排序方式: 共有64条查询结果,搜索用时 31 毫秒
1.
Monolithic Catalysts with Low Noble-Metal Content for Exhaust Purification of Small Gasoline Engines
A series of low noble-metal coment monolithic catalysts for exhaust purification of small gasoline engines was investigated, and it was found that the Pt/Rh-OSM/Al2O3 (where OSM was oxygen storage material) catalyst with Ce0.5Zr0.5-MnOx(3%MnOx) OSM held low light-off temperature for CO, HC, and NO; quite wide three-way window, and outstanding thermal stability. The catalyst could efficiently comrol exhaust emission of small gasoline engines. 相似文献
2.
采用浸渍法制备了一系列低Pt、Rh含量的Pt-Rh型汽车尾气净化催化剂.研究了在Pt、Rh含量一定以及其他条件不变的情况下,只改变铑在不同栽体上的分配比对催化剂性能的影响,测定了催化剂对C3H8、CO、NO的起燃温度,并对催化剂样品进行了程序升温还原(H2-TPR)、程序升温脱附(O2-TPD)表征.结果表明:新鲜催化剂对C3H8、CO、NO的起燃温度相差不大,但经过1000℃、5h的水热老化后,催化剂性能发生了显著的变化,C3H8、CO、NO的起燃温度出现较大的差异,说明了铑在不同栽体上的分配比对催化剂性能有一定影响,特别是对催化剂的抗老化性能影响较大. 相似文献
3.
4.
Ce0.35Zr0.55Y0. 10 solid solution was prepared by co-precipitation technique and characterized by specific surface area measurements (BET) and X-ray diffraction (XRD). Ce0.35Zr0.55Y0.10 was used to prepare low Pt-Rh threeway catalyst (TWC), and its influence on the performance of TWC was investigated. The results revealed that Ce0.35 Zr0.55Y0.10 had a cubic structure similar to Ce0.50Zr0.50O2 and its specific surface area can maintain higher than Ce0.50 Zr0.50O2 after 1000 ℃ calcination for 5 h. Being hydrothermal aged at 1000 ℃ for 5 h, the catalyst containing Ce0.35 Zr0.55Y0.10 still exhibited higher conversion of C3H8, CO and NO and lower light-off temperature in comparison with Ce0.50Zr0.50O2 TWC. 相似文献
5.
Nickel catalysts supported on CeO2-ZrO2-CeO2,ZrO2-Al2O3 and Al2O3 were prepared and characterized by means of X-ray diffraction(XRD),BET areas,H2 temperature-programmed reduction(H2-TPR),and X-ray photoelectron spectroscopy(XPS).Through the test of catalytic partial oxidation of methane(CPOM),Ni/CeO2-ZrO2-Al2O3 displayed the highest activity,which resulted from its largest BET area and best NiO dispersion.Furthermore,Ni/CeO2-ZrO2-Al2O3 maintained a long-time stability in CPOM,which was attributed to its best coking resistance among all the prepared catalysts. 相似文献
6.
甲烷在整体式Co基催化剂上的燃烧性能 总被引:1,自引:0,他引:1
以Ce0.25Zr0.50Mn0.25O2(OSM)和YSZ—Al2O3(Y2O3,ZrO2稳定的γ—Al2O3)为载体,制备了Co/OSM和Co/YSZ—Al2O3整体式催化剂,以及不同Co/OSM:Co/YSZ—Al2O3比例的Co/OSM Co/YSZ-Al2O3整体式催化剂.研究了上述催化剂的甲烷催化燃烧性能,并利用XRD和H2-TPR对催化剂进行了表征.XRD结果表明,在OSM和YSZ-Al2O3上Co均以高分散形式存在.H2-TPR结果表明,Co/OSM Co/YSZ-Al2O3样品的可还原性随着Co/OSM含量的增加而提高,表现出可调节的还原性能.Co/OSM的甲烷燃烧催化活性高于Co/YSZ—Al2O3,Co/OSM Co/YSZ—Al2O3表现出协同作用和高活性. 相似文献
7.
对TiO2、Mn/TiO2、La/TiO2、La-Mn/TiO2、Li-Mn/TiO2、Li-La/TiO2和Li-La-Mn/TiO2等系列钛基甲烷氧化偶联催化剂的催化性能进行了考察,并用XRD和XPS对该系列催化剂进行了表征。实验结果表明,Li-La-Mn/TiO2催化剂对甲烷氧化偶联反应具有较高的反应活性和C2烃选择性。催化剂中Ti组分主要以+4价存在;Li组分能促进La与TiO2的相互作用,而形成钛酸镧,使La组分在催化剂表面的浓度减小,而Li组分本身则主要是以Li2SO4状态存在于催化剂中,是Mn/TiO2、La/TiO2、La-Mn/TiO2等催化剂的优良添加剂。Mn组分主要以低价(+2、+3)氧化物分布于催化剂表面,La、Mn的添加主要是使甲烷活化,提高催化剂的活性,Li组分的添加主要是提高甲烷氧化偶联反应的选择性即C2烃收率。 相似文献
8.
9.
采用浸渍法制备了MoO3/ZrO2, 用低温氮吸附-脱附法和NH3-程序升温脱附法(TPD)分别对其比表面积和酸碱性进行了表征. 结果表明, MoO3/ZrO2具有106.8m2/g的比表面积和超强酸的性能. 用等体积浸渍法制备了Pt/MoO3/ZrO2催化剂, 在汽车尾气模拟气中考察了其对C3H8、CO和NO的催化活性.与传统三效催化剂Pt/La2O3/Al2O3相比较, Pt/MoO3/ZrO2具有更好的低温起燃性能和更宽的空燃比窗口, 并显著地改善了C3H8在富氧状态下的转化效率. 通过XRD、H2-TPR对催化剂进行了表征, 结果表明, Pt在催化剂载体上具有高度的分散性和优异的氧化还原性能. 相似文献
10.
Complete oxidation of benzene over supported manganese oxides catalysts was studied.Composite supports Ce0.5+xZr0.4–xLa0.1O1.95-Al2O3 (x=0,0.1,0.2,0.3,0.4),and CeO2-Al2O3 were prepared by co-precipitation method,and manganese oxides (MnOx) catalysts were prepared by incipient wetness method.Catalytic activity was performed in a conventional fixed bed flow reactor.Among these catalysts,MnOx supported on Ce0.8Zr0.1La0.1O1.95-Al2O3 was found to have the highest catalytic activity for benzene oxidation.The comp... 相似文献