Graphite formation on Ni film by chemical vapor deposition

Thin film formation of graphite by chemical vapor deposition using 2-methyl-1,2′-naphthyl ketone as a starting material was carried out on Ni film substrates. On Ni films directly deposited on quartz glass, the graphite films were obtained when the Ni film thickness was above 1 000 Å and above 5 000 Å at 700 °C and 1 000 °C, respectively. Depositions on thinner Ni film substrates comprise amorphous carbon (a-C) or graphite tubes which was owing to the thermal coagulation of the Ni film into droplets. On the other hand, graphite film was obtained on the Ni film with thickness 10 Å when a-C was inserted between the Ni film and the quartz glass. The coagulation of the Ni film is considered to be avoided by inserting a-C layer.     

Potential bile acid metabolites. 24. An efficient synthesis of carboxyl-linked glucosides and their chemical properties

A facile and efficient synthesis of the carboxyl-linked glucosides of bile acids is described. Direct esterification of unprotected bile acids with 2,3,4,6-tetra-O-benzyl-d-glucopyranose in pyridine in the presence of 2-chloro-1,3,5-trinitrobenzene as a coupling agent afforded a mixture of the α- and β-anomers (ca. 1∶3) of the 1-O-acyl-d-glucoside benzyl ethers of bile acids, which was separated effectively on a C₁₈ reversedphase chromatography column (isolated yields of α- and β-anomers are 4–9% and 12–19%, respectively). Subsequent hydrogenolysis of the α- and β-acyl glucoside benzyl ethers on a 10% Pd−C catalyst in acetic acid/methanol/EtOAc (1∶2∶2, by vol) at 35°C under atmospheric pressure gave the corresponding free esters in good yields (79–89%). Chemical specificities such as facile hydrolysis and transesterification of the acyl glucosides in various solvents were also discussed.     

Effect of polycyclopentene on crystallization of isotactic polypropylene

The application of some polymers as nucleating agents for polypropylene has been examined. Among various polymeric nucleating agents, polycyclopentene was found to be a superior nucleating agent to typical organic nucleating agents. When polycyclopentene was added to polypropylene, the crystallization temperature and the degree of crystallinity of polypropylene increased. In addition, the crystallization rate and the number of spherulites increased whereas the size of spherulites decreased remarkably. As a result of polycyclopentene addition, the transparency of polypropylene film could be improved considerably. © 1994 John Wiley & Sons, Inc.     

A two-stage heuristic for single machine capacitated lot-sizing and scheduling with sequence-dependent setup costs

This paper considers a single machine capacitated lot-sizing and scheduling problem. The problem is to determine the lot sizes and the sequence of lots while satisfying the demand requirements and the machine capacity in each period of a planning horizon. In particular, we consider sequence-dependent setup costs that depend on the type of the lot just completed and on the lot to be processed. The setup state preservation, i.e., the setup state at the end of a period is carried over to the next period, is also considered. The objective is to minimize the sum of setup and inventory holding costs over the planning horizon. Due to the complexity of the problem, we suggest a two-stage heuristic in which an initial solution is obtained and then it is improved using a backward and forward improvement method that incorporates various priority rules to select the items to be moved. Computational tests were done on randomly generated test instances and the results show that the two-stage heuristic outperforms the best existing algorithm significantly. Also, the heuristics with better priority rule combinations were used to solve case instances and much improvement is reported over the conventional method as well as the best existing algorithm.     

On the probability theory on MV algebras

 The paper contains a review of some results concerning probability theory on MV algebras (laws of large numbers, central limit theorem, martingale convergence theorem). Also some algebraic and methodical aspects are discussed.     

Enhanced soft-handoff scheme for real-time streaming services in intelligent transportation systems based on CDMA

Code division multiple access (CDMA)-based radio-on-fiber road-vehicle communication systems were proposed to support real-time streaming services in intelligent transportation systems (ITSs). Soft handoff should be provided for real-time streaming services because these services are required to guarantee real-time property and quality of service (QoS). However, soft handoff of real-time streaming services causes the shortage of resource in view of the system. In this paper, the double-adjustment soft-handoff (DASH) scheme is proposed to support seamless service regardless of the shortage of resource and maximize the resource efficiency when real-time streaming services are served in CDMA-based ITSs. The DASH scheme adjusts the data rate of a call when it starts and finishes soft handoff. The performance of the DASH scheme is evaluated by analytical and simulation methods. Performances are evaluated with respect to the blocking probability, the handoff failure probability, and the carried traffic. Numerical results show that the proposed scheme can give relative good maintenance of calls and good throughput.     

Performance Analysis on Coexistence of EDCA and Legacy DCF Stations in IEEE 802.11 Wireless LANs

The distributed coordination function (DCF) scheme of IEEE 802.11 MAC protocol does not support any concepts of quality of service (QoS) but the enhanced distributed channel access (EDCA) scheme in IEEE 802.11e standard provides QoS according to access categories using different access parameters. However, the legacy DCF stations may be used together with EDCA stations. In this letter, we investigate and analyze the performance discrimination when EDCA and DCF stations operate simultaneously     

Performance evaluation of soft handoff for multimedia services in intelligent transportation systems based on CDMA

To support multimedia services in intelligent transportation systems (ITS), CDMA based radio-on-fiber road-vehicle communication systems were proposed. Soft handoff should be provided for multimedia services because these services are required to guarantee real-time property and quality of service (QoS). The performance evaluation of soft handoff is important in view of system management such as determination of optimal resource allocation, cell configuration, and admission strategy. But, the performance evaluation of soft handoff when multimedia services are serviced has not been previously researched, even though there have been some previous works for voice-call service. In this paper, we develop a new analytical model of soft handoff when multimedia services are served in CDMA based ITS. We evaluate the performance of soft handoff scheme by analytical and simulational method. Blocking probability, handoff failure probability and carried traffic are obtained.