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1.
为配合化工产品新工艺的开发,研究了25~70 ℃硫酸钙-硫酸钠-铬酸钙-铬酸钠-水体系中复盐的生成规律.摇床实验及X射线衍射分析发现,将固体铬酸钙加入不同浓度的硫酸钠和铬酸钠溶液中时,除生成CaSO4·2H2O外,还可能生成4种复盐沉淀,即CaSO4·Na2SO4,CaSO4·Na2SO4·4H2O,CaSO4·2Na2SO4·2H2O和5CaSO4·Na2SO4·3H2O.当温度和溶液浓度发生变化时,复盐的形式会相应变化,低温稀溶液中只有CaSO4·2H2O沉淀,没有复盐沉淀析出,而高温浓溶液中,4种复盐都会析出. 相似文献
2.
Protection of water environment while developing socio-economy is a challenging task for lake regions of many developing countries. Poyang Lake is the largest fresh water lake in China, with its total drainage area of 160,000 km2. In spite of rapid development of socio-economy in Poyang Lake region in the past several decades, water in Poyang Lake is of good quality and is known as the "last pot of clear water" of the Yangtze River Basin in China. In this paper, the reasons of "last pot of clear water" of Poyang Lake were analysed to demonstrate how economic development and environmental protection can be coordinated. There are three main reasons for contributing to this coordinated development: 1) the unique geomorphologic features of Poyang Lake and the short water residence time; 2) the matching of the basin physical boundary with the administrative boundary; and 3) the implementation of "Mountain-River-Lake Program" (MRL), with the ecosystem concept of "mountain as source, river as connection flow, and lake as storage". In addition, a series of actions have been taken to coordinate development, utilisation, management and protection in the Poyang Lake basin. Our key experiences are: considering all basin components when focusing on lake environment protection is a guiding principle; raising the living standard of people through implementation of various eco-economic projects or models in the basin is the most important strategy; preventing soil and water erosion is critical for protecting water sources; and establishing an effective governance mechanism for basin management is essential. This successful, large-scale basin management model can be extended to any basin or lake regions of developing countries where both environmental protection and economic development are needed and coordinated. 相似文献
3.
Qi Jia Xin Ou Manuel Langer Benjamin Schreiber Jörg Grenzer Pablo F. Siles Raul D. Rodriguez Kai Huang Ye Yuan Alireza Heidarian René Hübner Tiangui You Wenjie Yu Kilian Lenz Jürgen Lindner Xi Wang Stefan Facsko 《Nano Research》2018,11(7):3519-3528
A nanofabrication method for the production of ultra-dense planar metallic nanowire arrays scalable to wafer-size is presented. The method is based on an efficient template deposition process to grow diverse metallic nanowire arrays with extreme regularity in only two steps. First, III–V semiconductor substrates are irradiated by a low-energy ion beam at an elevated temperature, forming a highly ordered nanogroove pattern by a “reverse epitaxy” process due to self-assembly of surface vacancies. Second, diverse metallic nanowire arrays (Au, Fe, Ni, Co, FeAl alloy) are fabricated on these III–V templates by deposition at a glancing incidence angle. This method allows for the fabrication of metallic nanowire arrays with periodicities down to 45 nm scaled up to wafer-size fabrication. As typical noble and magnetic metals, the Au and Fe nanowire arrays produced here exhibited large anisotropic optical and magnetic properties, respectively. The excitation of localized surface plasmon resonances (LSPRs) of the Au nanowire arrays resulted in a high electric field enhancement, which was used to detect phthalocyanine (CoPc) in surface-enhanced Raman scattering (SERS). Furthermore, the Fe nanowire arrays showed a very high in-plane magnetic anisotropy of approximately 412 mT, which may be the largest in-plane magnetic anisotropy field yet reported that is solely induced via shape anisotropy within the plane of a thin film. 相似文献
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随着开采深度的进一步增加,软破岩工程变得越来越突出。本文在分析软破岩石特点的基础上,提出了依据软破岩石三轴试验,而建立其破坏准则,为对软破岩的进一步深入研究提供了条件,同时为岩石强度的研究开辟了一条实用途径。 相似文献
6.
研究了焙烧填料贮存期对铬铁矿无钙焙烧过程的影响。结果表明,无钙焙烧浸出渣经分选后粗渣作为氧化焙烧填料时,填料的焙烧活性及填料性能随贮存期的延长而提高。在相同配料及焙烧条件下,随着填料贮存期的延长,氧化焙烧熟料中游离碱含量降低、水溶铬含量升高,回转窑的稳定运行时间增长。结合无钙焙烧生产铬盐的工业实践,填料的贮存风化期以6~8个月为宜。 相似文献
7.
模块化多电平换流阀(modular multi-level converter,MMC)作为统一潮流控制器(unified power flow controller,UPFC)系统中的关键设备,其运行的可靠性直接影响到整个系统的安全稳定运行。采用k/n(G)可靠性模型描述方法,清晰地描述了换流阀可靠性与各种冗余度之间的关系,定量计算了500 kV苏南UPFC换流阀的可靠性指标,并对换流阀可靠性进行了优化设计,满足500 kV苏南UPFC工程要求,并为UPFC换流阀冗余度设计和优化提供了参考依据。 相似文献
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9.
Wei Li Tiangui Liang Yuanchuang Lin Weixiong Wu Song Li 《International journal of molecular sciences》2022,23(22)
Capturing formaldehydes (HCHO) from indoor air with porous adsorbents still faces challenges due to their low capacity and poor selectivity. Metal-organic frameworks (MOFs) with tunable pore properties were regarded as promising adsorbents for HCHO removal. However, the water presence in humid air heavily influences the formaldehyde capture performance due to the competition adsorption. To find suitable MOFs for formaldehyde capture and explore the relationship between MOFs structure and performance both in dry air and humid air, we performed grand canonical Monte Carlo (GCMC) molecular simulations to obtain working capacity and selectivity that evaluated the HCHO capture performance of MOFs without humidity. The results reveal that small pore size (~5 Å) and moderate heat of adsorption (40–50 kJ/mol) are favored for HCHO capture without water. It was found that the structure with a 3D cage instead of a 2D channel benefits the HCHO adsorption. Atoms in these high-performing MOFs should possess relatively small charges, and large Lennard-jones parameters were also preferred. Furthermore, it was indicated that Henry’s constant (KH) can reflect the HCHO adsorption performance without humidity, in which the optimal range is 10−2–101. Hence, Henry’s constant selectivity of HCHO over water (SKH HCHO/H2O) and HCHO over mixture components (H2O, N2, and O2) was obtained to screen MOFs at an 80% humidity condition. It was suggested that SKH for the mixture component overestimates the influence of N2 and O2, in which the top structures absorb a quantity of water in GCMC simulation, while SKH HCHO/H2O can efficiently find high-performing MOFs for HCHO capture at humidity in low adsorption pressure. The ECATAT found in this work has 0.64 mol/kg working capacity, and barely adsorbs water during 0–1 bar, which is the promising candidate MOF for HCHO capture. 相似文献
10.
小官庄铁矿承压区两翼开采回采顺序的研究 总被引:2,自引:0,他引:2
本文以小官庄铁矿东区为工程背景,在详细分析了其地压环境、采准进度、各矿块完成采准的可能时间、回采展开条件以及对产量要求的满足程度等基础上,提出三种回采方案,并采用三维非线性有限元计算进行方案比较,最后提出最优方案并付诸工程实施。本项研究对采用无底柱分段崩落法回采的类似矿山具有一定的参考价值。 相似文献