全文获取类型
收费全文 | 75250篇 |
免费 | 6772篇 |
国内免费 | 3440篇 |
专业分类
电工技术 | 4495篇 |
技术理论 | 10篇 |
综合类 | 5248篇 |
化学工业 | 12582篇 |
金属工艺 | 3960篇 |
机械仪表 | 4365篇 |
建筑科学 | 5848篇 |
矿业工程 | 2032篇 |
能源动力 | 2099篇 |
轻工业 | 6251篇 |
水利工程 | 1451篇 |
石油天然气 | 3904篇 |
武器工业 | 598篇 |
无线电 | 8930篇 |
一般工业技术 | 9247篇 |
冶金工业 | 3522篇 |
原子能技术 | 802篇 |
自动化技术 | 10118篇 |
出版年
2024年 | 306篇 |
2023年 | 1343篇 |
2022年 | 2375篇 |
2021年 | 3446篇 |
2020年 | 2626篇 |
2019年 | 2065篇 |
2018年 | 2341篇 |
2017年 | 2457篇 |
2016年 | 2358篇 |
2015年 | 3073篇 |
2014年 | 3854篇 |
2013年 | 4428篇 |
2012年 | 4885篇 |
2011年 | 5313篇 |
2010年 | 4389篇 |
2009年 | 4173篇 |
2008年 | 4141篇 |
2007年 | 3837篇 |
2006年 | 3600篇 |
2005年 | 3070篇 |
2004年 | 2279篇 |
2003年 | 2017篇 |
2002年 | 1873篇 |
2001年 | 1647篇 |
2000年 | 1752篇 |
1999年 | 2039篇 |
1998年 | 1727篇 |
1997年 | 1399篇 |
1996年 | 1379篇 |
1995年 | 1147篇 |
1994年 | 995篇 |
1993年 | 698篇 |
1992年 | 541篇 |
1991年 | 391篇 |
1990年 | 338篇 |
1989年 | 300篇 |
1988年 | 217篇 |
1987年 | 144篇 |
1986年 | 105篇 |
1985年 | 76篇 |
1984年 | 55篇 |
1983年 | 42篇 |
1982年 | 50篇 |
1981年 | 33篇 |
1980年 | 33篇 |
1979年 | 14篇 |
1977年 | 9篇 |
1976年 | 13篇 |
1974年 | 11篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Yuhang Xing Ruyi Li Lu Xue Mianhong Chen Xuli Lu Zhihao Duan Wei Zhou Jihua Li 《International Journal of Food Science & Technology》2022,57(8):5268-5279
Mangiferin (MGF) is a phenolic compound isolated from mango, but its poor solubility significantly limits its use. In this study, MGF was embedded into the inner aqueous phase of W1/O/W2 emulsions. Firstly, the dissolution method of MGF was determined. MGF remained stable in solution with pH 13 at 30 min, and its solubility reached 10 mg mL−1. When the pH of MGF solutions was adjusted from pH 13 to pH 6, MGF did not immediately crystallise, providing sufficient time to construct the MGF-loaded W1/O/W2 emulsions. Subsequently, the MGF-loaded W1/O/W2 emulsions were constructed using polyglycerol polyricinoleate (PGPR) and calcium caseinate (CAS). The formation and stability of the W1/O/W2 emulsions were investigated. The MGF-loaded W1/O/W2 emulsions stabilised with 1% PGPR and 1% – 3% CAS exhibited a low viscosity, limited loading capacity, and poor stability. Conversely, the MGF-loaded W1/O/W2 emulsions stabilised by 3%PGPR–3%CAS exhibited optimal loading capacity (encapsulation efficiency = 95.31% and loading efficiency = 0.91%) and stability, which was attributed to the fact that high viscosity and gel state retarded the migration of inner aqueous phase. These results indicated that the W1/O/W2 emulsions stabilised by PGPR and CAS may be a potential alternative for encapsulating mangiferin. 相似文献
2.
KH550, KH560, CTAB, and F127 were adopted to modify silicon (Si) to improve the dispersity and stability of Si in the polyacrylonitrile/dimethyl sulfoxide (PAN/DMSO) polymer solutions. The influence of surfactants on rheological behaviors of PAN/DMSO/Si blending polymer solutions was investigated by an advanced solution and melt rotation rheometer. The homogeneity and stability were also studied. The results showed that the surfactants could change the viscosity dependence of blending polymer solutions on shear rate, temperature and storage time by increase the steric hindrance of Si. Among the four solutions, PAN/DMSO/Si blending polymer solution with F127 exhibited the lowest viscosity, activation energy and the smallest structural viscosity index and exhibited the trend close to the Newtonian fluids. Moreover, PAN/DMSO/Si blending polymer solution with F127 exhibited the best dispersity and stability, indicating its best physical properties and machinability. 相似文献
3.
Shuang Chen Chao Yu Zhanfang Cao Xiaoping Huang Shuai Wang Hong Zhong 《International Journal of Hydrogen Energy》2021,46(10):7037-7046
The development of efficient and stable oxygen evolution reaction (OER) catalysts is an ongoing challenge. In order to solve the problem of low oxygen evolution efficiency of the current OER catalysts, a novel material was synthesized by the incorporation of NiFeCr-LDH and MoS2, and its structural and electrochemical properties were also investigated. The introduction of MoS2 improves the electrochemical performance of NiFeCr-LDH. The polarization curve shows that the potential of composite material is only 1.50 V at a current density of 10 mA cm?2, which is far superior to commercial precious metal catalysts. In addition, the stability experiment shows that the composite material has excellent stability, and the current density has little change after 500 cycles. Furthermore, we found that some metal ions, such as Ni, Cr and Mo, exist in the form of high valence on the surface of NiFeCr-LDH@MoS2, which is also conducive to the occurrence of oxygen evolution reaction. 相似文献
4.
Wenlong Song Shoujun Wang Yang Lu Xuan Zhang Zixiang Xia Kai Sun Guangming Xin 《Ceramics International》2021,47(9):12631-12640
To enhance the tribological performance of Si3N4/TiC ceramics, MoS2/PTFE composite coatings were deposited on the ceramic substrate through spraying method. The micrographs and basic properties of the MoS2/PTFE coated samples were investigated. Dry sliding friction experiments against WC/Co ball were performed with the coated ceramics and traditional ones. These results showed that the composite coatings could significantly reduce the friction coefficient of ceramics, and protect the substrate from adhesion wear. The primary tribological mechanisms of the coated ceramics were abrasive wear, coating spalling and delamination, and the tribological property was transited from slight wear to serious wear with the increase of load because of the lower surface hardness and shear strength. The possible mechanisms for the effects of MoS2/PTFE composite coatings on the friction performance of ceramics were discussed. 相似文献
6.
Cuiping Yu Shuang Sun Sihui Li Huijia Yan Henan Zou 《International Journal of Food Science & Technology》2022,57(2):1173-1185
In this study, the effect of high-intensity ultrasound (HIUS) (200 and 400 W for 0, 5, 10 and 15 min respectively) on conformational changes, physicochemical, rheological and emulsifying properties of scallop (Patinopecten yessoensis) myofibrillar protein (SMP) was investigated. HIUS-treated SMP had lower α-helix content and higher β-sheet content compared with the native SMP. HIUS treatment induced the unfolding of SMP and increased the surface hydrophobicity. The particle size of SMP decreased and the absolute zeta-potential increased after ultrasonication, which in turn increased the solubility of SMP. The conformational changes and the improvement of physicochemical properties of SMP increased the ability for SMP to lower the interfacial tension at the oil–water interface and increased the percentage of adsorbed protein. As a result, the emulsifying properties, rheological properties of SMP and storage stability of emulsions were also improved. In conclusion, HIUS treatment has future potential for improving the emulsifying properties of SMP. 相似文献
7.
Liang Yan-Jun Lu You-Jun Gao De-Xin Wang Zhong-Sheng 《International Journal of Control, Automation and Systems》2022,20(2):507-514
International Journal of Control, Automation and Systems - The vibration control problem of offshore jacket platforms is studied. The model of offshore platforms with nonlinear interactions of the... 相似文献
8.
9.
10.
Chuntao Lan Haiyang Zou Longfei Wang Meng Zhang Shuang Pan Ying Ma Yiping Qiu Zhong Lin Wang Zhiqun Lin 《Advanced materials (Deerfield Beach, Fla.)》2020,32(47):2005481
Despite recent rapid advances in metal halide perovskites for use in optoelectronics, the fundamental understanding of the electrical-poling-induced ion migration, accounting for many unusual attributes and thus performance in perovskite-based devices, remain comparatively elusive. Herein, the electrical-poling-promoted polarization potential is reported for rendering hybrid organic–inorganic perovskite photodetectors with high photocurrent and fast response time, displaying a tenfold enhancement in the photocurrent and a twofold decrease in the response time after an external electric field poling. First, a robust meniscus-assisted solution-printing strategy is employed to facilitate the oriented perovskite crystals over a large area. Subsequently, the electrical poling invokes the ion migration within perovskite crystals, thus inducing a polarization potential, as substantiated by the surface potential change assessed by Kelvin probe force microscopy. Such electrical-poling-induced polarization potential is responsible for the markedly enhanced photocurrent and largely shortened response time. This work presents new insights into the electrical-poling-triggered ion migration and, in turn, polarization potential as well as into the implication of the latter for optoelectronic devices with greater performance. As such, the utilization of ion-migration-produced polarization potential may represent an important endeavor toward a wide range of high-performance perovskite-based photodetectors, solar cells, transistors, scintillators, etc. 相似文献