Synthesis and characterization of conducting copolymers from aniline and o‐anisidine in HCl solutions

Conducting poly(aniline‐co‐o‐anisidine) (PAS) films with different ratios of aniline units in the polymer chain were prepared by oxidative polymerization of different molar ratios of aniline and o‐anisidine in 1 M HCl using cyclic voltammetry. Due to the much higher reactivity of o‐anisidine, the structure and properties of PASs were found to be dominated by the o‐anisidine units. The polymerization of poly‐o‐anisidine and PASs followed zero‐order kinetics with respect to formation of the polymer (film thickness) and the autocatalytic polymerization of aniline was completely inhibited. In contrast to polyaniline, a decrease in the polymerization temperature was found to increase the amount of copolymer formed and its redox charge. The presence of aniline units in PASs led to a pronounced increase in the molecular weight and conductivity, and a decrease in the solubility in organic solvents. Repetitive charging/discharging cycles showed that PASs resist degradation more than polyaniline. Copyright © 2003 Society of Chemical Industry     

Corrosion Control by water‐soluble extracts from leaves of economic plants

Water extracts from leaves of date palm, phoenix dactylifera, henna, Lawsonia inermis, and corn, Zea mays, were tested as corrosion inhibitors for steel, aluminum, copper and brass in acid chloride and sodium hydroxide solutions using weight loss, solution analysis and potential measurements. The inhibition action was found to critically depend on metal type and solution composition. Only, date palm and henna extracts were found highly effective in reducing corrosion rate of steel in acid chloride solutions and aluminum in sodium hydroxide solutions. The inhibition efficiency increased with increasing the concentration of the extract. The inhibition was interpreted in terms of chemisorption of some active ingredients in the leaves according to Temkin isotherm.     

Tumor size and prognosis in aggressively treated osteosarcoma

PURPOSE: The aim of this retrospective analysis was to investigate the prognostic significance and optimal measures of tumor size in osteosarcoma treated with intensive neoadjuvant chemotherapy. PATIENTS AND METHODS: Initial anterior-posterior (AP) and lateral x-ray films of 128 patients treated within the trials Cooperative Osteosarcoma Study (COSS)-80, -82, and -86, were evaluated for the following three tumor diameters: length, width, and depth. Metastasis-free survival (MFS) analyses were performed in univariate and multivariate models with one, two, and three dimensions of the tumor as absolute or relative measures (tumor length, referred to bone length, plane and volume to body-surface area). RESULTS: Univariate analyses of MFS showed a high prognostic significance of all absolute measures. Relative measures, at best, showed a comparable predictive value. Cox regression analysis indicated the high prognostic significance of absolute tumor volume (ATV; P < .0001) and histologic response (P < .0001). None of 19 patients with an ATV < or = 70 cm3 and only four of 53 with an ATV < or = 150 cm3 relapsed, while in patients with an ATV more than 150 cm3, the relapse rate remained 40% to 60%, irrespective of further increase in volume. CONCLUSION: Initial tumor size is an important and easily obtainable prognostic factor in osteosarcoma and may serve as a basis for risk-adapted therapy. It is best represented by the absolute three-dimensional measure ATV. There is a cut-off point regarding the incidence of metastases at a tumor volume of approximately 150 cm3 as calculated from two-plane x-ray films.     

Delay-dependent anti-windup synthesis for stability of constrained state delay systems using pole-constraints

This paper proposes the design of anti-windup compensator gain for stability of actuator input constrained state delay systems using constrained pole-position of the closed-loop. Based on Delay-Dependent Lyapunov-Krasovskii functionals and local sector conditions, a new LMI characterization is derived that ensures closed-loop asymptotic stability of constrained state delay systems while accounting upper bound fixed state delay and largest lower bound of the system’s pole-position in the formulation of anti-windup gain. Besides, at saturation, the method significantly nullifies the inherent slow dynamics present in the system. It is shown in the comparative numerical examples that the LMI formulation draws stability with improved time-domain performance.     

Sustainability evaluation framework for building cooling systems: a comparative study of snow storage and conventional chiller systems

In Canada, the residential building sector consumes 17 % of the total energy and 15 % of the total greenhouse gas emissions. In particular, the energy demand for cooling in the residential sector is increasing due to the large occupancy floor area and high usage of air conditioning. Minimizing energy use and greenhouse gas emissions is one of the highest priority goals set for national energy management strategies in developed countries including Canada. In this study, a framework based on the life cycle assessment approach is developed to assess the environmental impacts of different building cooling systems, namely conventional snow storage system, watertight snow storage system, high-density snow storage system, and the conventional chiller cooling system. Moreover, all these systems have varying energy requirements and associated environmental impacts during different phases (extraction and construction, utilization, and end of life) of the life cycle of a building. A low-rise residential building in Kelowna (BC, Canada) has been selected for the pragmatic application of the proposed framework. The annual cooling energy demand for the building is estimated for different phases. Subsequently, the life cycle impact assessment has been carried out using SimaPro 8.1 software and TRACI 2.1 method. For sustainability evaluation of different cooling systems over their life cycle, multi-criteria decision analysis has been employed using the ‘Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE II).’ The results showed that the snow storage systems tend to reduce greenhouse gas emissions and associated environmental impacts more than the conventional system.     

Modeling contaminant intrusion in water distribution networks: A new similarity-based DST method

Contaminant intrusion in a water distribution network is a complex but a commonly observed phenomenon, which depends on three elements – a pathway, a driving force and a contamination source. However, the data on these elements are generally incomplete, non-specific and uncertain. In an earlier work, Sadiq, Kleiner, and Rajani (2006) have successfully applied traditional Dempster–Shafer theory (DST) to estimate the “risk” of contaminant intrusion in a water distribution network based on limited uncertain information. However, the method used for generating basic probability assignment (BPA) was not very flexible, and did not handle and process uncertain information effectively. In this paper, a more pragmatic method is proposed that utilizes “soft” computing flexibility to generate BPAs from uncertain information. This paper compares these two methods through numerical examples, and demonstrates the efficiency and effectiveness of modified method.     

Evidential reasoning using extended fuzzy Dempster–Shafer theory for handling various facets of information deficiency

This work investigates the problem of combining deficient evidence for the purpose of quality assessment. The main focus of the work is modeling vagueness, ambiguity, and local nonspecificity in information within a unified approach. We introduce an extended fuzzy Dempster–Shafer scheme based on the simultaneous use of fuzzy interval‐grade and interval‐valued belief degree (IGIB). The latter facilitates modeling of uncertainties in terms of local ignorance associated with expert knowledge, whereas the former allows for handling the lack of information on belief degree assignments. Also, generalized fuzzy sets can be readily transformed into the proposed fuzzy IGIB structure. The reasoning for quality assessment is performed by solving nonlinear optimization problems on fuzzy Dempster–Shafer paradigm for the fuzzy IGIB structure. The application of the proposed inference method is investigated by designing a reasoning scheme for water quality monitoring and validated through the experimental data available for different sampling points in a water distribution network. © 2011 Wiley Periodicals, Inc.     

Reliability evaluation and optimal design in heterogeneous multi-state series-parallel systems

This paper addresses the heterogeneous redundancy allocation problem in multi-state series-parallel reliability structures with the objective to minimize the total cost of system design satisfying the given reliability constraint and the consumer load demand. The demand distribution is presented as a piecewise cumulative load curve and each subsystem is allowed to consist of parallel redundant components of not more than three types. The system uses binary capacitated components chosen from a list of available products to provide redundancy so as to increase system performance and reliability. The components are characterized by their feeding capacity, reliability and cost. A system that consists of elements with different reliability and productivity parameters has the capacity strongly dependent upon the selection of constituent components. A binomial probability based method to compute exact system reliability index is suggested. To analyze the problem and suggest an optimal/near-optimal system structure, an ant colony optimization algorithm has been presented. The solution approach consists of a series of simple steps as used in early ant colony optimization algorithms dealing with other optimization problems and offers straightforward analysis. Four multi-state system design problems have been solved for illustration. Two problems are taken from the literature and solved to compare the algorithm with the other existing methods. The other two problems are based upon randomly generated data. The results show that the method can be appealing to many researchers with regard to the time efficiency and yet without compromising over the solution quality.     

Probabilistic risk analysis of corrosion associated failures in cast iron water mains

This paper proposes a method using probabilistic risk analysis for application to corrosion associated failures in grey cast iron water mains. External corrosion reduces the capacity of the pipeline to resist stresses. When external stresses exceed the residual ultimate strength, pipe breakage becomes imminent, and the overall reliability of a water distribution network is reduced. Modelling stresses and external corrosion acting on a pipe involves uncertainties inherent in the mechanistic/statistical models and their input parameters. Monte Carlo (MC) simulations were used to perform the probabilistic analysis. The reduction in the factor of safety (FOS) of water mains over time was computed, with a failure defined as a situation in which FOS becomes smaller than 1. The MC simulations yielded an empirical probability density function of time to failure, to which a lognormal distribution was fitted leading to the derivation of a failure hazard function. A sensitivity analysis revealed that the contribution of corrosion parameters to the variability of time to failure was more significant than the combined contributions of all other parameters. Areas where more research is needed are identified.     

Evaluation of natural gas hydrates as a future methane source

In recent years, attention has been given to obtaining methane gas from natural gas hydrates (NGHs) sediment; but its production, economics, and safety are still far away from being commercially viable for many years, and so more research is needed. NGHs are nonstoichiometric crystalline solid compounds that form from mixtures of water molecules and light weight natural gases such as methane, ethane, propane, and carbon dioxide. They are formed in specific thermodynamic conditions, low temperatures (5–15°C) and high pressures (2–3 MPa), and are found in (a) onshore polar regions beneath permafrost and (b) offshore deep-sea sediments. Methane, NG, is the cleanest fossil fuel and its huge amounts in NGHs have carbon quantities more than double of all fossil fuels. The methods that have been proposed for NG extraction from NGHs include: (a) depressurization, (b) thermal stimulation, and (c) chemical inhibitor injections. The authors review the potential of methane gas from NGHs as an unconventional source of future energy. The formation of NGHs as well as extraction of methane from NGHs coupled with technical and environmental challenges are also addressed.