Real-time organic aerosol chemical speciation in the indoor environment using extractive electrospray ionization mass spectrometry

Understanding the sources and composition of organic aerosol (OA) in indoor environments requires rapid measurements, since many emissions and processes have short timescales. However, real-time molecular-level OA measurements have not been reported indoors. Here, we present quantitative measurements, at a time resolution of five seconds, of molecular ions corresponding to diverse aerosol-phase species, by applying extractive electrospray ionization mass spectrometry (EESI-MS) to indoor air analysis for the first time, as part of the highly instrumented HOMEChem field study. We demonstrate how the complex spectra of EESI-MS are screened in order to extract chemical information and investigate the possibility of interference from gas-phase semivolatile species. During experiments that simulated the Thanksgiving US holiday meal preparation, EESI-MS quantified multiple species, including fatty acids, carbohydrates, siloxanes, and phthalates. Intercomparisons with Aerosol Mass Spectrometer (AMS) and Scanning Mobility Particle Sizer suggest that EESI-MS quantified a large fraction of OA. Comparisons with FIGAERO-CIMS shows similar signal levels and good correlation, with a range of 100 for the relative sensitivities. Comparisons with SV-TAG for phthalates and with SV-TAG and AMS for total siloxanes also show strong correlation. EESI-MS observations can be used with gas-phase measurements to identify co-emitted gas- and aerosol-phase species, and this is demonstrated using complementary gas-phase PTR-MS observations.     

基于有限状态的全周期序列混沌映射的研究

在有限长度的数字计算机中，混沌迭代序列是一个有限周期序列，其相关性能远远低于理想序列。基于skew tent映射，提出一种离散化的有限状态混沌映射，它允许精确的数值计算，没有舍入误差，通过选择合适的参数，映射能产生全周期长度的序列。仿真实验表明，归一化的序列平均周期对计算机精度不敏感，生成的二进制序列具有良好的相关性能。     

武汉市长丰低闸施工期安全监测资料分析

对武汉市长江烂泥湖堤长丰低闸重建施工期间的安全监测资料进行了分析。重点分析了闸过水箱涵的结构缝开合、不均匀沉降等变形监测量变化特征及发展趋势 ,并由此对长丰低闸在施工期的安全状态进行了评判     

富氧燃烧技术在梭式窑中的应用

研究了富氧燃烧技术对梭式窑烧成的影响.研究结果表明,随着氧浓度从21%-30%的逐渐增加,CO总浓度和NO总浓度都先明显下降,后缓慢上升;节能效果在初始段较为明显,而后效果不明显;而实际烟气量与氧浓度成反比,与过剩空气系数成正比.     

高速微粒携基因侵入植物细胞的速度条件

本文围绕基因枪技术中用高速微粒向植物细胞中导入外源基因的速度条件，分析了其中的三个动力学过程：发射宏弹、加速微弹、侵入细胞．提出了气动撞击发射式基因枪中弹簧刚度应满足的条件；得到了一种用理论分析与试验测试相结合确定微弹出射速度的方法；找到了微弹侵入植物细胞的最小速度条件。从而为基因枪的设计提供了理论依据。     

聚苯胺电化学性能的改性研究

改善聚苯胺的电化学性能是聚苯胺研究中的一个重点，介绍了对聚苯胺的取代，共聚，复合和掺杂等几种改性方法，及其对聚苯胺电化学性能和其他性能的影响。     

煤直接液化中SO2-4 /ZrO2固体酸的催化作用

以二苯甲烷、苯乙醚为煤的模型化合物,以四氢萘(THN)为溶剂,进行中高压加氢液化实验,结合产物的气相色谱和质谱分析,考察了SO2-4/ZrO2固体酸对煤直接液化的催化作用及加氢液化机理.实验结果表明,SO2-4/ZrO2固体酸对模型化合物的转化具有良好的催化活性,与非催化液化相比,400 ℃、H2初压5 MPa、30 min时二苯甲烷的转化率由8.96%提高到61.75%,且模型化合物的存在促进了溶剂THN的转化,上述条件下THN的转化率也达到10.92%;模型化合物及THN的转化主要包括氢解、异构、氢转移及烷基化等反应;SO2-4/ZrO2固体酸的催化作用主要为酸催化的离子反应机理,增强催化剂的酸性有利于煤的催化液化.     

研究生创造性培养与头脑风暴法的应用

对前沿性课题进行探索与研究是研究生教育的特点之一,因而创造性对于研究生的学习是必不可少的.头脑风暴法是由美国创造学家奥斯本(Osbotn)提出的一种在集体活动中产生创造性思维的方法.在研究生创造性培养中运用头脑风暴法,不失为一种有价值的尝试.     

Magnetic properties of nickel filament polymer-matrix composites

The magnetic properties of polyethersulfone-matrix composites with 3-19 vol.% polycrystalline nickel filaments (0.4 (im diam) were investigated. These filaments were found to exhibit hysteresis energy loss 10800 J/m³ of nickel and coercive force 16.9 kA/m, compared to corresponding values of 4930 J/m³ and 4.7 kA/m for 2 μ.m diam polycrystalline nickel fibers, 1020 J/m³ and 0.5 kA/m for 20 μm diam polycrystalline nickel fibers, and 1280 J/m³ and 2.3 kA/m for solid polycrystalline nickel.