三氨基胍与乙二醛反应相互作用能的理论研究

采用量子化学方法详细计算了三氨基胍与乙二醛反应中各分子的结构,反应相互作用能。计算结果表明,反应过程中A分子中2个亚氨基上的氮原子分别与B分子中的2个碳原子结合形成一个咪唑烷五员环,同时,原来B分子中的碳原子由sp~2杂化转变为sp~3杂化。反应过程中A和B分子由于结构变化造成的分子能量增量之和小于A和B分子相互作用(吸引)能的绝对值,因此,A和B分子可以结合生成C分子。     

电流互感器饱和对保护影响的仿真研究

目前广州地区10kV系统的短路电流水平较过去有了很大程度的提高,从而使电流互感器可能承受的短路电流远大于其一次额定准确限值电流,短路情况下电流互感器是否会发生饱和,是否会因此造成保护的不正确动作。这些是目前工程中急于解决,却难以定量分析的问题。本文通过建立电流互感器的EMTP仿真模型,定量分析了短路电流和二次负载变化对电流互感器饱和及保护测量值的影响及规律。     

Study on the dual-curing mechanism of epoxy/allyl compound/sulfur system

Allyl-based epoxy resin/Sulfur (S) system is a facile and novel dual-curing system which conducts a unique curing mechanism. In this paper, Bisphenol-A diglycidyl ether (BADGE) and 2-Allylphenol (OAP) cured by S were comparatively investigated to clarify the dual-curing mechanism of Epoxy (EP)/Allyl Compound (AC)/S system. When the temperature was above 170 °C, DSC and FTIR data showed that S could cleave to form thiyl radicals, and FTIR, NIR, and ¹H NMR measurements proved the disappearance of allyl groups and the generation of thiol groups by the thiyl radicals abstracting α-H atoms of allyl groups in the OAP/S reaction system. Real-time infrared spectroscopy (RT-FTIR) results showed that the reaction of the generation of thiol groups is the dominant reaction in the two possible pathways of the OAP/S system; allyl groups and epoxy groups disappeared sequentially in the OAP/S/BADGE system. DSC curve also revealed the one-stage reaction for OAP/S system and two-stage reaction for OAP/S/BADGE system. These data were used to develop a detailed, experimentally validated pathway for the dual-curing of EP/AC/S system, in which thiol groups are important intermediate, and the dual-curing process included the crosslinking of double bonds that initiated by thiyl radicals and the ring-opening reaction of epoxy groups with thiol groups. Besides, the dual-curing mechanism of EP/AC/S system shares a close resemblance to the classical rubber vulcanization mechanism and the recent thiol-ene radical addition mechanism.     

Human thermoregulation model for estimating thermal protection performance of anti-G garments

The body temperature of pilots wearing anti-G garments becomes uncomfortably or even dangerously high in moderate to hot environments.To reduce the body heat stress,thermal characteristics and thermal protection performance of anti-G garments should be studied systematically,but up to now there is no related research to simulate the anti-G garment thermal protection performance.First,a human thermoregulation model is established which can analyze blood convective heat exchange and the central blood temperature fluctuation,according to this model the heat and mass transfer processes of a thermal system are simulated which consists of human body,an anti-G garment,and the surrounding environment,then on the base of this thermal system simulation influences of clothing permeability,thermal resistance and bladder coverage on anti-G garments are analyzed.Calculation of the human thermoregulation model is carried out by using finite element method.Experiments are conducted in 35 ℃ and 40 ℃ climate chambers,and model built above is well validated by these experiments.Model simulation reveals that low thermal resistance and high permeability of anti-G garments reduce body heat stress in moderate environments.In hot environments,however,anti-G garments with lower thermal resistance increase body heat stress.The body heat stress rises significantly as the bladder coverage area of anti-G garments increases.Anti-G garments thermal parameters can be appropriately designed by using the model built in this paper to ensure body physiological requirements.     

黑龙江二克山与五大连池富钾火山岩特征及成因

二克山与五大连池火山岩为一套基性、酸性程度偏高、强碱性系列的富钾白榴橄榄玄武岩和白榴玄武岩组合。岩石成分，随ＳｉＯ２含量增加，Ａｌ２Ｏ３，Ｋ２Ｏ，Ｎａ２Ｏ增加，ＭｇＯ，ＣａＯ，ＦｅＯ降低。微量元素具有不相容元素强烈富集，相容元素较高的特征。地球化学特征表明，本区地幔曾受过部分熔融，导致地幔的亏损，尔后地幔又受到上升流体交代作用。地壳的同化混染，只能降低原生岩浆的基性度，不能使其富钾，表明源区可能存在着金云母熔融，在部分熔融程度较低条件下，形成原始富钾岩浆。     

Diagnose the mild cognitive impairment by constructing Bayesian network with missing data

Mild Cognitive Impairment (MCI) is thought to be the prodromal phase to Alzheimer’s disease (AD), which is the most common form of dementia and leads to irreversible neurogenerative damage of the brain. In order to further improve the diagnostic quality of the MCI, we developed a MCI expert system to address MCI’s prediction and inference question, consequently, assist the diagnosis of doctor. In this system, we mainly deal with following problems: (1) Estimate missing data in the experiment by utilizing mutual information and Newton interpolation. (2) Make certain the prior feature ordering in constructing Bayesian network. (3) Construct the Bayesian network (We term the algorithm as MNBN). The experimental results indicate that MNBN algorithm achieved better results than some existing methods in most instances. The mean square error comes to 0.0173 in the MCI experiment. Our results shed light on the potential application in MCI diagnosis.     

考虑主动管理措施的配电网无功补偿双层优化配置

为了适应未来大量分布式电源(DG)并网及自动化水平显著提高的主动配电网发展,在规划阶段应该考虑主动管理措施,优化系统运行方式。同时,现有的无功补偿规划研究忽略了DG及负荷的不确定性。为此,计及间歇性DG及负荷的不确定性,提出主动配电网无功补偿双层优化配置模型。上层规划以无功补偿电容器的投资成本、网络损耗费用综合最优为目标函数,下层规划在此基础上考虑调节无功补偿容量及调节有载变压器抽头两种主动管理措施,对每个场景进行优化。采用K-均值聚类法对场景进行缩减,结合和声搜索算法和粒子群算法联合求解模型。通过IEEE33节点算例进行仿真计算,验证所提模型和方法的正确性。     

肿瘤坏死因子促α粒子致细胞恶性转化的研究

实验以０．５Ｇｙ＾２３８Ｐｕ源α粒子照射后的斜利亚地鼠胚胎细胞为靶细胞，１０ｄ克隆形成实验评价人重且肿瘤坏死因子α促癌作用。通过传代的方法获得不同代龄的细胞，测定它们的生长速率、锚着独立性生长、裸鼠成瘤性等多项生物学指标。结果表明，人重组不死国α使０．５Ｇｙα粒子致叙利亚地鼠胚胎细胞转化频率增高２倍；经人重组肿瘤坏死因子α处理的０．５Ｇｙα粒子照射后的斜利亚地鼠胚胎细胞寿命明显延长，第４０代细胞的     

Application of AFM in microbiology: a review

Atomic force microscopy (AFM) is a powerful tool for microbiological investigation. This versatile technique cannot only image cellular surfaces at high resolution, but also measure many forms of fundamental interactions over scales ranging from molecules to cells. In this work, we review the recent development of AFM applications in the microbial area. We discuss several approaches for using AFM scanning images to investigate morphological characteristics of microbes and the use of force–distance curves to investigate interaction of microbial samples at the nanometer and cellular levels. Complementary techniques used in combination with AFM for study of microbes are also discussed. SCANNING 32: 61–73, 2010. © 2010 Wiley Periodicals, Inc.     

采前喷施胺鲜酯对采后龙眼果实贮藏期间果皮膜脂代谢的影响

为研究采前喷施胺鲜酯（diethyl aminoethyl hexanoate,DA-6）对采后龙眼果实贮藏期间果皮膜脂代谢的影响,以‘福眼’龙眼为实验材料,在龙眼盛花期后70、90、110 d用10 mg/kg DA-6溶液各喷施龙眼果实1 次,以蒸馏水喷施为对照。龙眼果实在盛花期后120 d采收,采后龙眼果实经过挑选、清洗和晾干后用厚度为0.015 mm的聚乙烯薄膜袋密封包装（每组50 袋,每袋50 个）,在（28±1）℃、相对湿度85%条件下贮藏。结果表明：采前喷施DA-6可延缓采后龙眼果实贮藏期间果皮细胞膜透性的增加,降低果皮脂氧合酶、脂酶和磷脂酶D等膜脂降解酶活力,延缓果皮膜磷脂（磷脂酰胆碱（phosphatidylcholine,PC）、磷脂酰肌醇（phosphatidylinositol,PI））和不饱和脂肪酸（油酸（C18:1）、亚油酸（C18:2）、亚麻酸（C18:3））的降解,保持较高的PC和PI含量及脂肪酸不饱和指数、脂肪酸不饱和度,保持较低的磷脂酸含量,维持正常细胞膜区室化功能和结构。因此,采前喷施DA-6增强采后龙眼果实耐贮性与采前喷施DA-6能有效降低采后龙眼果实贮藏期间果皮膜脂代谢有关。