Processing and characterization of a biaxially oriented conducting polymer

Two methods have been developed for the preparation of biaxially oriented poly(phenylene vinylene) from its poly(sulfonium salt) precursor. A two-stage stretching process permits non-equibiaxial stretching over a wide range of deformation ratios and a bubble expansion technique allows equibiaxial planar extension. The resulting films were examined using X-ray diffraction prior to chemical doping with SbF₅ vapor. Biaxial orientation was shown to exert considerable influence over the attainable electrical conductivity.     

PETROPHYSICS OF LOWER CRETACEOUS PLATFORM CARBONATE OUTCROPS IN PROVENCE (SE FRANCE): IMPLICATIONS FOR CARBONATE RESERVOIR CHARACTERISATION

High resolution petrophysical analyses were carried out on Urgonian (Lower Cretaceous) carbonates from outcrops in Provence, SE France. Porosity and permeability were measured on 541 plug samples selected from grain‐supported carbonates analogous to those in the age‐equivalent Shu'aiba and Kharaib Formation reservoirs in the eastern Arabian Plate. The sampling strategy allowed property heterogeneities from centimetre to kilometre scales to be investigated, as well as correlations between porosity and permeability in several different reservoir rock types. Property spatial modelling sensitivity analyses were also undertaken. The relative abundance of microporosity, grain size and sedimentary‐diagenetic anisotropy were the main geological parameters which controlled the petrophysical characteristics of the grainstones studied. Increasing microporosity decreased permeability but resulted in an increase in the homogeneity of the reservoir rocks and therefore in their predictability. An increase in grain size, from fine sand to gravel, and in the amount of intergranular pores, enhanced permeability significantly but resulted in a decrease in the homogeneity (and therefore predictability) of the reservoir rock. At a plug scale, poro‐perm relationships are very good and can be used predictively for fine grainstones dominated by microporosity; but relationships are moderate to weak for coarse rudstones with mixed pore types, including intraskeletal pores. In grainstone units, weak sedimentary anisotropy, such as decametre‐scale cross‐bedding, did not prevent the prediction of the horizontal property distribution from vertical data over a few hundreds of metres. In these units, the lateral correlation of rock properties follows periodic variograms with a 7 m wavelength. The lateral distribution of properties in coarse‐grained and heterogeneous rudstones with complex pore types and intense sedimentary heterogeneities, such as channel structures, was however more difficult to predict from a vertical data set. Upscaling poroperm data from plug scale to reservoir scale is linear in the case of grainstones with intergranular microporosity, but is non‐linear in the case of skeletal rudstones with coarser pore types including skeletal porosity.     

Preference-based English reverse auctions

This paper studies English reverse auctions within a unified framework for preference-based English reverse auctions. In this context, and particularly for electronic auctions, representing and handling the buyer?s preferences, so as to enable him/her to obtain the best possible outcome, is a major issue. Existing auction mechanisms, which are based on single or multi-attribute utility functions, are only able to represent transitive and complete preferences. It is well known, however, in the preference modeling literature that more general preference structures, allowing intransitivity and incomparability, are more appropriate to capture preferences. On the other hand, we must also consider properties on the evolution and, above all, on the outcome of any auction executed by an auction mechanism. These properties, as well as properties of non-dominance and fair competition defined for multiple criteria auctions, impose restrictions on the preference relation. This leaves room for interesting preference models to be implemented within English reverse auction mechanisms.     

Early disruptive behavior, poor school achievement, delinquent behavior, and delinquent personality: Longitudinal analyses.

Three alternative models concerning the causal links between early disruptive behavior, poor school achievement, and delinquent behavior or antisocial personality were tested with linear structural equation modeling. Ss were boys and girls followed from 1st grade to age 14 yrs. Disruptive behavior was assessed in Grade 1; school achievement was assessed in Grades 1 and 4; delinquent behavior and antisocial personality were assessed at age 14 yrs. With regard to self-reported delinquent behavior at age 14 yrs, results indicate that the best model for boys was a direct causal link between Grade 1 disruptive behavior and delinquent behavior. Poor school achievement was not a necessary causal factor. For girls, none of the tested models were a good fit to the delinquent behavior data. As for delinquent personality, results indicate that, for boys and girls, poor school achievement was a necessary component of the causal path between Grade 1 disruptive behavior and age 14 delinquent personality. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Sensitivity of CFP/YFP and GFP/mCherry pairs to donor photobleaching on FRET determination by fluorescence lifetime imaging microscopy in living cells

Fluorescent protein-based FRET is a powerful method for visualizing protein-protein interactions and biochemical reactions in living cells. It can be difficult, however, to avoid photobleaching when observing fluorescent cells under the microscope, especially those expressing CFP. We compared the sensitivity of two protein-based FRET pairs to light-induced fluorescence changes in the donor, on FRET determination by fluorescence lifetime imaging microscopy (FLIM). Thanks to the very low excitation light levels of the time- and space-correlated single photon counting (TSCSPC) method, FLIM acquisitions were achieved without donor photobleaching. Here, we show that photobleaching of CFP by a mercury lamp under the microscope induced a decrease in the mean fluorescence lifetime, which interfered with FRET determination between CFP and YFP. Importantly, the range of light-induced variation of the mean fluorescence lifetime of CFP was not proportional to the decrease in the steady state fluorescence intensity and varied from cell to cell. The choice of the CFP/YFP pair therefore requires that the cells be observed and analyzed at very low light levels during the whole FRET experiment. In contrast, the GFP/mCherry pair provided an accurate FRET measurement by FLIM, even if some GFP photobleaching took place. We thus demonstrate that CFP can be an unreliable donor for FRET determination in living cells, due to its photosensitivity properties. We demonstrate that the GFP/mCherry pair is better suited for FRET measurement by FLIM in living cells than the CFP/YFP pair.     

Quality of MPEG2 signal on a simulated digital terrestrialtelevision

The monitoring of the quality of service in digital television networks needs instruments to assess automatically the perceived quality of audio and video components of an MPEG2 signal. In order to improve the knowledge of the impact of the impairments on the final service, and to validate the algorithms that will be implemented in the quality evaluation instruments, a general simulation chain has been designed and developed. This paper presents the simulations performed as well as the analysis and the synthesis of the obtained results