumed formula SrTi_1?xCr_xO₃ (where x = 0, 1, 4, 6 mol.%) were obtained by sol-gel method. The structure and microstructure of materials were characterised by X-ray diffraction and scanning electron microscopy methods. Moreover, the study of electrical properties and evaluation of chemical stability in CO₂/H₂O atmosphere was performed by electrochemical impedance spectroscopy and thermogravimery methods, respectively. The possibility of participation of Cr-doped strontium titanate in oxidation–reduction processes was analysed by temperature-programed reduction (TPR) and temperature-programed oxidation (TPOx) measurements. The changes of lattice parameters together with XPS analysis, the Seebeck coefficient measurements results and TPR profiles obtained for SrTi_1?xCr_xO₃ materials prove the presence of chromium on +3 and +6 oxidation stages. Thus, chromium can be treated as both acceptor- and donor-type dopant in the SrTiO₃ structure. The Cr³⁺/Cr⁶⁺ ratio strongly affects the electrical properties, as the change of conduction mechanism was observed. The results of performed stability test clearly indicate that incorporation of chromium into SrTiO₃ structure results with decrease of chemical stability in CO₂ atmosphere.     

Preventing Listeria contamination in foods

Keeping ready-to-eat foods cold is key to reducing listeriosis, a serious infection in humans. That's one of the conclusions of a recent Food and Drug Administration risk assessment on the relationships between foodborne listeriosis and human health.     

The influence of ions’ substitution on the optical properties of A<Subscript>2</Subscript>MX<Subscript>4</Subscript> crystals

In this article, results based on the research of optical properties of A₂MX₄ type crystals (A—organic cation, M—metal, X—halogen) composed of different chemical elements are presented. These crystals were grown by the evaporation method from water solutions of AX and MX₂ compounds in an appropriate molar ratio. The conducted X-ray investigations show a different crystal structures, ranging from tetragonal to triclinic ones. Also, the structure of the ion complex for Cu²⁺ crystals varied. The investigation showed both CuCl₄²⁻ tetrahedral and CuCl₄ · 2H₂O²⁻ octahedral deformed complexes in investigated crystals. Additionally, the optical spectra of the samples were measured in the range of 250–850 nm. Based on the crystal field theory, it was shown that the shape of absorption spectra and colour of the crystals depend on the distortion of these complexes.     

Novel visible photoinitiators systems for free-radical/cationic hybrid photopolymerization

Free radical/cationic hybrid photopolymerization of acrylates and epoxides was induced using an initiator system comprised of the dye derivative 5,12-dihydroquinoxalino[2,3-b]quinoxaline or 5,12-dihydroquinoxalino[2,3-b]pyridopyrazine as the sensitizers and hexafluoroantimonate triarylsulfonium salt as the initiators. The curing experiments were carried out in the presence of air and the consumption of each monomer upon VIS-radiation was monitored in situ by real-time infrared spectroscopy. Hardness (H), elastic modulus (E) and the H/E ratio of the coatings obtained by visible-initiated acrylate/epoxide hybrid photopolymerization were determined using nanoindentation. DSC measurements show that the initiator system presented here may produce an interpenetrating polymer network. The pencil hardness of the obtained coatings indicates that the dye/hexafluoroantimonate triarylsulfonium salts systems studied here may have practical applications as visible-light hybrid initiators.